Preliminary assessment of trace metals and polycyclic aromatic hydrocarbons in the sediments

Total concentrations of Cd, Cr, Co, Fe, Pb, Ni, Mn and Zn were determined by atomic absorption spectrophotometry in the surface sediments of Taylor Creek, Southern Nigeria. The most concentrated trace metals, ranging from 113.2 to 5160.7 mg/g-dry weights were Fe, Pb, Mn, Ni and Zn. There was no significant variation in sediment-associated metal levels (P>0.05). The metal pollution index was highest at Agbia/Nedugo and is attributed to local contamination of the Creek. The concentrations of low molecular weight polycyclic aromatic hydrocarbons (PAHs) were also detected and quantified in the sediments by capillary gas chromatography equipped with a flame ionization detector. The concentration levels of 178.1-1266.3 mg/g-wet weights were high for the PAHs. The results indicate that the pollutants, which are bio-accumulatable, could contribute to inferior biodiversity, and shifts in community composition from sensitive to tolerant taxa.     

UPPER PALAEOZOIC FORMATIONS AND FAUNAS OF YAOLING,CHENHSIEN,S.HUNAN.

STRATIGRAPHY Yao Ling (瑤林) lies 40 li southeast from Chen Hsien city (郴縣), about Long. 112°30′E., Lat. 25°40′N., and is halfway between Chen Hsien city and the well known wolfram mining district, Yao Kang Sien (瑤崗仙). On the     

A stochastic model of the atmospheric precipitation in the coastal zone of the Tropical Atlantic

A stochastic prognostic model of the atmospheric precipitation in the tropical area of the Atlantic Ocean is developed on the basis of a large data array. The data represent a series of monthly precipitation rates for 31 towns in the Republic of Guinea covering a period of 35–64 years as well as satellite data on the meridional displacement of the Intertropical Convergence Zone during 11 years. The model takes into account major regularities of the tropical precipitation: their impulsive periodic regime, trends, and the modulation of the stochastic component by the determined variability.Translated by Mikhai M. Trufanov.     

The δ-Cancrids Meteor Complex

Solar System Research - In studying the connections of the δ-Cancrids (DCA) meteor stream, consisting of the northern (NCC) and southern (SCC) branches, with the comet–asteroid complex,...     

Pile foundation analysis and design using experimental data and 3-D numerical analysis

Capacity based design of pile foundations limits the soil-structure interaction mechanism to group bearing capacity estimation, neglecting, in most cases, the contribution of the raft. On the other hand, a straightforward, nonlinear, 3-D analysis, accounting for soil and structural nonlinearities and the effects arising from pile–soil–pile interaction, would be extremely high CPU-time demanding and will necessitate the use of exceptionally powerful numerical tools. With the aim of investigating the most efficient, precise, and economical design for a bridge foundation, a hybrid method, compatible with the notion of sub-structuring is proposed. It is based on both experimental data and nonlinear 3-D analysis. The first step to achieve these targets is a back-analysis of a static pile load test, fitting values for soil shear strength, deformation modulus, and shear strength mobilization at the soil–pile interface. Subsequently, the response of 2 × 2 and 3 × 3 pile group configurations is numerically established and the distribution of the applied load to the raft and the characteristic piles is discussed. Finally, a design strategy for an optimized design of pile raft foundations subjected to non-uniform vertical loading is proposed.     

A new semi-quantitative Surface-Enhanced Raman Spectroscopy (SERS) method for detection of maleimide (2,5-pyrroledione) with potential application to astrobiology

Nitrogen-containing heterocyclic compounds are fundamental biochemical components of all life on Earth and, presumably, life elsewhere in our solar system. Dete...     

Trace element distribution in the soils above deeply weathered pegmatites, Virginia, U.S.A.: implications for exploration

Chemical partitioning data are of fundamental interest to exploration geochemists. This paper is one of the few studies which has investigated the relative proportions of the rare elements in various soil extracts. The dispersion of trace elements from weathering pegmatites in Powhatan Country, Virginia, was found to be restricted to the immediate vicinity of the pegmatites. A sequential extraction procedure was used to measure the distribution of Be, La, Nb, Sn, U, Li, and Ni,among the following fractions of the B soil horizons: exchangeable, Fe and Mn oxyhydroxide, residual, and aqua regia digestion. The elements Sn, Be, Li, and U were found to be associated with soils over the complex Herbb No. 2 pegmatite, whereas La and Ni were generally associated with the background soils.A geochemical exploration model was developed using stepwise discriminant function analysis to determine the combination of elements and soil extracts that best differentiates between complex pegmatitic, simple pegmatitic, and background soils. Log-transformed aqua regia extract concentrations of Sn, La, U, and Li were the most effective variables when used to separate complex pegmatitic from simple pegmatitic soils.