Natural Arsenic Attenuation via Metal Arsenate Precipitation in Soils Contaminated with Metallurgical Wastes: I. Wet Chemical and Thermodynamic Evidences

Arsenic from natural and anthropogenic sources is a worldwide contaminant of aqueous environments, such as groundwater and soils. The present investigation was performed on Mexican soils contaminated with residues from metallurgical processes that have shown a natural As attenuation. Experimental aqueous arsenic extractions in these were successfully simulated for almost half of the soil samples using a database updated for all known metal arsenate formation constants, revealing the predominance of solubility-controlled As mobility via Pb, mixed Pb–Cu, and Ca arsenate solid formation. The relatively low total Fe/As ratios (2–13 w/w) present in the soils studied, together with the high and equivalent contents of As, Pb, and Cu in these, favor the precipitation process over As(V) adsorption to Fe oxides, despite a 2% average Fe content in the soils studied. Under these conditions bicarbonate was found to be a highly unsuitable extractant due to its indirect As release from the solid arsenates, via heavy metal carbonate precipitation processes.     

Evaluation of recent hydro-climatic changes in four tributaries of the Niger River Basin (West Africa)

West Africa experienced severe drought during the 1970s and 1980s, posing a threat to water resources. A wetter climate more recently suggests recovery from the drought. The Mann-Kendall trend and Theil-Sen’s slope estimator were applied to detect probable trends in weather elements in four sub-basins of the Niger River Basin between 1970 and 2010. The cross-entropy method was used to detect breakpoints in rainfall and runoff, Spearman’s rank test for correlation between the two, and cross-correlation analysis for possible lags. Results showed an overall increase in rainfall and runoff and a decrease in sunshine duration. Spearman’s coefficients suggest significant (5%) moderate to strong rainfall–runoff correlation for three sub-basins. A significant lower runoff was observed around 1979, with a rainfall break around 1992, indicating possible cessation of the drought. Temperatures increased significantly, at 0.02–0.05°C year^-1, with a negative wind speed trend for most stations. Half of the stations exhibited an increase in potential evapotranspiration.

EDITOR M.C. Acreman

ASSOCIATE EDITOR Not assigned     

Advective heat transfer and fabric development in a shallow crustal intrusive granite — the case of Proterozoic Vellaturu granite,south India

Syntectonic plutons emplaced in shallow crust often contain intermediate-to low-temperature deformation microstructures but lack a high-temperature, subsolidus deformation fabric, although the relict magmatic fabric is preserved. The Proterozoic Vellaturu granite emplaced at the eastern margin of the northern Nallamalai fold belt, south India during the late phase of regional deformation has a common occurrence of intermediate-to low-temperature deformation fabric, superimposed over magmatic fabric with an internally complex pattern. But high-T subsolidus deformation microstructure and fabric are absent in this pluton. The main crystal plastic deformation and fluid enhanced reaction softening was concentrated along the margin of the granite body. Resulting granite mylonites show Y-maximum c-axis fabric in completely recrystallized quartz ribbonds, dynamic recrystallization of perthites, and myrmekite indicative of fabric development under intermediate temperature (∼ 500–400°C). The weakly-deformed interior shows myrmekite, feldspar microfracturing and limited bulging recrystallization of quartz. The abundance of prism subgrain boundaries is indicative of continuing deformation through low-temperature (∼ 300°C). The relative rates of cooling influenced by advective heat transfer and deformation of the pluton seem to control the overall subsolidus fabric development. The rapid advective heat transfer from the interior in the early stages of subsolidus cooling was followed by slow cooling through intermediate temperature window as a well-developed phyllosilicate rich mylonitic skin around the granite body slowed down conductive heat loss. Low-T crystal plastic deformation of quartz was effected at a late stage of cooling and deformation of the shallow crustal granite body emplaced within the greenschist facies Nallamlai rocks.     

Dynamical evolution properties of debris flows controlled by different mesh-sized flexible net barriers

Because the flexible net barrier is a gradually developed open-type debris-flow counter-measure, there are still uncertainties in its design criterion. By using several small-scale experimental flume model tests, the dynamical evolution properties of debris flows controlled by large and small mesh-sized (equal to D₉₀ and D₅₀, respectively) flexible net barriers are studied, including the debris flow behaviors, segregation, and permeability of sediments, as well as the energy absorption rates and potential overtopping occurring when debris flows impact the small mesh-sized one. Experimental results reveal that (a) two sediment deposition patterns are observed depending on variations in debris flow textures and mesh sizes; (b) the aggregation against flexible net barriers is dominated by flow dynamics; (c) the segregation and permeable functions of the barrier are determined by the mesh size, concentration, and flow dynamics; and (d) the smaller mesh-sized flexible net barrier tends to be more efficient in restraining more turbulent debris flows and can absorb greater rate of kinematic energy, and finally, the great kinematic energy dissipation that occurs when secondary debris flows interact with the post-deposits in front of the small mesh-sized flexible net barrier is believed to cause the failure of overtopping phenomenon. The mesh size is concluded to be the decisive parameter that should be associated with debris flow textures to design the control functions of flexible net barriers.     

Effects of tilling methods on soil penetration resistance,organic carbon and water stable aggregates in a vineyard of semiarid Mediterranean environment

Tillage, especially in semiarid Mediterranean environment, enhances the mineralization process of soil organic matter (SOM) and, in turn, decreases aggregate stability. Furthermore, continuous tillage leads to the formation of plough pan beneath the tilled layer. In the present study, we investigated the effect of an innovative self-propelled machine (spading machine, SM) for shallow tillage on SOM, water stable aggregates (WSA) and soil penetration resistance (PR). Such effects were compared to those of chisel plough (CP), rotary tiller (RT) and no tillage (NT). Each tilling method was applied up to a depth of 15 cm, whereas in NT only a brush cutter was used for weed control. Soil analyses were performed at the start of the experiment (March 2009, T0), in April 2010 (T1), May 2012 (T3), and June 2014 (T5) at both 0–15 and 15–30 cm. Compared to T0, soil PR increased with time in all the treatments and generally followed the order SM?<?RT?<?CP?<?NT. In soil tilled with the SM, soil PR never exceeded 2.5 MPa that was demonstrated to be a critical value for root elongation, and no evidence of the formation of plough pan beneath the tilled layer was observed. SOC as well as water content and WSA were higher in SM compared with CP and RT. In conclusion, the spading machine was proved to be more efficient in lowering the soil PR and in avoiding the formation of the plough pan. Furthermore, SM increased SOC and WSA.     

Adapting a texture synthesis algorithm for conditional multiple point geostatistical simulation

Computer vision provides several tools for analyzing and simulating textures. The principles of these techniques are similar to those in multiple-point geostatistics, namely, the reproduction of patterns and consistency in the results from a perceptual point of view, thus, ensuring the reproduction of long range connectivity. The only difference between these techniques and geostatistical simulation accounting for multiple-point statistics is that conditioning is not an issue in computer vision. We present a solution to the problem of conditioning simulated fields while simultaneously honoring multiple-point (pattern) statistics. The proposal is based on a texture synthesis algorithm where a fixed search (causal) pattern is used. Conditioning is achieved by adding a non-causal search neighborhood that modifies the conditional distribution from which the simulated category is drawn, depending on the conditioning information. Results show an excellent reproduction of the features from the training image, while respecting the conditioning information. Some issues related to the data structure and to the computer efficiency are discussed.     

Precursor times of abnormal <Emphasis Type="Italic">b</Emphasis>-values prior to mainshocks

Seismic observations exhibit the presence of abnormal b-values prior to numerous earthquakes. The time interval from the appearance of abnormal b-values to the occurrence of mainshock is called the precursor time. There are two kinds of precursor times in use: the first one denoted by T is the time interval from the moment when the b-value starts to increase from the normal one to the abnormal one to the occurrence time of the forthcoming mainshock, and the second one denoted by T _p is the time interval from the moment when the abnormal b-value reaches the peak one to the occurrence time of the forthcoming mainshock. Let T* be the waiting time from the moment when the abnormal b-value returned to the normal one to the occurrence time of the forthcoming mainshock. The precursor time, T (usually in days), has been found to be related to the magnitude, M, of the mainshock expected in a linear form as log(T)?=?q?+?rM where q and r are the coefficient and slope, respectively. In this study, the values of T, T _p , and T* of 45 earthquakes with 3?≤?M?≤?9 occurred in various tectonic regions are compiled from or measured from the temporal variations in b-values given in numerous source materials. The relationships of T and T _p , respectively, versus M are inferred from compiled data. The difference between the values of T and T _p decreases with increasing M. In addition, the plots of T*/T versus M, T* versus T, and T* versus T-T* will be made and related equations between two quantities will be inferred from given data.     

Analytical investigation of bidirectional ductile diaphragms in multi-span bridges

In the AASHTO Guide Specifications for Seismic Bridge Design Provisions,ductile diaphragms are identified as Permissible Earthquake-Resisting Elements(EREs),designed to help resist seismic loads applied in the transverse direction of bridges.When adding longitudinal ductile diaphragms,a bidirectional ductile diaphragm system is created that can address seismic excitations acting along both the bridge’s longitudinal and transverse axes.This paper investigates bidirectional ductile diaphragms with Buckling Restrained Braces(BRBs)in straight multi-span bridge with simply supported floating spans.The flexibility of the substructures in the transverse and longitudinal direction of the bridge is considered.Design procedures for the bidirectional ductile diaphragms are first proposed.An analytical model of the example bridge with bidirectional ductile diaphragms,designed based on the proposed methodology,is then built in SAP2000.Pushover and nonlinear time history analyses are performed on the bridge model,and corresponding results are presented.The effect of changing the longitudinal stiffness of the bidirectional ductile diaphragms in the end spans connecting to the abutment is also investigated,in order to better understand the impact on the bridge’s dynamic performance.     

Discovery of the Early Mesozoic granulite xenoliths in North China Craton

The discovery of the Early Mesozoic basic granulite xenoliths in the Harqin area of the Inner Mongolia Autonomous Region (for short Inner Mongolia) is reported for the first time in this paper. According to the mineral assemblage the xenoliths include two-pyroxene granulite, clinopyroxene granulite, and hypersthene granulite. Their protolytes are mainly gabbroite rocks. The zircon U?Pb age of the granulite xenoliths is 251 Ma, and K?Ar age of the hypersthene is 229 Ma. They represent the times of metamorphism and cooling of the granulite facies respectively. The host rock of the xenoliths is Early Mesozoic biotite-quartz diorites, whose whole-rock K?Ar age is 219 Ma. This discovery confirms existence of an Early Mesozoic underplating in the North China Craton, which is of much importance in research on the Early Mesozoic mantle-crust interaction in the concerned area.     

Thin accretion disc with a corona in a central magnetic field

We study the steady-state structure of an accretion disc with a corona surrounding a central, rotating, magnetized star. We assume that the magneto-rotational instability is the dominant mechanism of angular momentum transport inside the disc and is responsible for producing magnetic tubes above the disc. In our model, a fraction of the dissipated energy inside the disc is transported to the corona via these magnetic tubes. This energy exchange from the disc to the corona which depends on the disc physical properties is modified because of the magnetic interaction between the stellar magnetic field and the accretion disc. According to our fully analytical solutions for such a system, the existence of a corona not only increases the surface density but reduces the temperature of the accretion disc. Also, the presence of a corona enhances the ratio of gas pressure to the total pressure. Our solutions show that when the strength of the magnetic field of the central neutron star is large or the star is rotating fast enough, profiles of the physical variables of the disc significantly modify due to the existence of a corona.