Sicilian serpentinite xenolihs conaining abioic organics wih nanodiamond clusers ans key model for prebioic processes

Rock fragments from the deepest parts of a buried hydrothermal system belonging to the Mesozoic Tethys Oceanentered as xenoliths in a Miocenic diatreme. hence b...     

Evaporites,brines and base metals: Low‐temperature ore emplacement controlled by evaporite diagenesis

Salt beds and salt allochthons are transient features in most sedimentary basins, which through their dissolution can carry, focus and fix base metals. The mineralisation can be subsalt, intrasalt or suprasalt, and the salt body or its breccia can be bedded or halokinetic. In all these evaporite‐associated low‐temperature diagenetic ore deposits there are four common factors that can be used to recognise suitably prepared ground for mineralisation: (i) a dissolving evaporite bed acts either as a supplier of chloride‐rich basinal brines capable of leaching metals, or as a supplier of sulfur and organics that can fix metals; (ii) where the dissolving bed is acting as a supplier of chloride‐rich brines, there is a suitable nearby source of metals that can be leached by these basinal brines (redbeds, thick shales, volcaniclastics, basalts); (iii) there is a stable redox interface where these metalliferous chloride‐rich waters mix with anoxic waters within a pore‐fluid environment that is rich in organics and sulfate/sulfide/H₂S; and (iv) there is a salt‐induced focusing mechanism that allows for a stable, long‐term maintenance of the redox front, e.g. the underbelly of the salt bed or allochthon (subsalt deposits), dissolution or halokinetically maintained fault activity in the overburden (suprasalt deposits), or a stratabound intrabed evaporite dissolution front (intrasalt deposits). The diagenetic evaporite ‐ base‐metal association includes world‐class Cu deposits, such as the Kupferschiefer‐style Lubin deposits of Poland and the large accumulations in the Dzhezkazgan region of Kazakhstan. The Lubin deposits are subsalt and occur where long‐term dissolution of salt, in conjunction with upwelling metalliferous basin brines, created a stable redox front, now indicated by the facies of the Rote Faule. The Dzhezkazgan deposits (as well as smaller scale Lisbon Valley style deposits) are suprasalt halokinetic features and formed where a dissolving halite‐dominated salt dome maintained a structural focus to a regional redox interface. Halokinesis and dissolution of the salt bed also drove the subsalt circulation system whereby metalliferous saline brines convectively leached underlying sediments. In both scenarios, the resulting redox‐precipitated sulfides are zoned and arranged in the order Cu, Pb, Zn as one moves away from the zone of salt‐solution supplied brines. This redox zonation can be used as a regional pointer to both mineralisation and, more academically, to the position of a former salt bed. In the fault‐fed suprasalt accumulations the feeder faults were typically created and maintained by the jiggling of brittle overburden blocks atop a moving and dissolving salt unit. A similar mechanism localises many of the caprock replacement haloes seen in the diapiric provinces of the Gulf of Mexico and Northern Africa. Evaporite‐associated Pb–Zn deposits, like Cu deposits, are focused by brine flows associated with both bedded and halokinetic salt units or their residues. Stratabound deposits, such as Gays River and Cadjebut, have formed immediately adjacent to or within the bedded salt body, with the bedded sulfate acting as a sulfur source. In allochthon/diapir deposits the Pb–Zn mineralisation can occur both within a caprock or adjacent to the salt structure as replacements of peridiapiric organic‐rich pyritic sediments. In the latter case the conditions of bottom anoxia that allowed the preservation of pyrite were created by the presence of brine springs and seeps fed from the dissolution of nearby salt sheets and diapirs. The deposits in the peridiapiric group tend to be widespread, but individual deposits tend to be relatively small and many are subeconomic. However, their occurrence indicates an active metal‐cycling mechanism in the basin. Given the right association of salt allochthon, tectonics, source substrate and brine ponding, the system can form much less common but world‐class deposits where base‐metal sulfides replaced pyritic laminites at burial depths ranging from centimetres to kilometres. This set of diagenetic brine‐focusing mechanisms are active today beneath the floor of the Atlantis II Deep and are thought to have their ancient counterparts in some Proterozoic sedex deposits. The position of the allochthon, its lateral continuity, and the type of sediment it overlies controls the size of the accumulation and whether it is Cu or Pb–Zn dominated.     

Significance of pteropods in deciphering the late Quaternary sea-level history along the southwestern Indian shelf

The paper evaluates the usefulness of pteropods in palaeobathymetric synthesis along the southwestern continental shelf of India. Core samples collected from the shelf off north Kerala (SW coast of India) were studied for faunal assemblages (pteropods and foraminifers), calcium carbonate contents and lithological characteristics. A fundamental precept for considering any organism as a bathometer is that it should be highly sensitive to changing water depths. To ascertain this, the bathymetric distribution patterns of modern pteropods as well as planktonic and benthic foraminifers were recorded in core-top samples. The results reveal that certain pteropod species (Limacina inflata, Creseis acicula, Creseis virgula, and Creseis chierchiae) are highly depth sensitive. The response of these species to depth changes was assessed in terms of the L. inflata and Creseis spp. abundance ratio. A model for the relationship between water depths and the L. inflata/Creseis spp. ratio is proposed for the southwestern shelf of India. Variations of benthic/planktonic foraminifers (BF/PF) and pteropods/planktonic foraminifers (Pt/PF) in the modern sediments were also found to be depth controlled. Two sediment cores, representing the last 36,000 and 23,000 years, were collected to investigate past sea-level changes. These cores comprised two distinct lithological units, the upper unit corresponding to the Holocene, and the lower unit to the last glacial period. The L. inflata/Creseis spp. model was successfully applied to the fossil record for reconstructing the palaeobathymetry of the shelf study locations. Down-core variations in the BF/PF and Pt/PF ratios support these inferred sea-level changes. Major periods of sea-level oscillations were also found to have a strong influence on the calcium carbonate distribution. For both core sites, the palaeobathymetric curves reflect consistency in terms of changing sea level. The results suggest that the sea level stood around 100 m below the present mean sea level during the last glacial maximum. A rapid rise in sea level was documented between 15 and 10 ka B.P. The sea-level rise has been slower since 7 ka B.P.     

Some statistical methods of the objective classification of oceanographic data

Algorithms for the compression and objective classification of low-volume samplings according to the test of their belonging to different statistical populations are given. Samplings are discriminated by thex ² test. The distributions of the temperature patch horizontal scales in the upper ocean are analysed. It is shown that optimum empirical thresholds exist when the abstract classification mechanism goes over to the objective natural classification.Translated by Mikhail M. Trufanov.     

Travertine formation in Plitvice National Park, Yugoslavia: chemical versus biological control

Hydrochemical studies of the Plitvice Lakes and their tributaries (Croatia/Yugoslavia) were coupled with micromorphological investigations on carbonate lake sediments and recent travertines. Karst springs discharge water from aquifers in Triassic and Jurassic dolomites and limestones and collect in lakes, which are ponded behind accreting travertine dams. Waters at springs have a high CO₂ partial-pressure (greater than 7000 ppm) and are slightly undersaturated with respect to calcite (saturation index less than —0·03). CO₂ partial pressure is quickly reduced in swift running streams, leading to very high supersaturation with carbonate minerals (saturation indices between 0·74 and 0·53). Calcite deposition, however, is restricted to the lake bottoms (formation of lake marl) and to the tufa dams. The annual carbonate precipitating capacity of the system based on water balance and downstream loss of dissolved ions is estimated to be on the order of 10 000 t CaCO₃ as cascade deposits (tufa dams) or as micrite in lakes behind the travertine dams. The initial stages of travertine formation as a result of morphological, biological, and chemical factors are (i) moss settling on small ridges in the creek courses, (ii) epiphytes (diatoms and cyanobacteria) settling on the moss surface, (iii) micrite particles resuspending from lake bottoms and being trapped on mucous excretions from bacteria and diatoms, and (iv) inorganic calcite precipitating as sparite at nucleation sites provided by these crystal seeds. Geochemical studies of the lake marl and tufa dams show that amino acids are dominated by aspartic acid. Carbohydrates come from structural polysaccharides of diatoms. The sticky excretions, rich in aspartic acid, are necessary for the initiation of calcite precipitation. They may be a response of algal and bacterial metabolism to environmental stress by either nutrient depletion or high calcium concentrations in ambient waters. The formation of tufa and micrite (lake marl) appears to be initiated by localized biological factors and is not governed by mere calcite supersaturation of the water. Oligotrophy may be an essential precondition for the formation of fresh water carbonate deposits.     

Petrology and Geochemistry of Post-Collisional Early Miocene Volcanism in the Karacada? Area (Central Anatolia, Turkey)

Early Miocene (ca.?21–18 Ma) volcanism in the Karacada? area comprises three groups of volcanic rocks: (1) calcalkaline suite (andesitic to rhyolitic lavas and their pyroclastics), (2) mildly-alkaline suite (alkali basalt, hawaiite, mugearite, benmoreite and trachydacite), and (3) a single trachyandesitic flow unit. Field observations, 40Ar/39Ar ages and geochemical data show that there was a progressive temporal transition from group 1 to 3 in a post-collisional tectonic setting. The calcalkaline suite rocks with medium-K in composition resemble those of subduction-related lavas, whereas the mildly-alkaline suite rocks having a sodic tendency (Na2O/K2O=1.5–3.2) resemble those of within-plate lavas. Incompatible element and Sr-Nd isotopic characteristics of the suites suggest that the lithospheric mantle beneath the Karacada? area was heterogeneously enriched by two processes before collision: (1) enrichment by subduction-related processes, which is important in the genesis of the calcalkaline volcanism, (2) enrichment by small degree melts from the astenosphere, which dominates the mildly alkaline volcanism. Perturbation of the enriched lithosphere by either delamination following collision and uplift or removal of the subducted slab following subduction and collision (i.e., slab breakoff) is the likely mechanism for the initiation of the post-collision volcanism.     

The future of large format HgCdTe arrays for astronomy

Rockwell has developed the 256×256 NICMOS3 FPA for the Hubble Space Telescope under funding from NASA through the University of Arizona. Since 1989, dozens of science grade devices have been delivered to astronomers throughout the world for ground based infrared observations. These devices have excellent sensitivity at 77K with mean dark currents of 0.1 e-/s, noise of 25 e-, and quantum efficiency of 55–70%. Pixel yields as high as 99.9% have been achieved. Our present plans are to develop a 1024×1024 FPA with 2.5 micron cutoff and make it available to astronomers. Such large arrays are made possible by the advances in detector material size (3 in. diameter PACE-I wafers), multiplexer advances (ability to verify the design in detail and availability of advanced foundries), and novel hybridization and reliability approaches.     

Role of satellite remote sensing for monitoring of surface water resources in an arid environment

Abstract

Water bodies up to 0.9 ha surface area, which are indistinguishable by Landsat Multispectral Scanner (MSS) due to the latter's poor spatial resolution of 80 m, can be identified and mapped reliably and reasonably within ±10% accuracy by Landsat Thematic Mapper (TM) false colour composite because of its higher spectral and spatial resolution of 30 m. Comparative study of Landsat TM and the Survey of India topographical maps revealed reductions in the water surface and drainage basin areas up to 1.8 to 2.4 and 6.0 to 8.0 times, respectively, over a period of 28 years (1958–1986) due to the biotic interference resulting in desertification in the large adjoining areas.     

Collisional heating of interplanetary gas: Fokker-Planck treatment

Interstellar gas streaming through the solar system undergoes both elastic collisions with solar wind ions and destructive, ionizing processes. The Boltzmann equation is set up, with linear Fokker-Planck terms describing the glancing elastic collisions. Solutions combining the dynamical effects of the central force field and the diffusion in velocity space are derived, appropriate to cool gas.For the He component of the streaming gas, if initially at 100 K, the collisional heating dominates inside 2 a.u. upstream and 5 a.u. downstream. A modified formula is given for the density in the downstream wake, as enhanced by gravitational focussing. Calculations of the helium resonant radiation backscatter require substantial modification.     

List of forthcoming papers

List of forthcoming papers