Occurrence of low-Ca clinopyroxene and the role of deformation in the formation of pyroxene-Fe−Ti oxide symplectites

Pyroxene-Fe−Ti oxide symplectites in a norite from the leuconoritic phase of the Bjerkreim-Sokndal lopolith, SW Norway, have been studied using EMPA (electron microprobe analysis) and TEM (transmission electron microscopy) techniques. Textural and mineralchemical data indicate that the symplectites formed under subsolidus conditions at T=720–736°C and f_{o 2}=10^-17 bars. Solidus temperatures are estimated as 981–1060° C. Two models of formation are proposed: non-isochemical replacement of olivine, and growth at boundaries between exsolving grains of orthomagmatic high-Ca pyroxene and Fe−Ti oxide. TEM reveals the presence of low-Ca clinopyroxene and this formed in response to strain and/or shear stress. Comparison with published experimental data indicates that strain rates of up to 10^-12 s^-1 are necessary to explain the occurrence of low-Ca clinopyroxene. The transition from orthopyroxene to low-Ca clinopyroxene may be related to deformation which accompanied intrusion of the leuconoritic phase of the Bjerkreim-Sokndal lopolith or to local post-intrusive faulting and/or shearing. Selected-area diffraction shows that the Fe−Ti oxide lamellae are oriented with respect to the pyroxene such that (111)_oxide/(100)_pyroxene. the planes of closest oxygen packing in the constituent phases are thus adjacent to one another which leads to minimal misfit between the structures and to low interfacial strain energy. The same topotactic relationship exists in both lamellar and vermicular parts of symplectites (but is not continuous along the total length of the interface), indicating that the form of the intergrowths is a primary growth feature that to some extent can be explained in terms of growth models for duplex cells. Deformation during growth is probably necessary to account for the lattice distortion observed in the symplectites. Supercooling is necessary for nucleation and growth of the symplectites. A period of cooling under static, fluid-absent conditions allows substantial overstepping of equilibrium reaction boundaries. Nucleation and growth is triggered by local deformation accompanied by influx of fluid or, possibly, melt. Under these conditions growth can be rapid (≈1 year), and low-Ca clinopyroxene forms during or after growth. The proportions of pyroxene and Fe−Ti oxide in symplectites from a variety of rocks fall in a narrow range (70.5:29.5–74.8:25.3) which suggests a common growth mechanism. The interlamellar spacing is related to the amount of supercooling prior to growth, but the effects of fluid on growth rate must be studied before this relationship can be quqntified. Symplectites provide evidence for the development of retrograde mineral assemblages in relatively short time intervals under transitory fluid-present conditions. The models for symplectite formation in the intrusives of southwestern Norway may be applicable to pyroxene-Fe−Ti oxide intergrowths in other slowly cooled basic igneous rocks.     

SPM response to tide and river flow in the hyper-turbid Ems River

In this paper, we analyse the behaviour of fine sediments in the hyper-turbid Lower Ems River, with focus on the river’s upper reaches, a stretch of about 25 km up-estuary of Terborg. Our analysis is based on long records of suspended particulate matter (SPM) from optical backscatter (OBS) measurements close to the bed at seven stations along the river, records of salinity and water level measurements at these stations, acoustic measurements on the vertical mud structure just up-estuary of Terborg and oxygen profiles in the lower 3 m of the water column close to Leerort and Terborg. Further, we use cross-sectionally averaged velocities computed with a calibrated numerical model. Distinction is made between four timescales, i.e. the semi-diurnal tidal timescale, the spring–neap tidal timescale, a timescale around an isolated peak in river flow (i.e. about 3 weeks) and a seasonal timescale. The data suggest that a pool of fluid/soft mud is present in these upper reaches, from up-estuary of Papenburg to a bit down-estuary of Terborg. Between Terborg and Gandersum, SPM values drop rapidly but remain high at a few gram per litre. The pool of fluid/soft mud is entrained/mobilized at the onset of flood, yielding SPM values of many tens gram per litre. This suspension is transported up-estuary with the flood. Around high water slack, part of the suspension settles, being remixed during ebb, while migrating down-estuary, but likely not much further than Terborg. Around low water slack, a large fraction of the sediment settles, reforming the pool of fluid mud. The rapid entrainment from the fluid mud layer after low water slack is only possible when the peak flood velocity exceeds a critical value of around 1 m/s, i.e. when the stratified water column seems to become internally supercritical. If the peak flood velocity does not reach this critical value, f.i. during neap tide, fluid mud is not entrained up to the OBS sensors. Thus, it is not classical tidal asymmetry, but the peak flood velocity itself which governs the hyper-turbid state in the Lower Ems River. The crucial role of river flow and river floods is in reducing these peak flood velocities. During elongated periods of high river flow, in e.g. wintertime, SPM concentrations reduce, and the soft mud deposits consolidate and possibly become locally armoured as well by sand washed in from the river. We have no observations that sediments are washed out of the hyper-turbid zone. Down-estuary of Terborg, where SPM values do not reach hyper-turbid conditions, the SPM dynamics are governed by classical tidal asymmetry and estuarine circulation. Hence, nowhere in the river, sediments are flushed from the upper reaches of the river into the Ems-Dollard estuary during high river flow events. However, exchange of sediment between river and estuary should occur because of tide-induced dispersion.     

The Southern Region of Peru Earthquake of June 23rd, 2001

The western border of South America is one of the most important seismogenic regions in the world. In this region the most damaging earthquake ever recorded occurred. In June 23rd, 2001, another very strong earthquake (Mw = 8.1–8.2) occurred and produced death and damages in the whole southern region of Peru. This earthquake was originated by a friction process between Nazca and South American plates and affected an area of about 300 km × 120 km defined by the distribution of more than 220 aftershocks recorded by a local seismic network that operated 20 days. The epicenter of the main shock was localized in the northwestern extremity of the aftershock area, which suggests that the rupture propagated towards the SE direction. The modeling of P-wave for teleseismic distances permitted to define a focal mechanism of reverse type with NW-SE oriented nodal planes and a possible fault plane moving beneath almost horizontally in NE direction. The source time function (STF) suggests a complex process of rupture during 85 sec with 2 successive sources. The second one of greater size, and located approximately 100–120 km toward the SE direction was estimated to have a rupture velocity of about 2 km/sec on a 28°-dipping plane to the SE (N135°). A second event happened 45 sec after the first one with an epicenter 130km farther to the SE and a complex STF. This event and the second source of the main shock caused a Tsunami with waves from 7 to 8 meters that propagated almost orthogonally to the coast line, by affecting mainly the Camaná area.Three of all the aftershocks presented magnitudes greater or equal to Mw = 6.6, two of them occurred in front of the cities of Ilo and Mollendo (June 26th and July 7th) with focal mechanisms similar to the main seismic event. The aftershock of July 5th shows a normal mechanism at a depth of 75 km, and is therefore most likely located within the subducting Nazca plate and not in the coupling. The aftershocks of June 26th (Mw = 6.6) and July 5th (Mw = 6.6) show simple short duration STF. The aftershock of July 7th (Mw = 7.5) with 27-second duration suggests a complex process of energy release with the possible occurrence of a secondary shock with lower focal depth and focal mechanism of inverse type with a great lateral component. Simple and composed focal mechanisms were elaborated for the aftershocks and all have similar characteristics to the main earthquake.The earthquake of June 23rd caused major damages in the whole southern Peru. The damage in towns of Arequipa, Moquegua allow to consider maximum intensities from 6 to 7 (MSK79). In Alto de la Alianza and Ciudad Nueva zones from Tacna, the maximum intensity was of 7⁻ (MSK79).     

Streamflow response to native forest restoration in former Eucalyptus plantations in south central Chile

Global increases in intensive forestry have raised concerns about forest plantation effects on water, but few studies have tested the effects of plantation forest removal and native forest restoration on catchment hydrology. We describe results of a 14-year paired watershed experiment on ecological restoration in south central Chile which documents streamflow response to the early stages of native forest restoration, after clearcutting of plantations of exotic fast-growing Eucalyptus, planting of native trees, and fostering natural regeneration of native temperate rainforest species. Precipitation, streamflow, and vegetation were measured starting in 2006 in four small (3 to 5 ha) catchments with Eucalyptus globulus plantations and native riparian buffers in the Valdivian Coastal Reserve. Mean annual precipitation is 2500 mm, of which 11% occurs in summer. Streamflow increased, and increases persisted, throughout the first 9 years of vigorous native forest regeneration (2011 to 2019). Annual streamflow increased by 40% to >100% in most years and >150% in fall and summer of some years. Streamflow was 50% to 100% lower than before treatment in two dry summers. Base flow increased by 28% to 87% during the restoration period compared to pre-treatment, and remained elevated in later years despite low summer precipitation. Overall, these findings indicate that removal of Eucalyptus plantations immediately increased streamflow, and native forest restoration gradually restored deep soil moisture reservoirs that sustain base flow during dry periods, increasing water ecosystem services. To our knowledge this is the first study to assess catchment streamflow response to native forest restoration in former forest plantations. Therefore, the results of this study are relevant to global efforts to restore native forest ecosystems on land currently intensively managed with fast-growing forest plantations and may inform policy and decision-making in areas experiencing a drying trend associated with climate change.     

Water geochemical characteristic variations in and around a karst-dominated natural reserve area,southwestern China

This paper reports original data on the physical and chemical parameters of precipitation, river water and groundwater in and around the Longhushan Nature Reserve Area, located in southwestern China karst region, and provides a preliminary characterization of the hydrogeochemical process governing the natural water evolution in this area. The rainfall and river water mainly pertain to the HCO₃ ⁻–Ca²⁺ type and groundwater mainly pertain to the HCO₃ ⁻–Ca²⁺ + Mg²⁺ type. The HCO₃ ⁻ was the predominant anion and Ca²⁺ was the predominant cation in all waters, respectively. The Gibbs Boomerang Envelop model, the 1:1 relationship of Na⁺ plus K⁺ versus Cl⁻ as well as the 1:1 relationship of Ca²⁺ plus Mg²⁺ versus HCO₃ ⁻ all suggested geochemical weathering is the main controlling factor for the geochemical compositions of this natural water. In surface water, the Mg²⁺/Ca²⁺ ratios ranged from 0.32 to 0.42 and the Na⁺/Ca²⁺ varied between 0.04 and 0.05. In the groundwater, the Mg²⁺/Ca²⁺ ratios varied from 0.37 to 0.62 and were below the ideal ratio of 0.8. These ratios showed the presence of a dolomite source. Analysis of trace elements showed that As, B, Pb, Se, Sr, V and Zn elements were abundant in the natural water during summer in this region.     

New discoveries of vertebrate remains from the Triassic of Riba de Santiuste,Guadalajara (Spain)

The palaeontological sites of Riba de Santiuste and Sienes (Riba de Santiuste area) are located in the province of Guadalajara, Spain. They include a stratigraphic interval in Muschelkalk facies belonging to the “Cuesta del Castillo Sandstones” Formation and “Royuela Dolostones, Marls and Mudstones” Formation. These sites include numerous fossil plants, direct vertebrate remains, and vertebrate swim traces. The vertebrate remains correspond to a multitude of anatomical elements of Sauropterygia (Nothosauroidea, Placodontia) and possible Archosauria (Rauisuchia) remains. The fossil material attributed to nothosaurs includes teeth, coracoids, a thoracic vertebra, some isolated vertebral centra, humerus, rib fragments, and some dorsal and caudal vertebrae. The remains attributed to placodonts correspond to fragments of skull, quadrate, teeth and osteoderms. Other undetermined sauropterygian remains, such as ulnas, fragments of long bones, fragments of ribs, and articular facets of ribs have been also recovered. Additionally, a fragment of mandible and an intervertebral disk of indeterminate reptiles whose size could be compatible with archosaurs are also described. These bones are exceptionally well-preserved because the fossilization processes have preserved the microstructure of the tissues. The sites also show vertebrate traces, with parallel scratch impressions interpreted as swim traces. The relative stratigraphic position and the palaeontological content of these sites suggest a Ladinian age (Middle Triassic). The interpretation of the sedimentary facies here described also suggests that the sites could correspond to detrital-carbonate mixed deposits of coastal intertidal to supratidal environments.     

Wetland place names as indicators of manifestations of recent climate change in SW Spain (Doñana Natural Park)

Recent studies have shown the value of place names as environmental indicators. Until now they have not been applied to the effects of climate change, because verifying such relationship by this approach requires a multidisciplinary analysis and a study area where the anthropic impact has been recent. This study aims to test the possibility in a study area little altered by man until the second half of the twentieth century (Doñana Natural Park, SW Spain), and with a heritage very rich in wetlands. The results show that the desiccation of these wetlands is reflected in the local toponymy, and that in turn this regression is related with the end of the Little Ice Age and with the beginning of warming in southern Europe during the twentieth century. The coincidence of these results with data published for Arctic latitudes reveals—in our opinion—the possibility that certain place names can be used as indicators of recent climate changes, at least in some ecosystems.