Hydrogeochemical characteristics of central Jianghan Plain, China

The central Jianghan Plain is the semi-closed basin in the middle reaches of Yangtze River. A total of 78 water samples targeting groundwater were collected from 75 sites in this study site, the area between Yangtze River and Han River, including rivers and lakes for temperature, pH, electrical conductivity (EC), total dissolved solids (TDS) and ion composition measurements. Correlation matrix was used to assess the geochemical and anthropogenic processes. The most confined groundwater was grouped into HCO₃–Ca–Mg, while phreatic groundwater and surface water had a more diversified hydrochemistry. The spatial variation in overall water quality as well as comparison with WHO (World Health Organization) standards for drinking water is illustrated. Mn, As and NO₃ ^? concentrations were found to exceed the allowable limits for drinking water of WHO guidelines, and they also show remarkable spatial variations. Abnormally high nitrate concentration, up to 150–190 mg/l, was found only in phreatic groundwater, which suggested that the nitrate pollution might be caused by agricultural activities. The present study may be helpful in further studies concerning water quality issues in this area where groundwater is a vital source for drinking and other activities.     

Simulation of the 1980 eruption of Mount St. Helens using the ash-tracking model PUFF

The dispersal of volcanic ash from the May 18, 1980 eruption of Mount St. Helens (MSH) has been simulated using the Lagrangian ash-tracking model PUFF. Previous applications of the model were limited to smaller, short-lived eruptions with ash dispersal occurring mainly within the troposphere. Two high-resolution atmospheric reanalysis datasets (ERA-40 and NCEP/NCAR-40) allowed MSH ash cloud dispersal to be simulated up to 30 km elevation. The 1980 eruption was divided into two distinct eruptive phases, (1) an initial, relatively short-lived blast/surge phase that injected ash up to 30 km and (2) a subsequent nine-hour plinian phase that maintained an average eruption column height of 16 km. Using PUFF, the two phases of the MSH eruption were modeled separately based on a range of individual input parameters and then combined to produce an integrated simulation of the entire eruption. The trajectory and areal extent of the modeled atmospheric ash cloud best match the actual distribution of MSH ash when input parameters are set to values inferred from satellite and radar data collected on May 18, 1980. The prevailing wind field exerts the strongest control on the advection and ultimate position of the modeled ash cloud, making the maximum column height and the vertical distribution of ash the most sensitive of the PUFF input parameters for this event. The results indicate that the PUFF model works well at simulating the dispersal of ash injected well into the lower stratosphere from a moderate, relatively long-lived eruption, such as MSH. However, attempts to use PUFF to recreate some granulometric aspects of the MSH fallout deposit, such as the maximum particle size as a function of distance from source, were not successful. PUFF consistently predicts much greater fallout distances for small ash particles (< 500 µm) than actually observed in the MSH deposit. The effective settling velocities used by the PUFF model appear to be too slow to accurately predict fallout distances of small ash particles. As a consequence the PUFF model may overestimate the duration of ash loading in the atmosphere associated with the distal fine ash component of explosive eruptions.     

Hydrochemical behaviour of dissolved nitrogen and carbon in a headwater stream of the Canadian Shield: relevance of antecedent soil moisture conditions

This paper examines the impact of contrasting antecedent soil moisture conditions on the hydrochemical response, here the changes in dissolved nitrogen (NO₃^?, NH₄⁺ and dissolved organic nitrogen (DON)) and dissolved organic carbon (DOC) concentrations, of a first‐order stream during hydrological events. The study was performed in the Hermine, a 5 ha forested watershed of the Canadian Shield. It focused on a series of eight precipitation events (spring, summer and fall) sampled every 2 or 3 h and showing contrasted antecedent moisture conditions. The partition of the eight events between two groups (dry or wet) of antecedent moisture conditions was conducted using a principal component analysis (PCA). The partition was controlled (first axis explained 86% of the variability) by the antecedent streamflow, the streamflow to precipitation ratio Q/P and by the antecedent groundwater depth. The mean H⁺, NO₃^?, NH₄⁺, total dissolved nitrogen and DOC concentrations and electrical conductivity values in the stream were significantly higher following dry antecedent conditions than after wetter conditions had prevailed in the Hermine, although the temporal variability was high (17 to 138%). At the event scale, a significantly higher proportion of the changes in DON, NO₃^?, and DOC concentrations in the stream was explained by temporal variations in discharge compared with the seasonal and annual scales. Two of the key hydrochemical features of the dry events were the synchronous changes in DOC and flow and the frequent negative relationships between discharge and NO₃^?. The DON concentrations were much less responsive than DOC to changes in discharge, whereas NH was not in phase with streamflow. During wet events, the synchronicity between streamflow and DON or NO₃^? was higher than during dry events and discharge and NO₃^? were generally positively linked. Based on these observations, the hydrological behaviour of the Hermine is conceptually compatible with a two‐component model of shallow (DON and DOC rich; variable NO₃^?) and deep (DON and DOC poor; variable NO₃^?) subsurface flow. The high NO₃^? and DOC levels measured at the early stages of dry events reflected the contribution from NO₃^?‐rich groundwaters. The contribution of rapid surface flow on water‐repellent soil materials located close to the stream channel is hypothesized to explain the DOC levels. An understanding of the complex interactions between antecedent soil moisture conditions, the presence of soil nutrients available for leaching and the dynamics of soil water flow paths during storms is essential to explain the fluxes of dissolved nitrogen and carbon in streams of forested watersheds. Copyright © 2007 John Wiley & Sons, Ltd.     

On harbour siltation in the fresh-salt water mixing region

In this paper a novel series of field measurements are presented, which are the first to elucidate the processes influencing siltation in Botlek Harbour. Botlek Harbour is situated at the limit of saline water intrusion in the Rotterdam Waterway. Normally, after the ebb tide fresher river waters are found in the Rotterdam Waterway at the location of Botlek Harbour. On the flooding tide, the tip of the salt wedge is advected along the Rotterdam Waterway towards the mouth of Botlek Harbour. Hence on flood, a lock-exchange mechanism operates between Botlek Harbour and the Rotterdam Waterway. On the flood tide, when there is a supply of suspended particulate matter (SPM) associated with the presence of the estuarine turbidity maximum (ETM) at the mouth of the harbour, the survey data show exchange of SPM into the harbour. This lock-exchange process is found to be the dominant cause for SPM transport into the harbour. This is further substantiated by an analysis of the mass transport mechanisms. In this analysis, the vertical profiles of the instantaneous velocity, salinity and SPM concentration fields, recorded during the surveys, were decomposed into advective and dispersive transport components. The results of this analysis indicate that the correlation between the lock-exchange mechanism on the flood tide with the availability of SPM for exchange and efficient trapping, dominate the total exchange of SPM (97%). Hence, the increase in measured near-bed SPM concentration within the harbour is ascribed to tidal advection of saline water and the ETM along the Rotterdam Waterway. Tidal advection controls the density difference between the estuary and harbour, as well as the availability of SPM for exchange at the entrance to Botlek Harbour. The location of the ETM at the tip of the salt wedge is a key factor in supplying SPM to Botlek Harbour. Consequently the timing of the availability of SPM at the mouth of the harbour needs to be considered in siltation studies. The survey data suggest that Botlek Harbour basin has a 100% trapping efficiency. Analysis of 5 months of data, from a measuring rig located within the harbour, show excursions of the limit of the salt wedge and ETM. These excursions are likely to affect siltation of upstream harbours. Salinity-induced density gradients control the transport and subsequent trapping of SPM in the estuary in close proximity to the harbour entrance, the exchange of SPM between the estuary and harbour, and the trapping of SPM in the harbour basin.     

Engagement in the Third U.S. National Climate Assessment: commitment,capacity, and communication for impact

This paper examines the dynamics of energy investments and clean energy Research and Development (R&D) using a scenario-based modeling approach. Starting from the global scenarios proposed in the RoSE model ensemble experiment, we analyze the dynamics of investments under different assumptions regarding economic and population growth as well as availability of fossil fuel resources, in the absence of a climate policy. Our analysis indicates that economic growth and the speed of income convergence across countries matters for improvements in energy efficiency, both via dedicated R&D investments but mostly through capital-energy substitution. In contrast, fossil fuel prices, by changing the relative competitiveness of energy sources, create an economic opportunity for radical innovation in the energy sector. Indeed, our results suggest that fossil fuel availability is the key driver of investments in low carbon energy innovation. However, this innovation, by itself, is not sufficient to induce emission reductions compatible with climate stabilization objectives.     

Composition and petrology of HED polymict breccias: The regolith of (4) Vesta

We have done petrologic and compositional studies on a suite of polymict eucrites and howardites to better understand regolith processes on their parent asteroid, which we accept is (4) Vesta. Taking into account noble gas results from companion studies, we interpret five howardites to represent breccias assembled from the true regolith: Elephant Moraine (EET) 87513, Grosvenor Mountains (GRO) 95535, GRO 95602, Lewis Cliff (LEW) 85313, and Meteorite Hills (MET) 00423. We suggest that EET 87503 is paired with EET 87513, and thus is also regolithic. Pecora Escarpment (PCA) 02066 is dominated by melt‐matrix clasts, which may have been formed from true regolith by impact melting. These meteorites display a range in eucrite:diogenite mixing ratio from 55:45 to 76:24. There is no correlation between degree of regolith character and Ni content. The Ni contents of howardite, eucrite, and diogenites (HEDs) are mostly controlled by the distribution of coarse chondritic clasts and metal grains, which in some cases resulted from individual, low‐velocity accretion events, rather than extensive regolith gardening. Trace element compositions indicate that the mafic component of HED polymict breccias is mostly basalt similar to main‐group eucrites; Stannern‐trend basaltic debris is less common. Pyroxene compositions show that some trace element‐rich howardites contain abundant debris from evolved basalts, and that cumulate gabbro debris is present in some breccias. The scale of heterogeneity varies considerably; regolithic howardite EET 87513 is more homogeneous than fragmental howardite Queen Alexandra Range (QUE) 97001. Individual samples of a given howardite can have different compositions even at roughly 5 g masses, indicating that obtaining representative meteorite compositions requires multiple or large samples.     

Magmatic processes that generated the rhyolite of Glass Mountain, Medicine Lake volcano, N. California

Glass Mountain consists of a 1 km³, compositionally zoned rhyolite to dacite glass flow containing magmatic inclusions and xenoliths of underlying shallow crust. Mixing of magmas produced by fractional crystallization of andesite and crustal melting generated the rhyolite of Glass Mountain. Melting experiments were carried out on basaltic andesite and andesite magmatic inclusions at 100, 150 and 200 MPa, H₂O-saturated with oxygen fugacity controlled at the nickel-nickel oxide buffer to provide evidence of the role of fractional crystallization in the origin of the rhyolite of Glass Mountain. Isotopic evidence indicates that the crustal component assimilated at Glass Mountain constitutes at least 55 to 60% of the mass of erupted rhyolite. A large volume of mafic andesite (2 to 2.5 km³) periodically replenished the magma reservoir(s) beneath Glass Mountain, underwent extensive fractional crystallization and provided the heat necessary to melt the crust. The crystalline residues of fractionation as well as residual liquids expelled from the cumulate residues are preserved as magmatic inclusions and indicate that this fractionation process occurred at two distinct depths. The presence and composition of amphibole in magmatic inclusions preserve evidence for crystallization of the andesite at pressures of at least 200 MPa (6 km depth) under near H₂O-saturated conditions. Mineralogical evidence preserved in olivine-plagioclase and olivine-plagioclase-high-Ca clinopyroxene-bearing magmatic inclusions indicates that crystallization under near H₂O-saturated conditions also occurred at pressures of 100 MPa (3 km depth) or less. Petrologic, isotopic and geochemical evidence indicate that the andesite underwent fractional crystallization to form the differentiated melts but had no chemical interaction with the melted crustal component. Heat released by the fractionation process was responsible for heating and melting the crust. Received: 26 March 1996 / Accepted: 14 November 1996     

Long-term evolution of the aerosol debris cloud produced by the 2009 impact on Jupiter

We present a study of the long-term evolution of the cloud of aerosols produced in the atmosphere of Jupiter by the impact of an object on 19 July 2009 (Sánchez-Lavega, A. et al. [2010]. Astrophys. J. 715, L155-L159). The work is based on images obtained during 5 months from the impact to 31 December 2009 taken in visible continuum wavelengths and from 20 July 2009 to 28 May 2010 taken in near-infrared deep hydrogen-methane absorption bands at 2.1-2.3 μm. The impact cloud expanded zonally from ∼5000 km (July 19) to 225,000 km (29 October, about 180° in longitude), remaining meridionally localized within a latitude band from 53.5°S to 61.5°S planetographic latitude. During the first two months after its formation the site showed heterogeneous structure with 500-1000 km sized embedded spots. Later the reflectivity of the debris field became more homogeneous due to clump mergers. The cloud was mainly dispersed in longitude by the dominant zonal winds and their meridional shear, during the initial stages, localized motions may have been induced by thermal perturbation caused by the impact’s energy deposition. The tracking of individual spots within the impact cloud shows that the westward jet at 56.5°S latitude increases its eastward velocity with altitude above the tropopause by 5-10 m s⁻¹. The corresponding vertical wind shear is low, about 1 m s⁻¹ per scale height in agreement with previous thermal wind estimations. We found evidence for discrete localized meridional motions with speeds of 1-2 m s⁻¹. Two numerical models are used to simulate the observed cloud dispersion. One is a pure advection of the aerosols by the winds and their shears. The other uses the EPIC code, a nonlinear calculation of the evolution of the potential vorticity field generated by a heat pulse that simulates the impact. Both models reproduce the observed global structure of the cloud and the dominant zonal dispersion of the aerosols, but not the details of the cloud morphology. The reflectivity of the impact cloud decreased exponentially with a characteristic timescale of 15 days; we can explain this behavior with a radiative transfer model of the cloud optical depth coupled to an advection model of the cloud dispersion by the wind shears. The expected sedimentation time in the stratosphere (altitude levels 5-100 mbar) for the small aerosol particles forming the cloud is 45-200 days, thus aerosols were removed vertically over the long term following their zonal dispersion. No evidence of the cloud was detected 10 months after the impact.     

Australian ‘gayborhoods’ and ‘lesborhoods’: a new method for estimating the number and prevalence of adult gay men and lesbian women living in each Australian postcode

ABSTRACT

Gay men and lesbian women often demonstrate unique settlement patterns, forming what have been referred to as ‘gayborhoods’. This study sought to provide the first postcode-level estimates of population size and prevalence of gay and lesbian people in Australia. Data on same-gender-partnered households from the Australian Census were combined with information from six different surveys conducted from 2011 to 2017. We estimated that in 2016 there were 132,203 gay men (1.5% of adult males; 95% CI: 1.4–1.6) and 79,931 lesbian women (0.9% of adult females; 95% CI: 0.8–1.0) in Australia. While many postcodes were sparsely populated by gay and lesbian people (40.1% had prevalences of <0.1%), 24.6% were moderately populated (prevalences in the 50-95th percentile) and 2.7% were highly populated (95th percentile). By jurisdiction, the Australian Capital Territory had the highest prevalences of gay men (2.1%; 95% CI: 2.0–2.2) and lesbian women (1.5%; 95% CI: 1.4–1.6). Although the majority of highly populated postcodes were found in major cities (83.7%), some were also found in regional and remote area (16.3%). This method can be applied in other countries to enhance populate estimates. The accompanying dataset can be used to guide service delivery, conduct geographically contextualised research and develop policies relevant to gay men and lesbian women in Australia.     

The danger of overvaluing methane’s influence on future climate change

Minimizing the future impacts of climate change requires reducing the greenhouse gas (GHG) load in the atmosphere. Anthropogenic emissions include many types of GHG’s as well as particulates such as black carbon and sulfate aerosols, each of which has a different effect on the atmosphere, and a different atmospheric lifetime. Several recent studies have advocated for the importance of short timescales when comparing the climate impact of different climate pollutants, placing a high relative value on short-lived pollutants, such as methane (CH₄) and black carbon (BC) versus carbon dioxide (CO₂). These studies have generated confusion over how to value changes in temperature that occur over short versus long timescales. We show the temperature changes that result from exchanging CO₂ for CH₄ using a variety of commonly suggested metrics to illustrate the trade-offs involved in potential carbon trading mechanisms that place a high value on CH₄ emissions. Reducing CH₄ emissions today would lead to a climate cooling of approximately ~0.5 °C, but this value will not change greatly if we delay reducing CH₄ emissions by years or decades. This is not true for CO₂, for which the climate is influenced by cumulative emissions. Any delay in reducing CO₂ emissions is likely to lead to higher cumulative emissions, and more warming. The exact warming resulting from this delay depends on the trajectory of future CO₂ emissions but using one business-as usual-projection we estimate an increase of 3/4 °C for every 15-year delay in CO₂ mitigation. Overvaluing the influence of CH₄ emissions on climate could easily result in our “locking” the earth into a warmer temperature trajectory, one that is temporarily masked by the short-term cooling effects of the CH₄ reductions, but then persists for many generations.