A variance-ratio test for supporting a variable mean in kriging

This article discusses the issue of whether to use a variable mean and describes a test that can be used to evaluate whether it is justified to add terms to the drift (deterministic part) of a geostatistical model. The basic model could be the intrinsic one, where the deterministic part is a constant, and the alternate model could be any model that includes a constant term in the expression for the drift. Also, differences between constant- and variable-mean models are discussed.     

Whole-rock and sulfide lead-isotope data from the hydrothermal JADE field in the Okinawa back-arc trough

The mineralization of the active hydrothermal JADE field resembles in many aspects the Kuroko-type mineralization. The JADE field is located in a back-arc graben and is associated with a bimodal volcanism. Lead isotope data from igneous rocks, sediments, and ores further emphasize the similarities with the Kuroko ores and suggest that both sediments and volcanic rocks contributed comparable amounts of lead to the deposit. When compared to the sediments, a much larger volume of volcanic rocks must have contributed lead to the deposit, because of the considerably lower lead concentration of volcanic rocks. In contrast to the crustal type lead of the JADE field and the Kuroko-type sulfide deposits the lead isotope signatures of VMS-type deposits at mid-ocean ridges is distinctly different. In the absence of a sedimentary cover it reflects the composition of the mantle source, whereas in the presence of a sedimentary cover it is either a mixture of mantle and sedimentary lead or it may even be completely dominated by the latter. Received: 5 October 1995 / Accepted: 10 May 1996     

Late Cretaceous rift-related upwelling and melting of the Trindade starting mantle plume head beneath western Brazil

High mantle potential temperatures and local extension, associated with the Late-Cretaceous impact of the Trindade mantle plume, produced substantial widespread and voluminous magmatism around the northern half of the Paraná sedimentary basin. Our previous studies have shown that, above the central and eastern portions of the postulated impact zone where lithosphere extension is minimal, heat conducted by the plume caused large-scale melting of the more fusible parts of the subcontinental lithospheric mantle beneath the margin of the São Francisco craton and the surrounding Brasilía mobile belt. Here we combine geochemical data and field evidence from the Poxoreu Igneous Province, western Brazil to show how more intense lithospheric extension above the western margin of the postulated impact zone permitted greater upwelling and melting of the Trindade plume than further east. Laser ⁴⁰Ar/³⁹Ar age determinations indicate that rift-related basaltic magmas of the Poxoreu Igneous Province were emplaced at ? 84 Ma. Our detailed geochemical study of the mafic magmas shows that the parental melts underwent polybaric crystal fractionation within the crust prior to final emplacement. Furthermore, some magmas (quartz-normative) appear to have assimilated upper crust whereas others (nepheline- and hypersthene-normative) appear to have been unaffected by open-system crustal magma chamber processes. Incompatible trace element ratios (e.g. chondrite-normalised La/Nb?=?1) and isotopic ratios (⁸⁷Sr/⁸⁶Sr?=?0.704 and ¹⁴³Nd/¹⁴⁴Nd?=?0.51274) of the Hy-normative basalts resemble those of oceanic islands (OIB). We therefore propose that these “OIB-like” magmas were predominantly derived from convecting-mantle-source melts (i.e. Trindade mantle plume). Inverse modelling of rare-earth element (REE) abundances suggests that the initial melts were predominantly generated within the depth range of ?80–100 km, in mantle with a potential temperature of ?1500 °C.     

Electrokinetic remediation of metal contaminated glacial tills

This paper presents the results of an experimental investigation which studied the feasibility of using the electrokinetic process to remediate contaminated clays of glacial origin, otherwise known as glacial tills. An overview of the electrokinetic phenomena, as well as previously performed laboratory and field investigations, is first presented. The methodology of the electrokinetic experiments which were conducted to investigate the removal of metals from a glacial till is then described. A total of 16 experiments were conducted using glacial till samples obtained from a project site near Chicago. Sodium and calcium were used as the surrogate cationic metallic contaminants. These experiments demonstrated that ion transport during the electrokinetic process occurs due to both electro-osmosis and electromigration, but that due to electromigration is significantly higher than that due to electro-osmosis. Unlike other clays such as kaolinite, the glacial till used for this investigation possessed high buffering capacity because of its high carbonate content which prevented the acid front migration from the anode to the cathode during the electrokinetic process. The ion removal efficiency of the electrokinetic process was found to increase when: (1) the voltage gradient applied to the soil was increased, (2) the initial concentration of the contaminants was increased, and (3) the duration of the treatment process was increased. The ion removal efficiency was also greater for smaller ions which possess less ionic charge and when the ions existed independently in the soil as compared to when they coexisted. This investigation suggests that the electrokinetic process has significant potential for remediating glacial tills contaminated with metals. However, the properties of Na and Ca are not representative of contaminants, such as heavy metals, so further investigations are needed.     

Isotope composition of Medieval lead glasses reflecting early silver production in Central Europe

The lead isotope composition of 32 lead glasses excavated from strata of the twelfth to early fifteenth century in six countries of NW Europe made the predominance of the Harz Mountains in this period of the Medieval European lead and silver production highly probable. Post-Variscan vein type galena, Devonian syngenetic hydrothermal ore (Rammelsberg) and blended ore from both deposits in the Harz were used. Our evaluation of 200 mining sites in Germany, Britain and Ireland also demonstrated that minor lead sources for lead glass were located in Bavaria/Bohemia and England. Lead ores from the Rhenohercynian orogenic belt in Germany are derived from rock sources close to the upper continental crust composition in ²³⁸U/²⁰⁴Pb of about 10 and Th/U of about 4. The ores in Central England originated from rocks with ²³⁸U/²⁰⁴Pb of about 11. Received: 24 September 1996 / Accepted: 17 January 1997     

An application of factor analysis for the study of the hydrogeological conditions in Plio-Pleistocene aquifers of NW Achaia (NW peloponnesus, Greece)

R- andQ-mode factor analysis is applied to 51 groundwater samples collected from wells drilled in the Plio-Pleistocene aquifers of NW Achaia, Greece. The purpose ofR- andQ-mode factor analysis application is to identify (i) the regional groundwater flow pattern, and (ii) the deterioration of groundwater quality. Sixteen hydrogeological parameters are used in order to examine their importance and to provide significant insight into their correlations. In theR-mode factor analysis, a six-factor model is suggested which can explain more than 77.5% of the total variance. The contribution of each factor at every site (factor scores) also is computed. Maps are constructed showing the geographical distribution of the factor scores. From these maps, the high salinity areas are delineated (seawater intrusion, possible appearance of halite layers) and the areas with elevated contribution of karastic-water are defined. Using theQ-mode correspondence analysis the meaning of the electrical conductivity as the most important variable in groundwater quality characterization is demonstrated.     

Texture and mineralogy of sediments from the Ganges-Brahmaputra-Meghna river system in the Bengal Basin, Bangladesh and their environmental implications

 The Bengal basin, Bangladesh, represents one of the most densely populated recent floodplains of the world. The sediment flux through the basin is one of the highest on a global scale. A significant portion of this sediment load find its sink in the basin itself because of its lower elevation and frequent flooding. The textural, mineralogical and chemical nature of the sediments thus have an important bearing on the environmental quality of the basin as well as for the Bay of Bengal. The sediment load of the Ganges-Brahmaputra-Meghna (GBM) river system consists exclusively of fine sand, silt and clay at their lower reaches within the Bengal basin, Bangladesh, and is deposited under uniformly fluctuating, unidirectional energy conditions. The sediments have a close simitarity in grain size with the sediments of the surrounding floodplain. The mineral assemblage is dominated by quartz and feldspars. Illite and kaolinite are the major clay minerals, and occur in almost equal proportion in bed sediments. The heavy mineral assemblage is dominated by unstable minerals which are mostly derived from high-rank metamorphic rocks. The characteristic smaller grain-size, i.e. having large surface-to-mass ratios, and the mineralogy of sediments suggests that they are susceptible to large chemical adsorptive reactions and thus could serve as a potential trap for contaminants. However, the sediments of the GBM river system in the Bengal basin, Bangladesh, shows lower concentration of Pb, Hg and As, and a marginally higher value for Cd as compared to that of standard shale. Considering population density and extensive agricultural practice in the basin, the sediments can in the long run become contaminated. Received: 9 November 1994 · Accepted: 18 June 1996     

A bivariate meta-Gaussian density for use in hydrology

Convenient bivariate densities found in the literature are often unsuitable for modeling hydrologic variates. They either constrain the range of association between variates, or fix the form of the marginal distributions. The bivariate meta-Gaussian density is constructed by embedding the normal quantile transform of each variate into the Gaussian law. The density can represent a full range of association between variates and admits arbitrarily specified marginal distributions. Modeling and estimation can be decomposed into i) independent analyses of the marginal distributions, and ii) investigation of the dependence structure. Both statistical and judgmental estimation procedures are possible. Some comparisons to recent applications of bivariate densities in the hydrologic literature motivate and illustrate the model.