From aqueous solution to solid solutions: A process oriented review of the work performed within the FUNMIG project

The Fundamentals of Radionuclide Migration (FUNMIG) project was organised in some Research and Technological Development Components (RTDCs) integrated by a number of Work Packages (WP’s) attempting to cover the key migration processes at different scales (laboratory to repository) and in different geological media, mainly clay and granite, but also some salt rock related work was performed. The main RTDCs of interest for this review paper are numbers 1 and 2, which concerned laboratory studies of well-established and less-established migration processes. Some additional interesting outcomes arise also from RTDCs 3, 4 and 5 devoted to the upscaling and applicability of migration processes to clay, granite and salt rock environments, respectively. This review discusses the contribution of the various parts of the FUNMIG project in the process oriented context of understanding the mechanistic approximation to what can be seen as the final and thermodynamically stable stage of the long chain of processes which are covered under the general term of sorption and that culminate in the formation of solid solutions.     

A DUAL mission for nuclear astrophysics

DUAL will study the origin and evolution of the elements and explores new frontiers of physics: extreme energies that drive powerful stellar explosions and accelerate particles to macroscopic energies; extreme densities that modify the laws of physics around the most compact objects known; and extreme fields that influence matter in a way that is unknown on Earth. The variability of these extreme objects requires continuous all-sky coverage, while detailed study demands an improvement in sensitivity over previous technologies by at least an order of magnitude. The DUAL payload is composed of an All-Sky Compton Imager (ASCI), and two optical modules, the Laue-Lens Optic (LLO) and the Coded-Mask Optic (CMO). The ASCI serves dual roles simultaneously, both as an optimal focal-plane sensor for deep observations with the optical modules and as a sensitive true all-sky telescope in its own right for all-sky surveys and monitoring. While the optical modules are located on the main satellite, the All-Sky Compton Imager is situated on a deployable structure at a distance of 30?m from the satellite. This configuration not only permits to maintain the less massive payload at the focal distance, it also greatly reduces the spacecraft-induced detector background, and, above all it provides ASCI with a continuous all-sky exposure.     

Puerto Lápice eucrite fall: Strewn field,physical description,probable fireball trajectory,and orbit

Abstract— The fall of the Puerto Lápice eucrite occurred on May 10, 2007, at 17 h 57 m 30 ± 30 s UTC. Its daylight fireball was witnessed by hundreds of people from Spain, and produced a meteorite fall associated with a large strewn field of fragments. There were no direct pictures of the fireball, but several pictures of the fireball's train were taken from different locations in Spain. Additional theodolite calibrations of visual records were made in order to find the most probable fireball trajectory based on the available data. The shape of the meteorite strewn field was considered as well. Although the orbit of the Puerto Lápice meteoroid could not be computed due to the absence of velocity data, we assumed a likely range of geocentric velocities and computed a range of possible orbits. All solutions show that the body was in an Apollo‐type orbit, with low inclination and perihelion distance just below 1 astronomical unit (AU). This is the first case that an orbit can be discussed for an HED meteorite fall.     

Fluorite dissolution at acidic pH: In situ AFM and ex situ VSI experiments and Monte Carlo simulations

Dissolution of the fluorite (1 1 1) cleavage surface was investigated by means of in situ atomic force microscopy (AFM) and ex situ vertical scanning interferometry (VSI) experiments at pH range 1-3 in HCl solutions. Surface retreat was quantified at different pH values, yielding dissolution rates that were used to derive an empirical rate law for fluorite dissolution:

     

Chrysophyte cyst relationships to water chemistry in Pyrenean lakes (NE Spain) and their potential for environmental reconstruction

Chrysophyte cysts were identified from the surface sediment of 105 mountain lakes in the Pyrenees (NE Spain), and their statistical relationship to water chemistry was examined using canonical correspondence analysis (CCA). The chemical parameters that explained significant and independent amounts of variability were alkalinity, pH, potassium, nitrate and magnesium. In a CCA using these parameters, the first canonical axis was related to a gradient of alkalinity and pH, which reflected the varying nature of the watershed bedrock in the Pyrenees, while the second axis was correlated with potassium (negatively) and nitrate (positively). The potential for environmental reconstructions of the five chemical parameters was further studied by: (i) analyzing the distribution of optima and tolerances calculated by weighted-averaging (WA); (ii) carrying out detrended canonical correspondence analysis (DCCA) with a single environmental variable; and (iii) examining the performance of WA-PLS transfer functions. Acceptable transfer functions were obtained for alkalinity, pH and nitrate. However, for potassium and magnesium the tolerance of cysts was too broad and the distribution of optima too skewed, respectively. The possibility of reconstructing nitrogen-related issues using chrysophyte cysts is particularly interesting because of the lack of direct chemical records of nitrogen compounds in sediments. Nitrate reconstructions using transfer functions may be complemented by a holistic reconstruction using partial CCA, where, after subtracting the effects of other chemicals, samples are ordered on a plain defined by potassium and nitrate. This ordination could show down-core trends in lake productivity and renewal time.     

Quantitative assessment of the residual risk in a rockfall protected area

Quantitative Risk Assessment (QRA) has become an indispensable tool for the management of landslide hazard and for planning risk mitigation measures. In this paper we present the evaluation of the rockfall risk at the Solà d’Andorra slope (Andorra Principality) before and after the implementation of risk mitigation works, in particular, the construction of protective fences. To calculate the risk level we have (i) identified the potential rockfall release areas, (ii) obtained the volume distribution of the falling rocks, (iii) determined the frequency of the rockfall events, and (iv) performed trajectographic analysis with a 3D numerical model (Eurobloc) that has provided both the expected travel distances and the kinetic energy of the blocks. The risk level at the developed area located at the foot of the rock cliff has been calculated taking into account the nature of the exposed elements and their vulnerability. In the Forat Negre basin, the most dangerous basin of the Solà d’Andorra, the construction of two lines of rockfall protection fences has reduced the annual probability of loss of life for the most exposed person inside the buildings, from 3.8×10⁻⁴ to 9.1×10⁻⁷ and the societal risk from 1.5×10⁻² of annual probability of loss of life to 1.2×10⁻⁵.     

An integrated thermodynamic mixing model for sphalerite geobarometry from 300 to 850°C and up to 1 GPa

An asymmetric, Margules-type, solid solution model was used to model the mixing behavior of Fe-Zn sphalerites. The model is based on an analysis of experimental results from fifteen independent data sources. After a careful, stepwise, analysis of the available runs, the solid solution model was constrained using a refined experimental database of 279 experiments which were simultaneously regressed to obtain the excess parameters and a general geobarometric equation. The model indicates that, when pressures are low, the value of γ_FeS^Sph, which is always greater than one, is higher at low FeS contents and an increase in temperature causes it to decline. However, for certain compositions γ_FeS^Sph values might be slightly less at low T than at high T. This behavior is corrected when pressure increases, regardless of the composition. The excess Gibbs free energy has positive values at any P&T while it is asymmetric. Pressure increases the value of the excess free energy. On the other hand, the Gibbs free energy of mixing is always negative, with a single minimum that tends to move towards Fe-poorer compositions as the pressure goes up. An increase in temperature leads to a more negative Gibbs free energy mixing function suggesting that increasingly Fe-poorer sphalerite would be expected at high temperatures and pressures. The application of the solid solution model to a selection of case-studies provided results which are consistent with independent pressure estimates. However, the pressure determinations for sphalerite + pyrite + pyrrhotite and sphalerite + pyrrhotite assemblages are very sensitive to uncertainties in the composition of the phases involved and, to a lesser extent, to temperature. The results of the application of the model to a field case (scheelite-mineralized Hercynian veins from the Central Pyrenees) were also consistent when compared with independent pressure-constraining silicate assemblages. Thus, the solid solution model described in this paper provides a workable framework with which to compute the pressures of the formation of rocks over a wide range of geological conditions.