An Inter-Laboratory Assessment of the Thorium Isotopic Composition of Synthetic and Rock Reference Materials

We present a concerted international effort to cross-calibrate five synthetic Th isotope reference materials (UCSC Th "A", OU Th "U", WUN, IRMM-35 and IRMM-36), and six rock reference materials (UCSC TML, Icelandic ATHO, USGS BCR-2, USGS W-2, USGS BHVO-2, LV18) using multi-collector inductively coupled plasma-mass spectrometry (MC-ICP-MS). We then compare our new values with a compilation of literature mass spectrometric data for these reference materials and derive recommended "consensus"²³⁰Th/²³²Th values for each. We also present isotope dilution U and Th concentration data for four rock reference materials (UCSC TML, Icelandic ATHO, USGS BCR-2, USGS W-2).     

Basic hydrology,limnology, and meteorology of modern Lake El’gygytgyn,Siberia

A survey of the modern physical setting of Lake El’gygytgyn, northeastern Siberia, is presented here to facilitate interpretation of a 250,000-year climate record derived from sediment cores from the lake bottom. The lake lies inside a meteorite impact crater that is approximately 18 km in diameter, with a total watershed area of 293 km², 110 km² of which is lake surface. The only surface water entering the lake comes from the approximately 50 streams draining from within the crater rim; a numbering system for these inlet streams is adopted to facilitate scientific discussion. We created a digital elevation model for the watershed and used it to create hypsometries, channel networks, and drainage area statistics for each of the inlet streams. Many of the streams enter shallow lagoons dammed by gravel berms at the lakeshore; these lagoons may play a significant role in the thermal and biological dynamics of the lake due to their higher water temperatures (>6°C). The lake itself is approximately 12 km wide and 175 m deep, with a volume of 14.1 km³. Water temperature within a column of water near the center of this oligotrophic, monomictic lake never exceeded 4°C over a 2.5 year record, though the shallow shelves (<10 m) surrounding the lake can reach 5°C in summer. Though thermally stratified in winter, the water appears completely mixed shortly after lake ice breakup in July. Mean annual air temperature measured about 200 m from the lake was −10.3°C in 2002, and an unshielded rain gage there recorded 70 mm of rain in summer of 2002. End of winter snow water equivalent on the lake was approximately 110 mm in May 2002. Analysis of NCEP reanalysis air temperatures (1948–2002) reveals that the 8 warmest years and 10 warmest winters have occurred since 1989, with the number of days below −30°C dropping from a pre-1989 mean of 35 to near 0 in recent years. The crater region is windy as well as cold, with hourly wind speeds exceeding 13.4 m s⁻¹ (30 mph) typically at least once each month and 17.8 m s⁻¹ (40 mph) in winter months, with only a few calm days per month; wind may also play an important role in controlling the modern shape of the lake. Numerous lines of evidence suggest that the physical hydrology and limnology of the lake has changed substantially over the past 3.6 million years, and some of the implications of these changes on paleoclimate reconstructions are discussed. This is the second in a series of eleven papers published in this special issue dedicated to initial studies of El'gygytgyn Crater Lake and its catchment in NE Russia. Julie Brigham-Grette, Martin Melles, Pavel Minyuk were guest editors of this special issue.     

An accurate momentum advection scheme for a z-level coordinate models

In this paper, we focus on a conservative momentum advection discretisation in the presence of z-layers. While in the 2D case conservation of momentum is achieved automatically for an Eulerian advection scheme, special attention is required in the multi-layer case. We show here that an artificial vertical structure of the flow can be introduced solely by the presence of the z-layers, which we refer to as the staircase problem. To avoid this staircase problem, the z-layers have to be remapped in a specific way. The remapping procedure also deals with the case of an uneven number of layers adjacent to a column side, thus allowing one to simulate flooding and drying phenomena in a 3D model.     

Potential impacts of climate change on storage conditions for commercial agriculture: an example for potato production in Michigan

Climate change is anticipated to influence all parts of agricultural production systems. However, the potential impacts on crop storage have rarely been assessed, even though storage is an important component of a grower’s marketing strategy and is essential for the continuous supply of a commodity for processors, exporters, and consumers. The Michigan chip-processing potato industry provides an example of the importance of crop storage. Michigan is the largest producer of chip-processing potatoes in the USA, and potatoes are stored on farms from September to June. We use an ensemble of climate projections developed for three future time slices (early, mid, and late century) from 16 climate models forced by three greenhouse gas concentration pathways to assess future changes in potato storage conditions. Our findings indicate an increased future demand for ventilation and/or refrigeration immediately after harvest and again in spring and early summer, even for the early-century time slice. Furthermore, the period of reliably cold storage temperatures during winter is anticipated, when averaged across all models, to shorten by 11–17 days in Michigan’s primary production area and 14–20 days in the more southern secondary area by mid-century, and by 15–29 days and 31–35 days, respectively, for the northern and southern production areas by late century. The level of uncertainty, as indicated by the ensemble range, is large, although the sign of the projected changes in storage parameters is consistent. This case study provides an example of the potentially large effects of climate change on the storage conditions for agricultural commodities.     

Going to the Extremes

Projections of changes in climate extremes are critical to assessing the potential impacts of climate change on human and natural systems. Modeling advances now provide the opportunity of utilizing global general circulation models (GCMs) for projections of extreme temperature and precipitation indicators. We analyze historical and future simulations of ten such indicators as derived from an ensemble of 9 GCMs contributing to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change (IPCC-AR4), under a range of emissions scenarios. Our focus is on the consensus from the GCM ensemble, in terms of direction and significance of the changes, at the global average and geographical scale. The climate extremes described by the ten indices range from heat-wave frequency to frost-day occurrence, from dry-spell length to heavy rainfall amounts. Historical trends generally agree with previous observational studies, providing a basic sense of reliability for the GCM simulations. Individual model projections for the 21st century across the three scenarios examined are in agreement in showing greater temperature extremes consistent with a warmer climate. For any specific temperature index, minor differences appear in the spatial distribution of the changes across models and across scenarios, while substantial differences appear in the relative magnitude of the trends under different emissions rates. Depictions of a wetter world and greater precipitation intensity emerge unequivocally in the global averages of most of the precipitation indices. However, consensus and significance are less strong when regional patterns are considered. This analysis provides a first overview of projected changes in climate extremes from the IPCC-AR4 model ensemble, and has significant implications with regard to climate projections for impact assessments. An erratum to this article is available at . An erratum to this article can be found at     

The response of phytoplankton to iron enrichment in Sub-Antarctic HNLCLSi waters: Results from the SAGE experiment

Areas of high nutrients and low chlorophyll a comprise nearly a third of the world’s oceans, including the equatorial Pacific, the Southern Ocean and the Sub-Arctic Pacific. The SOLAS Sea-Air Gas Exchange (SAGE) experiment was conducted in late summer, 2004, off the east coast of the South Island of New Zealand. The objective was to assess the response of phytoplankton in waters with low iron and silicic acid concentrations to iron enrichment. We monitored the quantum yield of photochemistry (F_v/F_m) with pulse amplitude modulated fluorometry, chlorophyll a, primary productivity, and taxonomic composition. Measurements of F_v/F_m indicated that the phytoplankton within the amended patch were relieved from iron stress (F_v/F_m approached 0.65). Although there was no significant difference between IN and OUT stations at points during the experiment, the eventual enhancement in chlorophyll a and primary productivity was twofold by the end of the 15-day patch occupation. However, no change in particulate carbon or nitrogen pools was detected. Enhancement in primary productivity and chlorophyll a were approximately equal for all phytoplankton size classes, resulting in a stable phytoplankton size distribution. Initial seed stocks of diatoms were extremely low, <1% of the assemblage based on HPLC pigment analysis, and did not respond to iron enrichment. The most dominant groups before and after iron enrichment were type 8 haptophytes and prasinophytes that were associated with ∼75% of chlorophyll a. Twofold enhancement of biomass estimated by flow cytometry was detected only in eukaryotic picoplankton, likely prasinophytes, type 8 haptophytes and/or pelagophytes. These results suggest that factors other than iron, such as silicic acid, light or physical disturbance limited the phytoplankton assemblage during the SAGE experiment. Furthermore, these results suggest that additional iron supply to the Sub-Antarctic under similar seasonal conditions and seed stock will most likely favor phytoplankton <2 ??m. This implies that any iron-mediated gain of fixed carbon will most likely be remineralized in shallow water rather than sink and be sequestered in the deep ocean.     

Using additional roughness to characterize erosion control treatment effectiveness in roadside ditch lines

Forest roadside ditch lines capture and redirect road runoff and typically have erosion control treatments installed therein. Existing methods used to determine the effectiveness of roadside ditch line erosion control treatments estimate fixed fractional reductions in sediment yield. However, fixed fractional reductions do not describe dependence on any measurable physical property of treatment, climate, and the environment. Here, we use additional flow roughness induced by erosion control treatments as a metric that can be used as the basis of estimating treatment effectiveness in varying contexts. We investigate its utility in small-scale field experiments in western Washington. We measured the physical characteristics of each ditch (e.g., shape, soil texture, and slope) and flow velocities and sediment concentrations for each treatment under multiple experimental discharges. We then used the concept of shear stress partitioning to relate sediment yield from the ditch line erosion treatments to grain shear stress, which is a function of flow roughness (Manning's n) of the respective treatment. We found that (1) a given erosion control treatment produced consistent Manning's n values across multiple replications and sites, with a bare ditch (no treatment) yielding the lowest roughness (n = 0.05) and a densely wattled ditch yielding the highest roughness (n = 0.75); (2) sediment load and calculated grain shear stress data yielded a single positive relationship when data from each experiment were combined, which suggests the effect of additional roughness on grain shear stress is a main driver in the reduction of ditch line sediment load; and (3) in our dataset, fractional erosion reduction had a variable and nonlinear sensitivity to low flow rates (99% of observed flows) for lower roughnesses. Our results demonstrate how additional flow roughness can be used as a general metric to help evaluate the effectiveness of ditch line erosion control treatments for a variety of physical conditions.     

The tectono-sedimentary evolution of a hyper-extended rift basin: the example of the Arzacq–Mauléon rift system (Western Pyrenees,SW France)

In this paper, we present a sedimentary and structural analysis that together with maps, sections and new Ar/Ar data enable to describe the tectono-sedimentary evolution of the Mauléon hyper-extended rift basin exposed in the W-Pyrenees. Hyper-extension processes that ultimately resulted in exhuming mantle rocks are the result of the subsequent development of two diachronous detachment systems related to two evolutional stages of rifting. An initial Late Aptian Early Albian crustal thinning phase is first recorded by the development of a crustal necking zone controlled by the north-vergent Southern Mauléon Detachment system. During a subsequent exhumation phase, active faulting migrates to the north with the emplacement of the Northern Mauléon detachment system that exhumed north section thinned continental crust and mantle rocks. This diachronous crustal thinning and exhumation processes are also recorded by the diachronous deposition of syn-tectonic sedimentary tracts above the two supra-detachment sub-basins. Syn-tectonic sedimentary tracts record the progressive exhumation of footwall rocks along detachment systems. Tectonic migration from the southern to the northern Mauléon Detachment system is recorded by the coeval deposition of “sag” deposits above the necking zone basin and of syn-tectonic tracts above exhumed rocks north section. Located on a hanging-wall situation related to the Mauléon hyper-extension structures, the Arzacq Basin also records a major crustal thinning phase as shown by its subsidence evolution so as by deep seismic images. The absence of major top-basement structures and its overall sag morphology suggest that crustal thinning processes occurred by decoupled extension of lower crustal levels contrasting with the Southern Mauléon Detachment system. Reconciling observations from the Mauléon and Arzacq Basins, we finally propose in this paper that they were the result of one and the same asymmetric crustal thinning and exhumation processes, where extension is accommodated into the upper crust in the Mauléon Basin (lower plate basin) and relayed in ductile lower crust below the Arzacq Basin (upper plate basin).