Linear system techniques applied to the Fuenmayor Karst Spring, Huesca (Spain)

Black box identification techniques are very useful tools to study the relationship between rainfall and the discharge of karst aquifers. Autocorrelation, cross-correlation, cross-spectral, impulse response identification (Wiener–Hopf and error minimization methods) and parametric identification of transfer functions techniques have been used by different authors. A review of these techniques has been realized to assess the possibilities and limitations. The reviewed techniques are applied to a time rainfall–discharge series of Fuenmayor karst spring, (southern central Pyrenees, Spain) to establish the relative quality of the obtained models. The quality is evaluated with the Nash–Sutcliffe model efficiency coefficient. In addition, effective rainfall has been used to improve the performance of every model. The whitening technique has been used in the cross-correlation technique with good results. The studied spring shows a Fontestorbes type behavior. The linearity of the system has been analyzed by the coherence function. Fuenmayor has an acceptable linear response, except for high frequency events. The parametric identification provides the best efficiency value E = 0.8164 and provides a proper transfer function, with five parameters (one zero, two poles, the gain and the delay). The prediction power of this transfer function is validated with another time series, with an efficiency value of E = 0.7904.     

Technical, financial and location criteria for the design of land application system treatment

Conventional water treatments when downsized to cover the demands of small and scattered populations are costly and ineffective. In fact, many small towns cannot afford the high average treatment costs nor provide the skill and complex management requirements. Even when these facilities are available, waste water might not be properly treated. Land application system treatments (LAST) have been shown to be preferable on the basis of their technical effectiveness and financial viability. The recently approved Spanish regulations (RDL 1620/2007, pp 50369–50661) represent an opportunity for the implementation of well-designed LASTs. This paper presents an assessment methodology for the design of LASTs by combining technical, financial and location criteria. The method is applied to the design of LASTs to cover the water disposal demand of twelve municipalities located within the protected natural landscape, and surrounding areas of ‘El Rebollar’, Salamanca, Spain.     

The state of the environment in Mexico

The present work evaluates the state of the environment in Mexico based on indicators of the present status of the country’s natural resource management, social and economical conditions and anthropogenic modifications. The Mexican environment is interpreted as a spatially open system having a historical character that is essentially determined by the continual interaction between nature, society and economy. The landscape approach is followed, considering as units of territorial analysis each one of the 145 biophysical environmental units included in the national physiographic regionalization. The assessment of 16 indicators for each biophysical environmental unit was made considering their regional environmental integrity problems, the degree of disarticulation of their structure and function, and the alteration of their territorial structure, all of which determine whether or not they accomplish their environmental functions and achieve environmental stability. The classification of the state of the environment included 5 categories in 8 combinations represented in the map of the state of the environment in Mexico for the year 2008. The map shows that nearly 47.10% of the country’s surface has an environmental status ranging between unstable and critical, the problematic areas being mostly concentrated in the southeast and center of the national territory.     

Detection and mapping of burnt areas from time series of MODIS-derived NDVI data in a Mediterranean region

Moderate resolution remote sensing data, as provided by MODIS, can be used to detect and map active or past wildfires from daily records of suitable combinations of reflectance bands. The objective of the present work was to develop and test simple algorithms and variations for automatic or semiautomatic detection of burnt areas from time series data of MODIS biweekly vegetation indices for a Mediterranean region. MODIS-derived NDVI 250m time series data for the Valencia region, East Spain, were subjected to a two-step process for the detection of candidate burnt areas, and the results compared with available fire event records from the Valencia Regional Government. For each pixel and date in the data series, a model was fitted to both the previous and posterior time series data. Combining drops between two consecutive points and 1-year average drops, we used discrepancies or jumps between the pre and post models to identify seed pixels, and then delimitated fire scars for each potential wildfire using an extension algorithm from the seed pixels. The resulting maps of the detected burnt areas showed a very good agreement with the perimeters registered in the database of fire records used as reference. Overall accuracies and indices of agreement were very high, and omission and commission errors were similar or lower than in previous studies that used automatic or semiautomatic fire scar detection based on remote sensing. This supports the effectiveness of the method for detecting and mapping burnt areas in the Mediterranean region.     

Significance of ancient sulfide PGE and Re–Os signatures in the mantle beneath Calatrava,Central Spain

Spinel lherzolite and wehrlite xenoliths from the Cenozoic Calatrava volcanic field carry the geochemical imprint of metasomatic agents that have affected the subcontinental lithospheric mantle beneath Central Iberia. Some xenoliths (mainly wehrlites) were enriched in REE, Sr, P, and CO₂ by silicic-carbonate-rich metasomatic melts/fluids, while others record the effects of subduction-related hydrous silicate fluids that have precipitated amphibole and induced high Ti/Eu in primary clinopyroxene. The petrographic observations and geochemical data suggest that interstitial glass in the xenoliths represent the quenched products of Si-rich melts that infiltrated the mantle peridotite shortly before the entrainment of the xenoliths in the host magmas that erupted ca 2 million years ago. During their infiltration, the metasomatic melts reacted with peridotite, resulting in silica enrichment, while remobilizing grains of iron-rich monosulfide solid solution (Fe-rich Mss) initially enclosed in, or intergranular to, primary olivine and pyroxenes. In situ laser ablation inductively coupled plasma-mass spectrometry analysis of single sulfide grains reveals that the Fe-rich Mss in glass shows platinum-group element (PGE) patterns and ¹⁸⁷Os/¹⁸⁸Os compositions identical to the Fe-rich Mss occurring as inclusions in, or at grain boundaries of primary silicates. Moreover, independent of its microstructural position, Fe-rich Mss exhibits PGE and ¹⁸⁷Os/¹⁸⁸Os signatures typical of Mss either residual after partial melting or crystallized directly from sulfide melts. Our findings reveal that young metasomatic melt(s)/fluid(s) may carry remobilized sulfides with PGE and Os-isotopic signatures identical to those of texturally older sulfides in the peridotite xenolith. These sulfides thus still provide useful information about the timing and nature of older magmatic events in the subcontinental mantle.     

FTIR spectroscopy of Ti-chondrodite,Ti-clinohumite,and olivine in deeply subducted serpentinites and implications for the deep water cycle

Separated olivine grains from a deeply subducted serpentinized wehrlite (Changawuzi in the western Tianshan ultrahigh-pressure belt, China) were analysed with unpolarized transmission FTIR and the Ti contents were determined using LA-ICP-MS. The major bands in the olivine spectra display striking similarities to Ti-clinohumite and are interpreted as OH in lamellae. The quantification of the water content in lamellae requires calibration of the IR-absorption for such bands. We have obtained a new absorption coefficient for Ti-clinohumite of 0.125+/?0.017 ppm cm² based on polarized FTIR measurements on three orthogonal sections through a large single crystal of Ti-clinohumite from Val Malenco, which has a known water content of 1.53 wt%. The resulting water content in olivine using this calibration factor ranges from 440 to 2,600 ppm and correlates positively with the Ti content that ranges from 130 to 1,400 ppm. For the quantification of the water content in Ti-chondrodite and Ti-clinohumite that are associated with olivine, we developed a new method using attenuated total reflectance FTIR spectroscopy. Ti-chondrodite and Ti-clinohumite display similar IR bands at ~3,562, 3,525 and ~3,583–3,586 cm^?1. As in olivine, the water content and Ti content correlate in both Ti-clinohumite and Ti-chondrodite, indicating an intergrowth of these minerals, which has been confirmed by TEM analyses. Our results confirm previous suggestions that there is a strong correlation between the Ti content of ultramafic rocks and their capacity to transport water to the deeper mantle in subduction zones beyond conditions where hydrous phases are stable.     

The challenge of dating early pleistocene fossil teeth by the combined uranium series–electron spin resonance method: the Venta Micena palaeontological site (Orce,Spain)

The palaeontological site of Venta Micena (Orce, Andalusia, Spain) lies in the eastern sector of the Guadix–Baza basin, one of the best documented areas in Europe for Plio‐Pleistocene biostratigraphy. The combination of biochronological and palaeomagnetic results, combined with the radiometric data obtained for Atapuerca Sima del Elefante, indicated that the Venta Micena stratum was formed between the Jaramillo and Olduvai palaeomagnetic events, most likely between 1.22 and 1.77 Ma. Five fossil teeth from two outcrops (sites A and B) were selected to assess the potential of combined uranium series–electron spin resonance (US‐ESR) dating of Early Pleistocene sites. Although the US‐ESR results of the first outcrop showed a large scatter between the three teeth, the mean age of 1.37 ± 0.24 Ma can be considered a reasonable age estimate for Venta Micena. The mean ESR age of 0.62 ± 0.03 Ma obtained for site B seems to be a severe underestimation when compared with the independent age control. This underestimation is attributed to a relative recent U‐mobilization event that led to some U‐leaching. The results show that any ESR age calculations of old samples are extremely sensitive to variations in the measured ²³⁰Th/²³⁴U ratios in dental tissues. Although the results demonstrate that ESR can in principle be applied to Early Pleistocene sites, they also reveal the complexity of dating such old teeth. It is necessary to continue research in several directions, such as study of the behaviour of ESR signals in old teeth and understanding recent U‐mobilization processes, to improve the reliability of the combined US‐ESR dating method applied to Early Pleistocene times, a period for which the number of available numerical dating techniques is very limited. Copyright © 2011 John Wiley & Sons, Ltd.     

The droughts of 1996–1997 and 2004–2005 in Amazonia: hydrological response in the river main‐stem

Severe hydrological droughts in the Amazon have generally been associated with strong El Niño events. More than 100 years of stage record at Manaus harbour confirms that minimum water levels generally coincide with intense warming in the tropical Pacific sea waters. During 2005, however, the Amazon experienced a severe drought which was not associated with an El Niño event. Unless what usually occurs during strong El Niño events, when negative rainfall anomalies usually affect central and eastern Amazon drainage basin; rainfall deficiencies in the drought of 2005 were spatially constrained to the west and southwest of the basin. In spite of this, discharge stations at the main‐stem recorded minimum water levels as low as those observed during the basin‐wide 1996–1997 El Niño‐related drought. The analysis of river discharges along the main‐stem and major tributaries during the drought of 2004–2005 revealed that the recession on major tributaries began almost simultaneously. This was not the case in the 1996–1997 drought, when above‐normal contribution of some tributaries for a short period during high water was crucial to partially counterbalance high discharge deficits of the other tributaries. Since time‐lagged contributions of major tributaries are fundamental to damp the extremes in the main‐stem, an almost coincident recession in almost all tributaries caused a rapid decrease in water discharges during the 2005 event. Copyright © 2010 John Wiley & Sons, Ltd.