Ethnicity as a cause of migration in Eastern Europe

Migration within and from Eastern Europe has recently risen as a topic of significance on the European political agenda. One aspect of this complex migration matrix relates to ethnic unrest. This paper examines the scale and spatial ramifications of this movement on a part of the continent recently freed from communist rule.An attempt is made to divide the ethnic quilt of Eastern Europe into those countries with few such problems and those with many. It is possible then to define areas of active migration (hot spots) from those of potential migration (inflammable spots) based on predictions from the current situation.Active ethnic migration results from the present political/military instability in the western Balkans, where refugees have left for other parts of Europe to escape the present Croat-Serb-Muslim conflict. War escalation could encourage potential ethnic migration from Kosovo, the Sandzak and Vojvodina regions,and Macedonia within the former Yugoslavia. Future disquiet elsewhere could stimulate ethnic groups such as the Turks in Bulgaria,and the Hungarian minorities in Slovakia and Romania to join this migration movement scenario.     

Cesstibtantite—a geologic introduction to the inverse pyrochlores

Summary The crystal structure of cesstibtantite has been solved from diffractometer data collected on samples from Leshaia, Russia and the Tanco pegmatite, Manitoba. Cesstibtantite from the Leshaia pegmatite (type locality) hasa 10.515(2) Å, space groupFd3m, composition Cs_0.31(Sb_0.57Na_0.31Pb_0.02Bi_0.01)_O.91(Ta_1.88Nb_0.12)₂(O_5.69[OH, F]_0.31)₆(OH, F)_0.69, Z 8; its structure was refined toR 3.8,wR 4.3% using 96 observed (F > 3[F]) reflections (MoK). Cesstibtantite from the Tanco pegmatite hasa 10.496(1) Å, space groupFd3m, composition (Cs_0.22K_0.01)_0.23(Na_0.45Sb_0.39Pb_0.14· Ca_0.06Bi_0.02)_1.06(Ta_1.95Nb_0.05)₂(O_5.78[OH,F]_0.22)₆(OH,F)_0.55,Z 8; its structure was refined toR 3.9w R 3.7% using 104 observed reflections. Cesstibtantite differs from the normal pyrochlores in that it contains significant amounts of very large cations such as Cs. As these cations are too large (^VIII[r] > 1.60 Å) for the conventional [8]-coordinated A site, they occupy the [18]-coordinated site, which normally contains monovalent anions. Natural cesstibtantite samples are non-ideal in that both Cs and monovalent anions occur at the site; thus cesstibtantite is intermediate to thenormal pyrochlores (with only monovalent anions at the site) and theinverse pyrochlores (with only large cations at the site).

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Cesstibtantit—eine geologische Einfiihrung in die inversen Pyrochlore

Zusammenfassung Die Kristallstruktur von Cesstibtantit wurde auf der Basis von Diffraktometerdaten von Proben von Leshaia, Russland and dem Tanco Pegmatit, Manitoba, gelöst. Cesstibtantit aus dem Leshaia Pegmatit (Typlokalität) hat a 10.515(2) Å, RaumgruppeFd3m, die Zusammensetzung CS_0.31(Sb_0.57Na_0.31Pb_0.02Bi_0.01)_0.91(Ta_1.88Nb_0.12)₂· (O_5.69OH, F_0.31)₆(OH, F)_0.69 Z 8; die Struktur wurde aufR 3.8,wR 4.3% verfeinert unter Benützung von 96 beobachteten Reflexen. Cesstibtantit vom Tanco Pegmatit hat a 10.496(1) Å, RaumgruppeFd3m, die Zusammensetzung (Cs_0.22K_0.01)_0.23(Na_0.45· Sb_0.39Pb_0.14Ca_0.06Bi_0.02)_1.06(Ta_1.95Nb_0.05)₂(O_5.78OH,F_0.22)₆(OH,F)_0.55,Z 8; seine Struktur wurde aufR 3.9wR 3.7% auf der Basis von 104 beobachteten Rettexen verfeinert. Cesstibtantit unterscheidet sich von normalen Pyrochloren insofern, als er signifikante Mengen von sehr großen Kationen, wie z.B. Cs enthält. Da these Kationen zu groß sind (^VIII r 1.60 Å) für eine konventionelle [8]-koordinierteA Stelle, nehmen she die [18]-koordinierten Positionen ein, welche normalerweise monovalente Anionen enthalten. Natürliche Cesstibtantitproben sind nicht ideal insofern als sowohl Cs als auch monovalente Anionen in der Position vorkommen. Somit ist Cesstibtantit intermediär zu den normalen Pyrochloren (mit nur monovalenten Anionen auf der Position) and den inversen Pyrochloren (mit ausschließlichen großen Kationen an der Position).

     

Banded iron formations in Proterozoic greenstone belts: Call for further studies

Banded iron formations occur in greenstone belts in which volcanic rocks are predominant. Greenstone belts are not restricted to the Archaean (>2500 Ma), as is commonly perceived, but they continued to form, albeit in lesser abundance, in the Proterozoic. Thus, banded iron formations which are closely associated with volcanic sequences occur in several well-documented early-mid Proterozoic greenstone belts. Examples are the Yavapai belts at Jerome in Arizona, the Trans-Amazonian belts in Guiana, and the Dalma belts of the Singhbhum region of NE India. Stratigraphic and sedimentological studies are needed to establish the similarities and differences of these iron formations with those in Archaean greenstone belts, and with the banded iron formations which were common in cratonic-shelf environments in the early-mid Proterozoic.     

Sheet-flow deposits of graded beds and mudstones on an alluvial sandflat-playa system: Upper Triassic Blomidon redbeds, St Mary's Bay, Nova Scotia

The 400 m of Blomidon redbeds accumulated in a semi-arid rift valley in the subtropics. At St Mary's Bay, these redbeds are 64% sandy mudstone (playa mudflats), 25% graded beds (sandflats at the toes of alluvial fans), 10% fissile claystone (playa lakes), and 1% channel sandstone (stream channels). Flash floods in mountains south of the valley flowed down alluvial fans to spread out to the north-east as sheet flows on sandflats and playa mudflats. Deceleration of the sheet flows deposited graded beds 2–83 cm in thickness on the sandflats and thin layers of mud on the playas. Nine sequences, consisting of arrangements of six lithologies, compose 90% of the graded beds. In order of decreasing abundance, these are: ripple cross-laminated siltstone → horizontally laminated mudstone; fining-upward, ripple cross-laminated siltstone; ripple cross-laminated sandstone → horizontally laminated mudstone; cross-bedded sandstone horizontally laminated mudstone; ripple cross-laminated sandstone → ripple cross-laminated siltstone; rippledrift cross-laminated siltstone horizontally laminated mudstone; fining-upward, ripple-drift cross-laminated siltstone; cross-bedded sandstone → ripple cross-laminated siltstone; and cross-bedded sandstone → ripple cross-laminated siltstone → horizontally laminated mudstone. The sheet flows, perhaps up to 1 m in depth, had a high concentration of suspended load. Deposition was dominantly during lower flow regime conditions and moderate to rapid flow deceleration. There are 32 thinning and fining-up cycles where a sandflat package of graded beds is transitionally followed by a playa package of sandy mudstone. The cycles range in thickness from 1·3 to 13·3 m, averaging 4·6 m. Each cycle is initiated by avulsion to a new active channel network on a fan. Gradual abandonment of the channel network produces the thinning and fining-up cycle. The cycles are grouped in three 60–70 m fining-up megacycles. Upwards within each megacycle, the packages of sandy mudstone compose a progressively larger proportion of the cycles. Each megacycle evidently was initiated by a brief period of tectonic movement on the border faults that produced greater relief of the highlands relative to the valley floor. Subsequent erosion gradually lowered the relief to yield a fining-up megacycle.     

The history of the development of procedures for the rapid assessment of environmental conditions to aid the urban regeneration process at London Docklands

A process of urban regeneration of the former industrial dock area of east London by the London Docklands Development Corporation (LDDC) recognised the importance of geotechnical and geoenvironmental information. A systematic programme of data collection was implemented and stored in a series of bespoke computer database systems and cartographic registers. These allowed retrieval and manipulation of the data to provide rapid site assessments. The understanding of the natural setting of the area was enhanced as a consequence of the collation exercise. The data stored included geotechnical and environmental information on soil and groundwater. The hydrogeological regime was modelled by computer to determine the consequences of development on groundwater movement. In addition, a cartographic register of historic land use was developed. This gave instant detail on the potential for contamination of a site and became a fundamental tool in the UK planning process of the area. The information from the separate systems was finally combined into a geographic information system.     

Chemical assembly of Archean anorthosites from amphibolite- and granulite-facies terranes, SW Greenland

We report whole-rock, major- and trace-element compositions (obtained by XRF and INA methods) for the amphibolite-facies Buksefjorden and granulite-facies Nordland anorthosites, SW Greenland. In a previous petrologic study on the same sample suite, we documented differences in texture, mineralogy, and mineral compositions between these two anorthosite bodies. Chemical analyses confirm differences in composition between the two bodies, but these differences cannot be explained by variations in metamorphic conditions, and point towards differences in the nature of their protoliths. Analyzed Nordland samples are anorthosites and leucogabbros with 88-98% normative plagioclase, whereas those from Buksefjorden include anorthosite, leucogabbro, and gabbro with ~55-95% normative plagioclase. Two or more compositional groupings can be recognized at each site, which correspond to differences in color and mineralogy of the hand samples. Samples from Buksefjorden are mainly quartz-normative, whereas those from Nordland are olivine (- nepheline) normative. Other differences include higher Ni/Co ratio and REE contents in the granulite-facies anorthosites from Nordland. REE pattern shapes are similar, however, being moderately fractionated at ~0.5-102 chondrites with positive Eu-anomalies. Calculated equilibrium melt patterns are similar for both anorthosites, being relatively flat at ~50-1502 chondrites, suggesting unfractionated (but evolved) parental magmas. Olivine must have been present in the protoliths of the Nordland rocks compared with Buksefjorden. Otherwise, the protoliths contained plagioclase with variable An-content (~An₆₂-An₉₂) and a mafic component with variable Fe/Mg (mg ~0.3-0.8). This mafic component was either hornblende or a combination of ortho- and clinopyroxene in fixed proportions, plus a small amount of magnetite. Mixing calculations demonstrate that some Buksefjorden anorthosites contain two varieties of plagioclase: a calcic type that may correspond to cumulus crystals, and a sodic-type that may correspond to a trapped-melt component. On plots of normative whole-rock An versus mg, compositions of the Buksefjorden and Nordland anorthosites form crude negative arrays that differ from the generally positive trends of mafic layered intrusions (Kiglapait, Skaergaard) and from the generally flats trends of plagioclase-rich cumulate rocks (St. Urbain and Stillwater anorthosites). This difference provides further evidence for the distinctive nature of Archean calcic-anorthosite complexes compared with other types of mafic intrusions. Moreover, this distribution of data points is consistent with the assembly of the protolith of the SW Greenland anorthosites mainly as mixtures of plagioclase and hornblende. Finally, the field for the Buksefjorden and Nordland anorthosites overlaps only slightly with that for the Fiskenaesset Complex, thus extending the known range of compositions for Archean anorthosites in West Greenland.     

Syn- and post-collisional heat flow in the Cenozoic Eastern Alps

The heat flow evolution of a continental collisional zone is exemplified by the Eastern Alps. Heat flow maps for the syn-collision (Oligocene), syn-extrusion (Early/Middle Miocene), and post-extrusion (Late Miocene, Recent) stages are presented, and are discussed in relation to the orogenic evolution. Continental collision during Paleogene time was characterized by extremely low heat flow (<40 mW/m²) along the orogenetic front, and very high heat flow (>150 mW/m²) a few hundred kilometers south of it. The former was a result of crustal thickening and of thermal blanketing due to rapid sedimentation and nappe stacking. The latter was caused by slab break-off and magmatic activity. The Early/Middle Miocene syn-extrusion stage was characterized by rapid exhumation of metamorphic core complexes (Tauern and Rechnitz Windows), and by magmatic activity (Styrian Basin). Both mechanisms caused extremely high heat flow (>200 mW/m²). In contrast, the orogenetic front remained cold. Thereafter, magmatic activity ended and uplift rates decreased. Thus, Late Miocene heat flow is characterized by low to moderately high values. Heat flow values >75 mW/m² were restricted to the transition zone of the Pannonian Basin characterized by thinned crust, and to the Tauern Window area. Recent temperature data indicate a subtle post-Miocene increase in heat flow.     

Precision W BV R photoelectric photometry of the eclipsing system RR Lyncis

We carried out accurate ( $\sigma _{obs} \approx 0\mathop .\limits^m 003$ ) W BV R photoelectric photometry of RR Lyn and obtained light curves of this eclipsing system. Our analysis of the light curves using an iterative differential-correction method yields a self-consistent system of geometrical and physical characteristics of the two components of the system and their evolutionary states. The system's age is estimated to be t=(1.08±0.15)×10⁹ yr. Observations in all filters are fitted satisfactorily by the same geometry (r _1,2, i, e, and ω). An analysisof blanketing effects in the W, B, V, and R bands indicates that the atmospheric chemical compositions of both components of the system are peculiar: the primary shows an excess ([Fe/H]_I=0.31±0.08) and the secondary a deficit ([Fe/H]_II=?0.24±0.06) of heavy elements. This is in qualitative and quantitative agreement with the results of an earlier spectroscopic study of RR Lyn by Lyubimkov and Rachkovskaya (1995). The derived physical characteristics of RR Lyn provide evidence that the metallicity effects are probably restricted to the stellar surface layers, while their interiors have normal chemical abundances.     

Petrological significance of manganese carbonate inclusions in spessartine garnet and relation to the stability of spessartine in metamorphosed manganese-rich rocks

Idioblastic spessartine garnet pervasively developed in Mn-rich rocks and impure manganese carbonate ore at the Lower Proterozoic Nsuta manganese deposit, Western Ghana, contains abundant inclusions of micritic and microconcretionary carbonates and, to a lesser extent, quartz. Detailed mineralogical and microprobe studies indicate all the carbonate phases (i.e. carbonate inclusions in garnet, carbonates coexisting with garnet and carbonates not directly in contact with garnet, the latter hereafter referred to as matrix carbonates) lie within the rhodochrosite-kutnahorite solid solution series, i.e. ~Mn_55-80(Ca + Mg)_20-45CO₃ to Ca₄₂(Mn + Mg)₅₈(CO₃)₂. Minor compositional differences occur in the various carbonate phases, but partition of major elements among coexisting phases indicate most carbonate minerals strongly fractionate Ca and Mg over coexisting spessartine. The nature, composition and textural relationship of coexisting minerals and inclusions in porphyroblastic spessartine indicate that the latter formed from metamorphic reactions in which rhodochrosite and/or kutnahorite and quartz were consumed, in part corroborating earlier observations on a rhodochrosite precursor for spessartine. Spessartine formation is thus envisaged to have taken place when the predominantly Mn carbonate-quartz assemblage became unstable in the presence of minor amounts of an unknown aluminous phase. Because all the carbonates appear to be low-temperature phases with no indications of significant recrystallisation or homogenisation, it could be argued that the spessartine + rhodochrosite - kutnahorite - quartz - pyrite assemblage stabilised during very low-grade greenschist facies metamorphism under relatively low but uniform f_O2 conditions. These observations also suggest the stability field of spessartine could extend to relatively lower temperatures than currently envisaged.     

The DAV and Periadriatic fault systems in the Eastern Alps south of the Tauern window

Alpine deformation of Austroalpine units south of the Tauern window is dominated by two kinematic regimes. Prior to intrusion of the main Periadriatic plutons at ~30 Ma, the shear sense was sinistral in the current orientation, with a minor north-side-up component. Sinistral shearing locally overprints contact metamorphic porphyroblasts and early Periadriatic dykes. Direct Rb-Sr dating of microsampled synkinematic muscovite gave ages in the range 33-30 Ma, whereas pseudotachylyte locally crosscutting the mylonitic foliation gave an interpreted ⁴⁰Ar-³⁹Ar age of ~46 Ma. The transition from sinistral to dextral (transpressive) kinematics related to the Periadriatic fault occurred rapidly, between solidification of the earlier dykes and of the main plutons. Subsequent brittle-ductile to brittle faults are compatible with N-S to NNW-SSE shortening and orogen-parallel extension. Antithetic Riedel shears are distinguished from the previous sinistral fabric by their fine-grained quartz microstructures, with local pseudotachylyte formation. One such pseudotachylyte from Speikboden gave a ⁴⁰Ar-³⁹Ar age of 20 Ma, consistent with pseudotachylyte ages related to the Periadriatic fault. The magnitude of dextral offset on the Periadriatic fault cannot be directly estimated. However, the jump in zircon and apatite fission-track ages establishes that the relative vertical displacement was ~4-5 km since 24 Ma, and that movement continued until at least 13 Ma.