In situ atomic force microscopy measurements of biotite basal plane reactivity in the presence of oxalic acid

We have used a direct imaging technique, in situ atomic force microscopy (AFM), to observe the dissolution of the basal biotite surface by oxalic acid over a range of temperatures close to ambient conditions, using a specially designed AFM liquid cell and non-invasive intermittent contact mode of operation. From the 3-dimensional nanometre-resolution data sets, we observe a process characterised by the slow formation of shallow etch pits in the (0 0 1) surface and fast growth of etch pits from the resulting steps, which represent proxies for the {h k 0} surface. Measurements of dissolution rates as a function of temperature allow a determination of an apparent activation energy (E_a,app) for the process, via mass-loss calculations from image analysis. We obtain a value of E_a,app = 49 ± 2 kJ mol⁻¹, which is consistent with separate calculations based on planar area etch pit growth, and measurements of etch pit perimeters, indicating that this value of E_a,app is representative of {h k 0} surface dissolution. The measurement of etch pit perimeters also enables an estimation of apparent activation energy as a function of step density indicating substantially higher apparent activation energy, up to E_a,app = 140 kJ mol⁻¹, on extrapolation towards a pristine surface with no defects. We suggest that this higher value of E_a,app represents the slow formation of etch pits into the (0 0 1) surface.     

Suspended sediment transport and deposition in a high arctic meromictic lake

A study of sedimentary processes and sediment yields in a high arctic meromictic lake (Lake C2, Taconite Inlet, Northern Ellesemere Island, Canada) was undertaken from May 1990 through August 1992 to understand the links between climatic controls, hydrology, and the laminated sediment record preserved in the lake. Understanding the relationships between processes and the sediment record is critical for interpreting the climatic significance of the laminated sediments in a region where high resolution climate proxy records are quite limited.Sediment transport to Lake C2 is dominated by fluvial processes. During the early part of the melt season slushflows transport sediment to the lake surface. Subsequently, suspended sediment is delivered to the lake by the main inlet stream and distributed lakeward by a plume emanating the main inlet channel. Due to the strong density stratification of the water column the plume distributes sediment downlake by overflows and interflows in the epilimnion. In general, overflows are generated by lower discharge events whereas interflows penetrate to the halocline during high discharge with increased suspended sediment concentration.Sediment trap analysis demonstrates that suspended sediment transport and deposition responds to diurnal through annual changes in stream discharge. Seasonal and annual sediment trap yields agree with average accumulation rates determined from varve thickness measurements and cumulative suspended sediment discharge from the main inlet stream indicating a close link between climatological, hydrological, and sedimentological controls and varve deposition.This is the fourth in a series of papers published in this issue on the Taconite Inlet Lakes Project. These papers were collected by Dr R. S. Bradley.     

The effective number of cycles of earthquake ground motion

The seismic response of any system that accumulates damage under cyclic loading is dependent not only on the maximum amplitude of the motion but also its duration. This is explicitly recognized in methods for estimating the liquefaction potential of soil deposits. Many researchers have proposed that the effective number of cycles of the ground motion is a more robust indicator of the destructive capacity of the shaking than the duration. However, as is the case with strong‐motion duration, there is no universally accepted approach to determining the effective number of cycles of motion, and the different methods that have been proposed can give widely varying results for a particular accelerogram. Definitions of the effective number of cycles of motion are reviewed, classified and compared. Measurements are found to differ particularly for accelerograms with broad‐banded frequency content, which contain a significant number of non‐zero crossing peaks. The key seismological parameters influencing the number of cycles of motion and associated equations for predicting this quantity for future earthquakes are identified. Correlations between cycle counts and different duration measures are explored and found to be rather poor in the absence of additional parameters. Copyright © 2004 John Wiley & Sons, Ltd.     

Mapping block-and-ash flow hazards based on Titan 2D simulations: a case study from Mt. Taranaki,NZ

Numerical models for simulation of mass flows are typically focussed upon accurately predicting the paths, travel times and inundation from a single flow or collapse event. When considering catchment-based hazards from a volcano, this is complicated by often being faced with several possible scenarios. Over the last 800 years at Mt. Taranaki/Egmont, a number of dome growth and collapse events have resulted in the genesis and emplacement of block-and-ash flows (BAFs). Each BAF was directed northwestward by a breach in the crater rim. The latest dome collapse events in the AD 1880s and AD 1755 inundated the northwestern flank and had run-out lengths 10 km from source. Future activity of this type could have a devastating effect on the Taranaki region’s communities, infrastructure and economy. Hazard planning has involved constructing volcanic hazard maps based upon the areas inundated by past volcanic flows, with little consideration of present-day topography. Here, a numerical geophysical mass flow modelling approach is used to forecast the hazards of future comparable BAF events on NW Mt. Taranaki. The Titan2D programme encompasses a “shallow water”, continuum solution-based, granular flow model. Flow mechanical properties needed for this approach include estimates of internal and basal friction as well as the physical dimensions of the initial collapse. Before this model can be applied to Taranaki BAFs, the input parameters must be calibrated by simulating a range of past collapse events. By using AD 1860 and AD 1755 scenarios, initial collapse volumes can be well constrained and internal and basal friction angles can be evaluated through an iterative approach from previous run-out lengths. A range of possible input parameters was, therefore, determined to produce a suite of potentially inundated areas under present-day terrain. A suite of 10 forecasts from a uniformly distributed range were combined to create a map of relative probabilities of inundation by future BAF events. These results were combined in a GIS package to produce hazard zones related to user-specified hazard thresholds. Using these input parameter constraints, future hazard forecasts for this scale and type of event can also take into account changing summit and topographic configurations following future eruptive or collapse events.     

Behavior of Weak Soils Reinforced with End-Bearing Soil-Cement Columns Formed by the Deep Mixing Method

This article reports on a series of small-scale, plane strain, 1 g physical model tests designed to investigate the bearing capacity and failure mechanics of end-bearing soil-cement columns formed via Deep Mixing (DM). Pre-formed soil-cement columns, 24 mm in diameter and 200 mm in length, were installed in a soft clay bed using a replacement method; the columns represented improvement area ratios, a_p, of 17%, 26%, and 35% beneath a rigid foundation of width 100 mm. Particle Image Velocimetry (PIV) was implemented in conjunction with close-range photogrammetry in order to track soil displacement during loading, from which the failure mechanisms were derived. Bearing capacity performance was verified using Ultimate Limit State numerical analysis, with the results comparing favorably to the analytical static and kinematic solutions proposed by previous researchers. A new equation for bearing capacity was derived from this numerical analysis based on the improvement area ratio and cohesion ratio of the soil column and ground model.     

Reconstruction of New Zealand Temperatures Back to AD 1720 Using Libocedrus bidwillii Tree-Rings

The longest chronology from New Zealand so faris from Libocedrus bidwillii Hook. f. (i.e.,from AD 1992 back to AD 1140, a span of 853 years). A subset of 11 chronologies was selected from anetwork of 23 sites to reconstruct past temperaturesbased on the similarity of significant responsefunctions. A comparison of climate data overdifferent seasons with these 11 chronologies wascarried out using a bootstrap transfer function. Average late-summer (February–March) temperature wasselected for reconstruction based on independentverification results. The reconstructed temperaturewas then presented for the period back to AD 1720. The chronologies reconstructed years experiencing hotsummers better than cold summers. The power spectrumof the reconstructed temperatures showed periodicitiessimilar to those of the observed temperatures. Reconstructed temperatures were significantlycorrelated with other proxy climate reconstructionsderived from tree rings in New Zealand. However,unlike the other tree ring-based reconstructions, theLibocedrus bidwillii series reconstructed boththe 1950s and 1970s warming periods. The resultsalso compared very favourably with other palaeoclimateevidence.     

Influence of vegetation change on watershed hydrology: implications for paleoclimatic interpretation of lacustrine δ18O records

Stratigraphic shifts in the oxygen isotopic (¹⁸O) and trace element (Mg and Sr) composition of biogenic carbonate from tropical lake sediment cores are often interpreted as a proxy record of the changing relation between evaporation and precipitation (E/P). Holocene ¹⁸O and Mg and Sr records from Lakes Salpetén and Petén Itzá, Guatemala were apparently affected by drainage basin vegetation changes that influenced watershed hydrology, thereby confounding paleoclimatic interpretations. Oxygen isotope values and trace element concentrations in the two lowland lakes were greatest between ~ 9000 and 6800 ¹⁴C-yr BP, suggesting relatively high E/P, but pollen data indicate moist conditions and extensive forest cover in the early Holocene. The discrepancy between pollen- and geochemically-inferred climate conditions may be reconciled if the high early Holocene ¹⁸O and trace element values were controlled principally by low surface runoff and groundwater flow to the lake, rather than high E/P. Dense forest cover in the early Holocene would have increased evapotranspiration and soil moisture storage, thereby reducing delivery of meteoric water to the lakes. Carbonate ¹⁸O and Mg and Sr decreased between 7200 and 3500 ¹⁴C-yr BP in Lake Salpetén and between 6800 and 5000 ¹⁴C-yr BP in Lake Petén Itzá. This decline coincided with palynologically documented forest loss that may have led to increased surface and groundwater flow to the lakes. In Lake Salpetén, minimum ¹⁸O values (i.e., high lake levels) occurred between 3500 and 1800 ¹⁴C-yr BP. Relatively high lake levels were confirmed by ¹⁴C-dated aquatic gastropods from subaerial soil profiles ~ 1.0–7.5 m above present lake stage. High lake levels were a consequence of lower E/P and/or greater surface runoff and groundwater inflow caused by human-induced deforestation.     

A cross-ecosystem comparison of spatial and temporal patterns of covariation in the recruitment of functionally analogous fish stocks

Temporal and spatial patterns of recruitment (R) and spawning stock biomass (S) variability were compared among functionally analogous species and similar feeding guilds from six marine ecosystems. Data were aggregated into four regions including the Gulf of Maine/Georges Bank, the Norwegian/Barents Seas, the eastern Bering Sea, and the Gulf of Alaska. Variability was characterized by calculating coefficients of variation and anomalies for three response variables: ln(R), ln(R/S), and stock–recruit model residuals. Patterns of synchrony and asynchrony in the response variables were examined among and between ecosystems, between- and within-ocean basins and among functionally analogous species groups using pair-wise correlation analysis corrected for within-time series autocorrelation, multivariate cross-correlation analyses and regime shift detectors. Time series trends in response variables showed consistent within basin similarities and consistent and coherent differences between the Atlantic and Pacific basin ecosystems. Regime shift detection algorithms identified two broad-scale regime shift time periods for the pelagic feeding guild (1972–1976 and 1999–2002) and possibly one for the benthic feeding guild (1999–2002). No spatial patterns in response variable coefficients of variation were observed. Results from multivariate cross-correlation analysis showed similar trends. The data suggest common external factors act in synchrony on stocks within ocean basins but temporal stock patterns, often of the same species or functional group, between basins change in opposition to each other. Basin-scale results (similar within but different between) suggest that the two geographically broad areas are connected by unknown mechanisms that, depending on the year, may influence the two basins in opposite ways. This work demonstrates that commonalities and synchronies in recruitment fluctuations can be found across geographically distant ecosystems but biophysical causes of the fluctuations remain difficult to identify.     

Hydropyrolysis: A new technique for the analysis of macromolecular material in meteorites

The carbonaceous chondrite meteorites are fragments of asteroids that have remained relatively unprocessed since the formation of the Solar System 4.56 billion years ago. The major organic component in these meteorites is a macromolecular phase that is resistant to solvent extraction. The information contained within macromolecular material can be accessed by degradative techniques such as pyrolysis. Hydropyrolysis refers to pyrolysis assisted by high hydrogen gas pressures and a dispersed sulphided molybdenum catalyst. Hydropyrolysis of the Murchison macromolecular material successfully releases much greater quantities of hydrocarbons than traditional pyrolysis techniques (twofold greater than hydrous pyrolysis) including significant amounts of high molecular weight polyaromatic hydrocarbons (PAH) such as phenanthrene, carbazole, fluoranthene, pyrene, chrysene, perylene, benzoperylene and coronene units with varying degrees of alkylation. When hydropyrolysis products are collected using a silica trap immersed in liquid nitrogen, the technique enables the solubilisation and retention of compounds with a wide range of volatilities (i.e. benzene to coronene). This report describes the hydropyrolysis method and the information it can provide about meteorite macromolecular material constitution.