The macroinfauna of the Galician sandy beaches (NW Spain) affected by the Prestige oil-spill

Eighteen sandy beaches were sampled along the 1659 km of the Galician coast (NW Spain) six months after the Prestige oil-spill to study the impact of the fuel and the clean-up activities on the macroinfauna community. A transect was extended at each beach, from above the drift line to below the swash line at five sampled levels; at each level six 0.05 m2 replicates were taken to a depth of 30 cm and sieved through a 1mm mesh, and the organisms collected and preserved. Results were compared with previous data obtained using the same procedures. The macroinfauna was numerically dominated by the amphipod Pontocrates arenarius, the isopod genus Eurydice, the polychaete Scolelepis squamata, and the amphipod Talitrus saltator. As a result of the Prestige oil-spill and the clean-up activities, beach populations were reduced, with Eurydice and S. squamata as the most affected taxa.     

Surface area, porosity and water adsorption properties of fine volcanic ash particles

Our understanding on how ash particles in volcanic plumes react with coexisting gases and aerosols is still rudimentary, despite the importance of these reactions in influencing the chemistry and dynamics of a plume. In this study, six samples of fine ash (<100 m) from different volcanoes were measured for their specific surface area, a_s, porosity and water adsorption properties with the aim to provide insights into the capacity of silicate ash particles to react with gases, including water vapour. To do so, we performed high-resolution nitrogen and water vapour adsorption/desorption experiments at 77 K and 303 K, respectively. The nitrogen data indicated a_s values in the range 1.1–2.1 m²/g, except in one case where a a_s of 10 m²/g was measured. This high value is attributed to incorporation of hydrothermal phases, such as clay minerals, in the ash surface composition. The data also revealed that the ash samples are essentially non-porous, or have a porosity dominated by macropores with widths >500 Å. All the specimens had similar pore size distributions, with a small peak centered around 50 Å. These findings suggest that fine ash particles have relatively undifferentiated surface textures, irrespective of the chemical composition and eruption type. Adsorption isotherms for water vapour revealed that the capacity of the ash samples for water adsorption is systematically larger than predicted from the nitrogen adsorption a_s values. Enhanced reactivity of the ash surface towards water may result from (i) hydration of bulk ash constituents; (ii) hydration of surface compounds; and/or (iii) hydroxylation of the surface of the ash. The later mechanism may lead to irreversible retention of water. Based on these experiments, we predict that volcanic ash is covered by a complete monolayer of water under ambient atmospheric conditions. In addition, capillary condensation within ash pores should allow for deposition of condensed water on to ash particles before water reaches saturation in the plume. The total mass of water vapour retained by 1 g of fine ash at 0.95 relative water vapour pressure is calculated to be ~10^–2 g. Some volcanic implications of this study are discussed.Editorial responsibility: J. Gilbert     

Field assessment of innovative sensor for monitoring of sediment accumulation at inshore coral reefs

Sediment accumulation rate is a frequently required parameter in environmental and management studies, in particular near coral reefs where sediment accumulation can potentially cause severe impact. However, opportunities to obtain accurate sediment accumulation measurements are often limited by a lack of adequate instrumentation, in particular for high temporal resolution monitoring. For instance the traditional use of sediment traps, as the most widespread technique, offers poor temporal resolution (commonly of weeks) besides having significant hydrodynamic shortcomings. Therefore, a new optical backscatter sediment accumulation sensor (SAS) was developed to continuously measure in situ short-term sediment accumulation in sensitive riverine and coastal environments, enabling high temporal and vertical resolution (order of 1 h and with a deposited thickness resolution in the order of 20 microm respectively). This allows investigations of various parameters that influence accumulation: tides, current, waves, rain, or anthropogenic activity such as sediment dumping. This paper briefly describes the SAS and presents three field applications on nearshore coral reefs at Ishigaki Island (Japan), Lihir Island (Papua New Guinea), and Magnetic Island (Australia).     

Effects of 12 years' operation of a sewage treatment plant on trace metal occurrence within a Mediterranean commercial sponge (Spongia officinalis, Demospongiae)

The present field study uses Spongia officinalis for assessing trace metals occurrence in time and space within Mediterranean rocky communities. Nine sites were selected in the Marseille area for studying spatial trends in 12 metal concentrations. Long term changes in 8 metal concentrations were assessed at sites that had been sampled before and 12 years after the opening of a treatment plant. Spongia officinalis highly concentrated all the trace metal surveyed excepted Hg and Cd. The overall contamination level registered provided a classification of the study sites which is congruent with that given by other studies on pollutant accumulation in neighbouring sandy-bottoms or benthic assemblages. Among the metals studied, Fe, Pb, Cr are those that best highlighted a pollution gradient. In the present study, only Cd concentration did not vary in space. Except for Ni, all pollutant concentrations clearly decreased between 1984 and 1999. This very impressive decrease in heavy metal concentrations within the Marseille area represents an indisputable evidence of the improvement of the seawater quality resulting from 12 years' operation of the Marseille sewage plant. Moreover, the significant decrease also recorded in the reference population at Port-Cros might reflect an overall improvement in the seawater quality of the NW Mediterranean.     

Compression of ephemerides

Approximations in the normL ₁ by Chebyshev polynomials are generated to represent astronomical ephemerides over large intervals of time.     

Spin-forbidden resonance multiplets in light elements

We present new laboratory data on the multiplets 2s ^{2 1} S -2s2p ³ P, 2s ²2p ² P - 2s2p ^{2 4} P, and 2s ²2p ^{2 3} P - 2s2p ^{3 5} S in nitrogen, oxygen and fluorine, and discuss theZ-dependence of their wave-numbers. These multiplets are very faint in laboratory light sources, but can become prominent in astrophysical sources of low density. Our results confirm the solar identifications of the nitrogen and oxygen multiplets made by Burtonet al. Predicted positions of the corresponding multiplets in neon are given.     

Collective resonant phenomena on small bodies in the solar system

For both asteroids and meteor streams, and also for comets, resonances play a major role for their orbital evolutions but on different time scales. For asteroids both mean motion resonances and secular resonances not only structure the phase space of regular orbits but are mainly at the origin for the inherent chaos of planet crosser objects.For comets and their chaotic routes temporary trapping into orbital resonances is a well known phenomenon. In addition for slow diffusion through the Kuiper belt resonances are the only candidates for originating a slow chaos.Like for asteroids, resonances with Jupiter play a major role for the orbital evolution of meteor streams. Crossing of separatrix like zones appears to be crucial for the formation of arcs and for the dissolution of streams. In particular the orbital inclination of a meteor stream appears to be a critical parameter for arc formation. Numerical results obtained in an other context show that the competition between the Poynting-Robertson drag and the gravitational interaction of grains near the 2/1 resonance might be very important in the long run for the structure of meteor streams.     

Chlorinated hydrocarbons in the seawater and surface sediments of Blanca Bay,Argentina

In order to characterize our study area and to provide reference values to be used in the future to measure the changes produced by an increase in contamination, the concentrations of chlorinated hydrocarbons have been investigated in fifty-one samples of seawater, taken at four different depths: air-sea interface, surface, one metre and bottom waters, and in twenty-three samples of surface sediments from Blanca Bay, Argentina. Of eleven organochlorine compounds we were looking for (α BHC, lindane, heptachlor, δ BHC. aldrin, heptachlor epoxide, dieldrin, o-p′DDD, p-p′DDD, o-p′DDT and p-p′DDT), seven could be detected in seawater and three in surface sediments with the following mean concentrations: α-BHC=48·2 ng l^?1; lindane=54·2 ng l^?1; heptachlor=45·0 ng l^?1; δ BHC=12·5 ng l^?1; aldrin=61·8 ng l^?1 and ΣDDT=67·0 ng l^?1; and δ BHC=3·2 ng g^?1; lindane=4·2 ng g^?1 and heptachlor=1·0 ng g^?1 for seawater, regarding the surface waters, and sediment samples, respectively.Concentration factors among the different water layers were also studied to see if there was any correlation between chlorinated hydrocarbon contents and the water depths from which the samples were taken. As a mean value, the air-sea interface water contains 18 times more of these compounds than that of the water near the bottom. A comparison of the values corresponding to seawater and surface sediments from our study area with those levels measured in samples from other geographic locations is also presented.With the purpose to detect a relationship between chlorinated hydrocarbon concentrations and the contents of particulate matter (PM) on the one hand, and particulate organic material (POM) on the other hand, four groups of samples containing different amounts of PM and POM, respectively were formed. From a comparison of the results obtained, lindane, heptachlor and δ BHC showed a tendency to lower concentrations in those samples containing little PM whereas α BHC and aldrin remained without important changes. No significant correlation was found between organochlorine levels and contents of POM.     

Far-infrared properties of metallic dust grains

Far-infrared properties of metallic particle are reinvestigated in detail. In the far-infrared region, absorption due to the eddy current generally dominates over that obtained by using the Rayleigh approximation erroneusly. The wavelength dependence of the eddy current term is examined carefully and shown to be less steep than that predicted by the Rayleigh approximation for dust grains larger than 100 nm in radius. It also depends more sensitively on the grain size. A wider temperature distribution is expected corresponding to a given size distribution and hence the emission spectrum becomes less steep than the preductions by the Rayleigh approximation. Iron and graphite particles are investigated as typical interstellar metallic grains. Effects of coating of dielectric materials are also examined. Comparisons with experimental results and with observations are discussed.     

Position and velocity reliability testing in degraded GPS signal environments

Reliability testing, namely receiver autonomous integrity monitoring (RAIM), consists of statistical testing of least-squares residuals of observations, e.g., on an epoch-by-epoch basis aiming towards reliable navigation fault detection and exclusion (FDE). In this paper, classic RAIM and FDE methods are extended with testing of range-rate residuals to find inconsistent velocity solutions in order to contribute to the reliability of the system with special focus on degraded signal environments. Reliability enhancement efforts discussed include a Backward-FDE scheme based on statistical outlier detection and an iteratively reweighted robust estimation technique, a modified Danish method. In addition, measurement weighting assigned to code and Doppler observations is assessed in the paper in order to allow fitting a priori variance models to the estimation processes. The schemes discussed are also suitable in terms of computational convenience for a combined GPS/Galileo system. The objective of this paper is to assess position and velocity reliability testing and enhancement in urban and indoor conditions and to analyze the navigation accuracy conditions with high sensitivity GPS (HSGPS) tests. The results show the necessity of weighted estimation and FDE for reliability enhancement in degraded signal-environment navigation.