Effect of chlorine on near‐liquidus crystallization of olivine‐phyric shergottite NWA 6234 at 1 GPa: Implication for volatile‐induced melting of the Martian mantle

Martian magmas are thought to be rich in chlorine compared with their terrestrial counterparts. Here, we experimentally investigate the effect of chlorine on liquidus depression and near‐liquidus crystallization of olivine‐phyric shergottite NWA 6234 and compare these results with previous experimental results on the effect of chlorine on near‐liquidus crystallization of the surface basalts Humphrey and Fastball. Previous experimental results showed that the change in liquidus temperature is dependent on the bulk composition of the basalt. The effect of chlorine on liquidus depression is greater for lower SiO₂ and higher Al₂O₃ magmas than for higher SiO₂ and lower Al₂O₃ magmas. The bulk composition for this study has lower Al₂O₃ and higher FeO contents than previous work; therefore, we provide additional constraints on the effect of the bulk composition on the influence of chlorine on near‐liquidus crystallization. High pressure and temperature crystallization experiments were performed at 1 GPa on a synthetic basalt, of the bulk composition of NWA 6234, with 0–4 wt% Cl added to the sample as AgCl. The results are consistent with previous notions that with increasing wt% Cl in the melt, the crystallization temperature decreases. Importantly, our results have a liquidus depression ?T (°C) from added chlorine that is consistent with the difference in bulk composition and suggest a dependence on both the bulk Al₂O₃ and FeO content. Our results suggest that the addition of chlorine to the Martian mantle may lower magma genesis temperatures and potentially aid in the petrogenesis of Martian magmas.     

On the Parametrization of Urban Land Use in Mesoscale Models

The effects of urban structures on the distribution of meteorological variables can be included in mesoscale models by an appropriate parametrization. The different approaches are conventionally tested against wind profiles in the centre of the urban area while flow distortions around are not considered. In this study, the quality of different parametrizations in capturing the main wind-field modifications in, as well as around, a complex obstacle is investigated. The method applied consists of a building resolved microscale model and a mesoscale model including a suitable parametrization. The results demonstrate that a drag or a porosity approach can reproduce very satisfactorily the main characteristics of the airflow completely, while a simpler roughness length concept in general approximates the mean flow unsatisfactorily.     

Alignment of stone‐pavement clasts by unconcentrated overland flow – implications of numerical and physical modelling

The crucial role of stone pavements in arid environments for aeolian or alluvial processes and as numerical dating tools is increasingly acknowledged. This role is based on the assumption that stone pavements are stable landforms, formed gradually over time and predominantly by vertical processes. However, this is challenged by evidence of stone‐pavement clast reworking or burial. Bimodal, mostly slope aspect‐symmetrical clast orientation is a frequent phenomenon in various study areas. It implies that stone pavements may be influenced by unidirectional lateral processes besides vertical ones. Here, the finding of lateral processes contributing to stone‐pavement evolution is supported by numerical modelling and physical experiments. These unequivocally show that unconcentrated overland flow can transport clasts to form a closely packed stone mosaic with characteristics similar to those of natural stone pavements. The commonly observed length‐axes orientation angle of 40 ± 14° for natural stone‐pavement clasts is consistently reproduced by angle‐dependent force equilibrium. Monte Carlo runs confirm the natural scatter and allow characterization of the control parameters of clast orientation. The model explains up to 70% of the natural variance. It is further validated by flume experiments, which confirm model predictions of single object orientation angles. Experiments with multiple objects yield artificial stone pavements with properties similar to those found in the field. The unidirectional lateral process acting on natural stone pavements requires the presence of a vesicular horizon. This underlines the tight genetic coupling of this common epipedon feature and the clast cover. The presented findings highlight the role of stone pavements as process and environment proxies. However, stone pavements represent information since the last surface disturbance only. This has to be considered when using them as age indicators. Copyright © 2013 John Wiley & Sons, Ltd.     

Simulating damage evolution and fracture propagation in sandstone containing a preexisting 3-D surface flaw under uniaxial compression

Preexisting flaws and rock heterogeneity have important ramifications on the process of rock fracturing and on rock stability in many applications. Therefore, there is great interest in numerical modelling of rock fracture and the underlying mechanisms. We simulated damage evolution and fracture propagation in sandstone specimens containing a preexisting 3-D surface flaw under uniaxial compression. We applied the linear elastic damage model based on the unified strength theory following the rock failure process analysis code. However, in contrast to the rock failure process analysis code, we used the finite element method with tetrahedron elements on unstructured meshes. It provided higher geometrical flexibility and allowed for a more accurate representation of the disk-shaped flaw with various flaw depths, angles, and lengths through locally adapted meshes. The rock heterogeneity was modelled by sampling the initial local Young's modulus from a Weibull distribution over a cubic grid. The values were then interpolated to the computational finite element method mesh. This method introduced an additional length scale for the rock heterogeneity represented by the cell size in the sampling grid. The generation of three typical surface cracking patterns, called wing cracks, anti-wing cracks, and far-field cracks, were identified in the simulation results. These depend on the geometry of the preexisting surface flaw. The simulated fracture propagation, coalescence types, and failure modes for the specimens with preexisting surface flaw show good agreement with recent experimental studies.     

Storage of carbon in U.S. forests predicted from satellite data,ecosystem modeling,and inventory summaries

A plant and soil simulation model based on satellite observations of vegetation and climate data was used to estimate the potential carbon pools in standing wood biomass across all forest ecosystems of the conterminous United States up to the year 1997. These modeled estimates of vegetative carbon potential were compared to aggregated measurements of standing wood biomass from the U. S. Forest Service’s national Forest Inventory and Analysis (FIA) data set and the Carbon Online Estimator (COLE) to understand: 1) predominant geographic variations in tree growth rate and 2) local land cover and land use history including the time since the last stand-replacing disturbance (e.g., from wildfire or harvest). Results suggest that although wood appears to be accumulating at high rates in many areas of the U.S. (Northwest and Southeast), there are still extensive areas of relatively low biomass forest in the late 1990s according to FIA records. We attribute these low biomass accumulation levels to the high frequency of disturbances, which can be observed even in high production areas such as the Southeast due to frequent forest harvests. Ecosystem models like the one presented in this study have been coupled with satellite observations of land cover and green plant density to uniquely differentiate areas with a high potential for vegetative carbon storage at relatively fine spatial resolution.     

Laboratory testing of coupled hydro-mechanical processes during rock deformation

This paper gives an overview of the published literature on laboratory testing of the stress dependence of rock-permeability. Additionally results of personal research on the stress dependence of the permeability of a low-porosity sandstone are presented. Stress-dependent permeability is examined in the laboratory under different stress fields and stress paths, depending on the intended application of the research. The most commonly applied stress paths are hydrostatic compression, triaxial compression, uniaxial strain conditions, and testing under a constant stress path. The published results of several studies on different rock types under one or more of the mentioned stress conditions are described and compared. A general trend of permeability evolution under hydrostatic and triaxial conditions can be established for sandstones and some crystalline rocks such as granite or rocksalt. For uniaxial strain tests and stress path tests the published results are limited to a few rock types (mainly sandstones). Therefore, a general conclusion for the stress dependence of permeability under these conditions is not possible. Electronic Publication     

Inundation and isolation: dynamics of phytoplankton communities in seasonal inundated flood plain waters of the Lower Odra Valley National Park — Northeast Germany

The flood plains of the Lower Odra are inundated in winter and spring and are desiccated in summer and autumn. Phytoplankton composition as well as its seasonal succession in permanent oxbows and separate lakes were investigated between 1993 and 1996. Solitary centric diatoms were the characteristic phytoplankton taxa of these flood plain waters. They dominated the main channel non-seasonally, the flood plains during the entire inundation phase and long periods of the isolation phase. Only during long phases of low mixing (maximal 1.5-2 months in summer) separate water bodies were dominated by Cyano- and/or Dinophyceae. This special feature of the Lower Odra Valley is explained by the Inundation-Isolation-Model of phytoplankton development influenced by inundation. Out of a high diverse algal spectrum of 495 taxa, specialities such as 9 endangered taxa and 6 halophilous taxa were discussed. Additionally, taxon specific cell-volumes and maxima of biovolumes were given.