The Leonard Award Address Presented 1996 July 25, Berlin,Germany: The elemental composition of stony cosmic spherules

Abstract— Five hundred stony cosmic spherules collected from deep-sea sediments, polar ice, and the stratosphere have been analyzed for major and some minor element composition. Typical spherules are products of atmospheric melting of millimeter sized and smaller meteoroids. The samples are small and modified by atmospheric entry, but they are an important source of information on the composition of asteroids. The spherules in this study were all analyzed in an identical manner, and they provide a sampling of the solar system's asteroids that is both different and less biased than provided by studies of conventional meteorites. Volatile elements such as Na and S are depleted due to atmospheric heating, while siderophiles are depleted by less understood causes. The refractory nonsiderophile elements appear not to have been significantly disturbed during atmospheric melting and provide important clues on the elemental composition of millimeter sized meteoroids colliding with the Earth. Typical spherules have CM-like composition that is distinctively different than ordinary chondrites and most other meteorite types. We assume that C-type asteroids are the primary origin of spherules with this composition. Type S asteroids should also be an important source of the spherules, and the analysis data provide constraints on their composition. A minor fraction of the spherules are melt products of precursor particles that did not have chondritic elemental compositions. The most common of these are particles that are dominated by olivine. The observed compositions of spherules are inconsistent with the possibility that an appreciable fraction of the spherules are simply chondrules remelted during atmospheric entry.     

The ultrashort period dwarf nova SW ursae majoris

SW UMa is an unusual dwarf nova in several respects. Recent observations by Robinsonet al. (1986) have established that SW UMa is an SU UMa system, while Shafter, Szkody, and Thorstensen (1986) have presented evidence suggesting that SW UMa may be a DQ Her system as well. If the DQ Her classification is confirmed then SW UMa will be the only system to have this dual classification. Finally, time resolved spectroscopy of SW UMa has revealed the presence of an S-wave component in the H emission which has an unexpected phasing relative to the line wings.Paper presented at the IAU Colloquium No. 93 on Cataclysmic Variables. Recent Multi-Frequency Observations and Theoretical Developments, held at Dr. Remeis-Sternwarte Bamberg, F.R.G., 16–19 June, 1986.     

Implications from the shape of the viscosity-surface density relation

We present results of new vertical structure computations for cool, convective accretion disks. The influence of the uncertainty in the low temperature opacities on the cool branch of the viscosity-surface density relation is investigated. We discuss how the shape of this relation allows a prediction of temperatures in the accretion disk during the onset of an outburst and we compare this with observations for VW Hydri by Hassall (1984).Paper presented at the IAU Colloquium No. 93 on Cataclysmic Variables. Recent Multi-Frequency Observations and Theoretical Developments, held at Dr. Remeis-Sternwarte Bamberg, F.R.G., 16–19 June, 1986.     

The dynamo dilemma

The recent determination that the angular velocity of the Sun declines downward through the convective zone raises serious questions about the nature of the solar dynamo. The principal qualitative features of the Sun are the azimuthal fields that migrate toward the equator in association with an oscillating poloidal field which reverses at about the time of maximum appearance of bipolar magnetic regions. If decreases downward, or is negligible, the horizontal gradient in produces a dynamo with some of these essential characteristics. There is reason to think that the dynamo is confined to the lower half of the convective zone where has the opposite sign from the usual ( > 0 in the northern hemisphere) producing equatorward migration but reversing the sign of the associated poloidal field. Meridional circulation may play an essential role in shaping the dynamo. At the present time it is essential to measure accurately and determine the nature of the meridional circulation.Solar Cycle Workshop Paper.     

Model of geomagnetic paleosecular variations for the Northern Hemisphere

Summary A model of radial drifting and oscillating dipoles to represent geomagnetic palaeosecular variations, which showed to be appropriate for the Southern Hemisphere, is evaluated for the Northern Hemisphere. After a new fitting of some involved parameters, its theoretical results are compared with the palaeomagnetic data of Lake de Bouchet (France) and the Black Sea. A time lag between the declination and inclination profiles is observed in both cases. A good cross-correlation coefficient is obtained for the declination and inclination data.Presented at 2nd conference on New Trends in Geomagnetism, Castle of Bechyn, Czechoslovakia, September 24–29, 1990.     

Pleistocene mass-flow deposits of basaltic hyaloclastite on a shallow submarine shelf,South Iceland

A Pleistocene subaqueous, volcanic sequence in South Iceland consists of flows of basaltic hyaloclastite and lava with interbedded sedimentary diamictite units. Emplacement occurred on a distal submarine shelf in drowned valleys along the southern coast of Iceland. The higher sea level was caused by eustatic sea-level change, probably towards the end of a glaciation. This sequence, nearly 700 m thick, rests unconformably on eroded flatlying lavas and sedimentary rocks of likely Tertiary age. A Standard Depositional Unit, describing the flows of hyaloclastite, starts with compact columnar-jointed basalt overlain by cubejointed basalt, and/or pillow lava. This in turn is overlain by thick unstructured hyaloclastite containing aligned basalt lobes, and bedded hyaloclastite at the top. A similar lithofacies succession is valid for proximal to distal locations. The flows were produced by repeated voluminous extrusions of basaltic lava from subaquatic fissures on the Eastern Rift Zone of Iceland. The fissures are assumed to lie in the same general area as the 1783 Laki fissure which produced 12 km³ of basaltic lava. Due to very high extrusion rates, the effective water/melt ratio was low, preventing optimal fragmentation of the melt. The result was a heterogeneous mass of hyaloclastite and fluid melt which moved en masse downslope with the melt at the bottom of the flow and increasingly vesicular hyaloclastite fragments above. The upper and distal parts of the flow moved as low-concentration turbulent suspensions that deposited bedded hyaloclastite.     

Distribution and fluxes of metals in the St. Lawrence River from the outflow of Lake Ontario to Québec City

Six anchor stations in the St. Lawrence River from the outflow of Lake Ontario to Quebec City, were occupied for ca. 24 hours in June 1987 during low flow conditions. Samples of water and suspended particulate matter were separated by continuous-flow centrifugation, and were collected every two hours.During this sampling period, fluxes of dissolved forms of zinc, copper and nickel increased in Lac St. François and downstream relative to the sum of the fluxes for the two upstream stations at the outflow of Lake Ontario. Increases in the flux of dissolved zinc and copper were pronounced below Montreal and above Lac St. Pierre. For particulate forms of metals, all five metals show that there are significant inputs in the section of the St. Lawrence River between Lac St. François and the station just above the entrance to Lac St. Pierre.The average concentrations of dissolved cadmium, lead, zinc, copper and nickel ranged from 7–23 ng/l; 9–35 ng/l; 0.434–0.939 g/l; 0.15–0.89 g/l and 0.58–1.12 g/l respectively.Regression analysis of the dissolved and particulate metal concentrations suggests that the concentration of dissolved cadmium, lead, zinc and nickel can be predicted from the regression equation and the determination of particulate metal concentration. This prediction appears to be independent of the suspended particulate matter concentration which varies from ca. 1 to 10 mg/l from the outflow of Lake Ontario to Québec City.     

The redox states of basic and silicic magmas: a reflection of their source regions?

At present the best estimates of the oxygen fugacity of spinel-lherzolites that could be the source material of basic magmas is about five log units below the Ni–NiO buffer to one above it. However partially glassy basic lavas, ranging from MORBs to minettes, all with olivine on their liquidus, cover a wider range, and may have oxygen fugacities that extend to four log units above NNO. Surprisingly the range of oxygen fugacities observed in silicic lavas and ashflows with quartz phenocrysts is smaller, despite a crustal dominated evolution. The peralkaline silicic lava type pantellerite is the most reduced, equivalent to MORBs, whereas the large volume ashflows with phenocrysts of hornblende and/or sphene are the most oxidised. As the concentration of water in the basic lavas is correlated with increase in their redox state, it would seem that water could be the agent of this increase. That this is unlikely is seen in the behavior of silicic ashflows and lavas, particularly those of Yellowstone. Here the silicic magmas of the last 2Ma contain about 2 wt% FeO_(total), and typically phenocrysts of fayalite, quartz and Fe–Ti oxides. Despite extensive exchange of the ¹⁸O of the magma with meteoric water after caldera collapse (Hildreth et al. 1984), there is no displacement of the redox equilibria. Thus the thermal dissociation of molecular H₂O to H₂, and its subsequent diffusive loss to cause oxidation must have been minimal. This could only be so if the activity of water was small, as it would be if H₂O reacted with the silicate liquid to form OH groups (Stolper 1982). The conclusion is that silicic magmas with small amounts of iron and large amounts of water do not have their redox states reset, which in turn presumably reflect their generation. By analogy basic magmas with large amounts of iron and far less water are even less likely to have their redox equilibria disturbed, so that their oxygen fugacities will also reflect their source regions. The effect of pressure on the ferric-ferrous equilibrium in basic magmas can be calculated from experimental measurements of the partial molar volumes of FeO and Fe₂O₃, and their pressure derivatives V/P, in silicate liquids. The effect of pressure is found to be about the same on the liquid as it is for various solid oxygen buffers. Accordingly there should be mantle source regions covering the same range of oxygen fugacity as that found in basic lavas, but so far samples of spinel-lherzolite of equivalent oxygen fugacity to minettes or other potassic lavas have not been found. Whether or not the redox state of phlogopite-pyroxenites is equivalent to these potassic lavas cannot be established without experiment.