Analysis of soil drying incorporating a constitutive model for curling

This paper focuses on the shrinkage behavior of soil specimens involving sand, kaolinite, and kaolinite/sand mixtures subjected to desiccation under controlled conditions. Both, free and restrained shrinkage conditions are studied. The experiments show that pure soils do not curl upon unrestrained shrinkage; however, (under the same conditions) kaolinite/sand mixtures exhibited a marked curling. Furthermore, the mixture with the higher sand content broke through the middle of the sample after displaying a significant curling. Soils subjected to restricted shrinkage developed cracks with slight curling. To simulate the observed behavior, a mechanical model able to reproduce the detachment of the soil sample from the mold is proposed in this work and implemented in a fully coupled hydro-mechanical finite-element code. It is concluded that suction and differential shrinkage are key factors influencing the curling behavior of soils. The proposed framework was able to satisfactorily explain and reproduce the different stages and features of soil behavior observed in the experiments.

     

Paleomagnetic and palynologic analyses of Albian to Santonian strata at Bayn Shireh, Burkhant, and Khuren Dukh, eastern Gobi Desert, Mongolia

Cretaceous terrestrial sediments deposited in a series of intracratonic basins across the Gobi Desert region of southern Mongolia and northern China contain a unique and diverse vertebrate fauna. In 1996 an expedition jointly sponsored by the Mongolian Paleontological Center and the Hayashibara Museum of Natural Sciences revisited a number of famous vertebrate fossil localities in the eastern Gobi region of Mongolia and, as part of a broad geological and paleontological study, collected a series of paleomagnetic samples from measured sections at Bayn Shireh, Burkhant and Khuren Dukh, as well as from an unmeasured locality adjacent to Khuren Dukh. Expedition members also collected palynologic samples from Khuren Dukh and the adjacent locality. Paleomagnetic analysis shows that all the sites from which samples were collected display detrital remnant magnetization that is consistently normal in polarity. The measured Cretaceous magnetic directions are oriented to the east or northeast of the present day expected direction (declination 356.2°, inclination 65.2°), and they are wholly concordant with that expected for a mid-latitude Northern Hemisphere sampling locality, and with the directions for this period reported by other workers. These results, when considered in tandem with the known biostratigraphy, strongly suggest that the sedimentary deposits at all four localities in the eastern Gobi correlate to the normal polarity chron 34 (the Cretaceous Long Normal), which ranges in age from approximately 121 to 83.5 million years. Previous vertebrate, invertebrate and palynological data from Khuren Dukh suggest that the lower and middle parts of the stratigraphic interval exposed there (which have been assigned to the Shinekhudag Formation) are ‘Khukhtekian’ in age and correspond to the Aptian–Albian interval that can be broadly correlated to the older, Early Cretaceous part of the Cretaceous Long Normal, C34n. New palynologic data presented here indicate that these strata are no older than middle to late Albian. The rocks at Bayn Shireh (the Bayn Shireh Formation) have been assigned a ‘Baynshirenian’ biostratigraphic age that may range from Cenomanian to early Campanian. The magnetostratigraphy results presented here indicate that the strata at both the Bayn Shireh and Burkhant localities do not cross the Santonian/Campanian Stage boundary, however, as this is believed to lie at, or very near, the C34n/C33r reversal boundary. Thus, the Bayn Shireh Formation was most likely deposited near the end of the Cretaceous Long Normal Interval, no later than the latest Santonian.     

Peridotite Melting at 1 GPa: Reversal Experiments on Partial Melt Compositions Produced by Peridotite-Basalt Sandwich Experiments

One of the goals of igneous petrology is to use the subtle andmore obvious differences in the geochemistry of primitive basaltsto place constraints on mantle composition, melting conditionsand dynamics of mantle upwelling and melt extraction. For thisgoal to be achieved, our first-order understanding of mantlemelting must be refined by high-quality, systematic data oncorrelated melt and residual phase compositions under knownpressures and temperatures. Discrepancies in earlier data onmelt compositions from a fertile mantle composition [MORB (mid-oceanridge basalt) Pyrolite mg-number 87] and refractory lherzolite(Tinaquillo Lherzolite mg-number 90) are resolved here. Errorsin earlier data resulted from drift of W/Re thermocouples at1 GPa and access of water, lowering liquidus temperatures by30–80°C. We demonstrate the suitability of the ‘sandwich’technique for determining the compositions of multiphase-saturatedliquids in lherzolite, provided fine-grained sintered oxidemixes are used as the peridotite starting materials, and thechanges in bulk composition are considered. Compositions ofliquids in equilibrium with lherzolitic to harzburgitic residueat 1 GPa, 1300–1450°C in the two lherzolite compositionsare reported. Melt compositions are olivine + hypersthene-normative(olivine tholeiites) with the more refractory composition producinga lower melt fraction (7–8% at 1300°C) compared withthe model MORB source (18–20% at 1300°C). KEY WORDS: mantle melting; sandwich experiments; reversal experiments; anhydrous peridotite melting; thermocouple oxidation; olivine geothermometry     

A high P-T single-crystal X-ray diffraction study of thermoelasticity of MgSiO3 orthoenstatite

P-V-T data of MgSiO₃ orthoenstatite have been measured by single-crystal X-ray diffraction at simultaneous high pressures (in excess of 4.5 GPa) and temperatures (up to 1000 K). The new P-V-T data of the orthoenstatite, together with previous compression data and thermal expansion data, are described by a modified Birch-Murnaghan equation of state for diverse temperatures. The fitted thermoelastic parameters for MgSiO₃ orthoenstatite are: thermal expansion ?α/?P with values of a=2.86(29)×10^-5 K^-1 and b=0.72(16)×10^-8 K^-2; isothermal bulk modulus K _{T o} =102.8(2) GPa; pressure derivative of bulk modulus K′=?K/?P=10.2(1.2); and temperature derivative of bulk modulus K=?K/?T=-0.037(5) GPa/K. The derived thermal Grüneisen parameter is γ _th=1.05 for ambient conditions; Anderson-Grüneisen parameter is δ _{T o} =11.6, and the pressure derivative of thermal expansion is ?α/?P=-3.5×10^-6K^-1 GPa^-1. From the P-V-T data and the thermoelastic equation of state, thermal expansions at two constant pressures of 1.5 GPa and 4.0 GPa are calculated. The resulting pressure dependence of thermal expansion is Δα/ΔP=-3.2(1)× 10^-6 K^-1 GPa^-1. The significantly large values of K′, K, δ _T and ?α/?P indicate that compression/expansion of MgSiO₃ orthoenstatite is very sensitive to changes of pressure and temperature.     

Timing of the late-glacial climate reversal in the Southern Hemisphere using high-resolution radiocarbon chronology for Kaipo bog, New Zealand

The pattern of climate change in the Southern Hemisphere during the Younger Dryas (YD) chronozone provides essential constraint on mechanisms of abrupt climate change only if accurate, high-precision chronologies are obtained. A climate reversal reported previously at Kaipo bog, New Zealand, had been dated between 13,600 and 12,600 cal yr B.P. and appeared to asynchronously overlap the YD chron, but the chronology, based on conventionally radiocarbon-dated bulk sediment samples, left the precise timing questionable. We report a new high-resolution AMS ¹⁴C chronology for the Kaipo record that confirms the original chronology and provides further evidence for a mid-latitude Southern Ocean cooling event dated between 13,800 and 12,400 cal yr B.P. (2σ range), roughly equivalent to the Antarctic Cold Reversal.     

Reaction relationships of chrome-spinels in igneous rocks — further evidence from the layered intrusions of Rhum and Mull,Inner Hebrides,Scotland

Compositions of chrome-spinels in peridotites from the layered igneous rocks of Rhum and of the Ben Buie intrusion, Mull, show evidence of post-depositional reaction relationships with the cumulus olivine and/or the intercumulus liquid. Some seam-forming spinels in the Ben Buie intrusion are highly aluminous, more so than those in the Rhum intrusion. Occasional zoned spinels, in both intrusions, show enrichment in Al towards their rims. The evidence suggests that the spinel reaction trend involving Cr-Al exchange proceeds in the direction of Al-enrichment. Equilibrium between chrome-spinel and cumulus olivine appears to have been attained rarely, thus limiting the application of the olivine-spinel geothermometer.     

High-alumina basalts of Taupo Volcanic Zone,New Zealand

High-alumina basalt occurs at eight localities in the Taupo Volcanic Zone associated with the Okataina, Maroa and Taupo calderas. At Tarawera the basalt is associated with a series of craters aligned NNE, and at K Trig. a series of scoria cones of similar alignment. On a broader scale the eruptive centres lie on three lines probably corresponding to major faults within the graben.Petrographically the rocks are plagioclase-olivine-augite basalts with varying percentages of each mafic phenocryst. Most are fine-medium grained, but the Ongaroto basalt is coarser-grained, and has a higher modal percentage of olivine. Chemically all are high-alumina basalts. The Ongaroto basalts has lower Al₂O₃ and higher MgO, Ni and Cr, and this, together with petrographic evidence, suggests that the rock is a cumulate.All the basalts are likely to be derived from the mantle, with intrusion into the crust controlled largely by faulting.     

Incorporating hydro-mechanical coupling in an analysis of the effects of rainfall patterns on unsaturated soil slope stability

Rainfall-induced landslides can cause loss of life and damage to property, infrastructure, and the environment. Rainfall patterns affect the pore-water pressure of unsaturated soil slopes, and are related to the slopes’ stability. Four rainfall patterns were chosen to represent natural rainfall patterns for an examination of rainfall infiltration into soil slopes using numerical models incorporating coupled water infiltration and deformation in unsaturated soils. Our analysis showed that rainfall patterns play a significant role in the distribution of the pore-water pressure in soil slopes, and influence the slope stability. The pore-water pressure profile of soil slopes and the factor of safety are affected by the ratio of rainfall intensity and the coefficient of permeability. The depth and shape of the shallow sliding plane of the landslide is closely related to the rainfall pattern; moreover, the results showed a correlation between the factor of safety of the slope and the rainfall intensity. This relationship can be described by a dimensionless rainfall intensity. The nonlinear relationship can be used to estimate the slope stability resulting from rainfall infiltration when the hydro-mechanical coupling in unsaturated soil slopes is considered.