Implications for behavior of volatile elements during impacts—Zinc and copper systematics in sediments from the Ries impact structure and central European tektites

Moldavites are tektites genetically related to the Ries impact structure, located in Central Europe, but the source materials and the processes related to the chemical fractionation of moldavites are not fully constrained. To further understand moldavite genesis, the Cu and Zn abundances and isotope compositions were measured in a suite of tektites from four different substrewn fields (South Bohemia, Moravia, Cheb Basin, Lusatia) and chemically diverse sediments from the surroundings of the Ries impact structure. Moldavites are slightly depleted in Zn (~10–20%) and distinctly depleted in Cu (>90%) relative to supposed sedimentary precursors. Moreover, the moldavites show a wide range in δ⁶⁶Zn values between 1.7 and 3.7‰ (relative to JMC 3‐0749 Lyon) and δ⁶⁵Cu values between 1.6 and 12.5‰ (relative to NIST SRM 976) and are thus enriched in heavy isotopes relative to their possible parent sedimentary sources (δ⁶⁶Zn = ?0.07 to +0.64‰; δ⁶⁵Cu = ?0.4 to +0.7‰). In particular, the Cheb Basin moldavites show some of the highest δ⁶⁵Cu values (up to 12.5‰) ever observed in natural samples. The relative magnitude of isotope fractionation for Cu and Zn seen here is opposite to oxygen‐poor environments such as the Moon where Zn is significantly more isotopically fractionated than Cu. One possibility is that monovalent Cu diffuses faster than divalent Zn in the reduced melt and diffusion will not affect the extent of Zn isotope fractionation. These observations imply that the capability of forming a redox environment may aid in volatilizing some elements, accompanied by isotope fractionation, during the impact process. The greater extent of elemental depletion, coupled with isotope fractionation of more refractory Cu relative to Zn, may also hinge on the presence of carbonyl species of transition metals and electromagnetic charge, which could exist in the impact‐induced high‐velocity jet of vapor and melts.     

GPS for real-time earthquake source determination and tsunami warning systems

We identify the key design aspects of a GPS-based system (and in the future, GNSS-based systems) that could contribute to real-time earthquake source determination and tsunami warning systems. Our approach is based on models of both transient and permanent displacement of GPS stations caused by large earthquakes, while considering the effect of GPS errors on inverted earthquake source parameters. Our main conclusions are that (1) the spatial pattern, magnitude, and timing of permanent displacement of GPS stations can be inverted for the earthquake source and so predict the 3D displacement field of the ocean bottom, thus providing the initial conditions for tsunami models, and (2) there are no inherently limiting factors arising from real-time orbit and positioning errors, provided sufficient near-field GPS stations are deployed. This signal could be readily exploited by GPS networks currently in place, and will be facilitated by the IGS Real-Time Project as it comes to fruition.     

Flow dynamics,sedimentation and erosion of glacial lake outburst floods along the Middle Pleistocene Scandinavian Ice Sheet (northern central Europe)

During the Middle Pleistocene late Saalian glaciation of northern central Europe numerous pro‐glacial lakes formed along the southwestern margin of the Scandinavian Ice Sheet. Little is known about the drainage history of these lakes, the pathways of glacial lake outburst floods and their impacts on erosion, sedimentation and landscape evolution. This study investigated the impact of the late Saalian Weser and Münsterland Lake (Germany) outburst floods. In particular, we reconstructed the routing and flow dynamics of the lake outburst flood and analysed the flood related sediments. We employed one‐dimensional hydraulic modelling to calculate glacial lake outburst flood hydrographs. We modelled the flow pathway and local flow conditions along the pathway based on the boundary conditions of two different hydrographs and two different ice‐margin positions. The modelling results were compared with geomorphological and sedimentological field data in order to estimate the magnitude and impact of the flood on erosion and sedimentation. Two major lake drainage events are reconstructed for the study area, during which approximately 90–50 km³ of water was released. Modelling results indicate that the lake outburst floods created a high‐energy flood wave with a height of 35–50 m in confined valley areas that rapidly spread out into the Lower Rhine Embayment eventually flowing into the North Sea basin. The sedimentary record of the outburst floods comprises poorly sorted coarse‐grained gravel bars, long‐wavelength bedforms and sandy bedforms deposited by supercritical and subcritical flows. Some parts of the sandy flood deposits are rich in reworked mammoth bones or mammoth and horse teeth, pointing to reworking of older fluvial sediments, hydraulic concentration and subsequent re‐sedimentation of vertebrate remains. These deposits are preserved in sheltered areas or at high elevations, well above the influence of postglacial fluvial erosion. The flood‐related erosional features include up to 80‐m‐deep scour pools, alluvial channels and streamlined hills.     

Nonlinear adaptive regression predictors based on singular decomposition

Summary The paper deals with a non-linear regression model, linear in parameters. The least-squares adaptation method has been used to determine the model parameters. The conditionality problem in solving equations, which follows from the dependent predictors, has been suppressed by singular decomposition. This model is especially suitable for treating meteorological problems because non-linear processes, e.g. changes of air masses, changes of circulation patterns, etc., can be treated. The model has been tested in connection with the forecast of daily maximum and minimum temperatures. The RMS error lies in the range of 1–2°C, if the principal PPM is supposed.

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Резюме Оnuсывеamся мamемamuческuŭ annaрam нелuнеŭноŭ ре?rt;рессuонноŭ мо?rt;елu, лuнеŭноŭ оmнос umельно naрaмеmров. Для оnре?rt;еленuя naрaмеmров мо?rt;елu uсnользуеmся меmо?rt; нauменьщuх квa?rt;рamов. Плохaя обусловленносmь сuсmемы нauменьщuх квa?rt;рamов, коmорaя вызвaнa взauмноŭ зaвuсuмосmью nре?rt;uкmоров, всmрaняеmся nрu nомощu сuн?rt;улярноŭ ?rt;екомnозuцuu. Эma мо?rt;ель nо?rt;хо?rt;um ?rt;ля nрuмененuя в меmеороло?rt;uu, maк кaк онa nозволяеm рaбоmamь с нелuнеŭносmямu, кaк нanрuмер uзмененuе воз?rt;ущных мaсс, uзмененuе хaрaкmерa цuркуляцuu u m. n. Мо?rt;ель nроверяеmся нa nро?rt;нозе ?rt;невных мuнuмaльных u мaксuмaльных mемnерamур. Сре?rt;няя квa?rt;рamuческaя ошuбкa нaхо?rt;umся в uнmе?rt;рaле оm 1 ?rt;о 2° (uсnользовaн nрuнцun РРМ).

     

A concept for global access to information on geographical databases

Monitoring of the ecological as well as economical aspects of the planet Earth will in future require more sophisticated data obtaining systems (e. g. satellites) and data processing devices (e. g. GIS). In order to process the great amount of data, detailed information on geographical databases has to be provided in an easy way. In this paper a concept of an information system on geographical databases is presented which encompasses a centrally managed international directory with summary information as well as local information interfaces geographical databases. An information interface provides detailed information on the extent, structure and geographical meaning of the data stored in the geographical database belonging to it. To describe this information a conceptual scheme, based on an object oriented approach, is developed.     

Some possibilities of predicting radio wave absorption in the lower ionosphere

Summary An attempt is made to show possible ways of predicting radio wave absorption in the midlatitude lower ionosphere using relations between absorption and the intensity of solar ionizing radiation and/or common solar activity indices, and between absorption and f₀F2.

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aa mu nuau nu a¶rt;u ¶rt;um u u a mu ¶rt; nu u umum uuu uu (uu uu u¶rt;au amumu) u ¶rt; nu u f₀F2.

     

Deep structure of the bohemian massif from phase velocities of Rayleigh and Love waves

Summary Phase velocities of Rayleigh and Love waves have been measured between the broadband seismic stations KHC (Kaperské Hory, South Bohemia) and KSP (Ksi, Lower Silesia), a profile that nearly coincides with the Interactional DSS Profile VII. The data for both wave types were separately inverted into models of shear-wave velocity versus depth. Novotný's model KHKS 82[1] for the DSS Profile VII was used as a start model. While the crustal section of Novotný's model is compatible with both of our data sets, our Rayleigh-wave data require smaller shear-wave velocities, on the average by 0.24 km/s, in the top 180 km of the mantle. The average difference between Novotný's model and our Love-wave model in that depth range is only 0.06 km/s. If our identification of the observed Love waves as the fundamental mode is correct, this result indicates the presence of polarization anisotropy in the uppermost mantle.

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u a mu u a ¶rt; unu uuu mauu (an , a u) u S (, ua uu). u - S nuuum mmmm ¶rt;a¶rt; nu VII . a ¶rt; u mun m¶rt; umua ¶rt;u auumu mu nn mu. am mam¶rt;u a unaa ¶rt; S 82 m[1] ¶rt; nu VII . a am ¶rt;u m aua uu aau au ¶rt;a, ¶rt;a au ¶rt;a ¶rt; mm uu m nn — ¶rt; a 0,24 / 180 uma amuu. ¶rt;a aua ¶rt; ¶rt; m u a ¶rt; ¶rt; a m ¶rt;uanau n¶rt;mam 0,06 /. u aa u¶rt;muuau a¶rt;a a a ¶rt;ama ¶rt;a m nau, m mm mam u¶rt;ummm numuu nuau aumnuu amuu.

     

Some new aspects on the problem of CO2 and climate under particular consideration of the biosphere

A re-examination of the biosphere, in particular of the tropical rain forests, is necessary since there are some contradictions in our present knowledge about carbon fluxes and carbon storage in various reservoirs. Traditional land-use systems as well as modern exploitation methods in the tropical rain forest areas need not be necessarily of such a magnitude that the global carbon cycle would undergo a major upset or even a climatic catastrophe. This conclusion is primarily based on the high photosynthesis rates of the humid tropics and on the very important role of tropical river systems for carbon transport between terrestrial and aquatic ecosystems.After careful consideration of all known facts this paper comes to the conclusion that 2 × 10¹⁵ g/yr C are released to the atmosphere due to deforestation and burning in the tropical rain forest belt. The same amount is probably being fixed in the temperate forests and the northern ecosystems. A possible steady balance of all terrestrial ecosystems would, therefore, be the result of a particular historical constellation whereby a destruction of vegetation in the tropics would occur simultaneously to an increase of phytomass and also to a humus and peat accumulation in temperate and northern ecosystems.