Hydrothermal plume mapping as a prospecting tool for seafloor sulfide deposits: a case study at the Zouyu-1 and Zouyu-2 hydrothermal fields in the southern Mid-Atlantic Ridge

Seafloor hydrothermal polymetallic sulfide deposits are a new type of resource, with great potential economic value and good prospect development. This paper discusses turbidity, oxidation–reduction potential, and temperature anomalies of hydrothermal plumes from the Zouyu-1 and Zouyu-2 hydrothermal fields on the southern Mid-Atlantic Ridge. We use the known location of these vent fields and plume data collected in multiple years (2009, 2011, 2013) to demonstrate how real-time plume exploration can be used to locate active vent fields, and thus associated sulfide deposits. Turbidity anomalies can be detected 10 s of km from an active source, but the location precision is no better than a few kilometers because fine-grained particles are quasi-conservative over periods of many days. Temperature and oxidation–reduction potential anomalies provide location precision of a few hundred meters. Temperature anomalies are generally weak and difficult to reliably detect, except by chance encounters of a buoyant plume. Oxidation–reduction potential is highly sensitive (nmol concentrations of reduced hydrothermal chemicals) to discharges of all temperatures and responds immediately to a plume encounter. Real-time surveys using continuous tows of turbidity and oxidation–reduction potential sensors offer the most efficient and precise surface ship exploration presently possible.     

The identification of distinct patterns in California temperature trends

Regional changes in California surface temperatures over the last 80 years are analyzed using station data from the US Historical Climate Network and the National Weather Service Cooperative Network. Statistical analyses using annual and seasonal temperature data over the last 80 years show distinctly different spatial and temporal patterns in trends of maximum temperature (Tmax) compared to trends of minimum temperature (Tmin). For trends computed between 1918 and 2006, the rate of warming in Tmin is greater than that of Tmax. Trends computed since 1970 show an amplified warming rate compared to trends computed from 1918, and the rate of warming is comparable between Tmin and Tmax. This is especially true in the southern deserts, where warming trends during spring (March?CMay) are exceptionally large. While observations show coherent statewide positive trends in Tmin, trends in Tmax vary on finer spatial and temporal scales. Accompanying the observed statewide warming from 1970 to 2006, regional cooling trends in Tmax are observed during winter and summer. These signatures of regional temperature change suggest that a collection of different forcing mechanisms or feedback processes must be present to produce these responses.     

Properties of pressure fluctuations in an atmospheric boundary layer

From experimental data it is shown that there is a relationship between measured wind speed and associated micropressure levels. It is also shown that turbulent eddies associated with the wind vanish within distances of five to six times their size, and that these eddies exhibit normal dispersion. These results confirm, at the atmospheric scales, results previously observed only in model experiments.     

Marymia: an Archean, amphibolite facies-hosted, orogenic lode-gold deposit overprinted by Palaeoproterozoic orogenesis and base metal mineralisation, Western Australia

The Marymia gold deposit, comprising two orebodies, Keillor 1 and Keillor 2, is at the northern end of the Plutonic Well greenstone belt in the Marymia Inlier, in the southern Capricorn Orogen, just north of the Yilgarn craton. The Marymia Inlier is a discrete fault-bounded Archean gneiss-granitoid-greenstone domain surrounded by sedimentary basins that were formed and variably metamorphosed and deformed during several Palaeoproterozoic orogenic cycles. The greenstone sequence at Marymia is stratigraphically and geochemically similar to greenstone sequences in the Yilgarn craton, but was subjected to further deformation and metamorphism in the Palaeoproterozoic. Late Archean deformation (D1-D2) was ductile to brittle-ductile in style, whereas Palaeoproterozoic deformation was predominantly brittle. Equilibrium mineral assemblages indicate that peak amphibolite-facies metamorphism (540-575 °C, <3 kb) was overprinted by greenschist-facies metamorphism (300-360 °C). Petrographic textures indicate that prograde metamorphism was coeval with D1-D2, with peak metamorphism early to syn D2. Gold mineralisation at Marymia is hosted in metamorphosed tholeiitic basalts and banded iron formation. On a gross scale, the distribution of gold is controlled by D2 folds and shear zones. Lithological contacts with strong rheological or chemical contrasts provide local controls. Gold-related alteration comprises subtle millimetre- to centimetre-wide zones of silicification with variable amounts of quartz, hornblende, biotite, K-feldspar, plagioclase, calcite/siderite, scheelite, titanite, epidote, sulfide and telluride minerals. Quartz veins are generally narrow and discontinuous with low total volume of quartz. Gold is sited in the wall rock, at vein salvedges or within stringers of wall rock within veins. There are two distinct opaque-mineral assemblages: pyrite-pyrrhotite-chalcopyrite-galena and hessite-petzite-altaite-Bi-telluride-galena. Ore samples are variably enriched in Ag, Te, Pb, W, Cu, S and Fe reflecting heterogeneity of the ore mineralogy. Structural timing and temperature of formation of alteration and ore minerals support deposition of gold during late peak amphibolite-facies metamorphism from neutral to alkaline (pH=5-6), moderately oxidising (log P_O2,-21-22) and CO₂-bearing (X_CO2 Ƹ.2) fluids. The total sulfur content of the fluid is estimated at 1mDS. Lead isotope compositions support derivation of lead from within the local greenstone sequence. Gold lodes were deformed by faults and shear zones in the Palaeoproterozoic, with only limited remobilisation. Subeconomic, carbonate vein- and breccia-hosted base metal mineralisation is locally hosted within Palaeoproterozoic fault zones, which clearly cut gold lodes. Base-metal-related alteration is characterised by intense carbonatisation, chloritisation, and albitisation of the mafic host rocks. Mineral assemblages are consistent with formation at greenschist facies conditions. Lead isotope compositions support crystallisation at ca. 1.7 Ga from lead that is similar in composition to earlier gold-related galena.     

PM2.5 co-benefits of climate change legislation part 2: California governor’s executive order S-3-05 applied to the transportation sector

California Governor’s Executive Order (CGEO) S-3-05 requires that California greenhouse gas (GHG) emissions be reduced to 80 % below 1990 levels by the year 2050. Meeting this target will require drastic changes in transportation technology, fuel, and behavior which will reduce criteria pollutant emissions as well as GHG emissions. The improvement to local air quality caused by the reduced criteria pollutant emissions must be calculated to fully evaluate the overall benefits and costs of CGEO S-3-05. In the present study, seven different transportation scenarios that move towards the goals of CGEO S-3-05 in the transportation sector were examined to determine how they would affect future airborne particulate matter (PM_2.5) concentrations in California: (1) hydrogen fuel cells, (2) electric vehicles, (3) high efficiency vehicles, (4) public mass transit, (5) biofuels, (6) biofuels + hybrid electric vehicles, and (7) hydrogen fuel cells + electric vehicles. The air quality implications of each scenario were evaluated using a chemical transport model applied during a wintertime stagnation episode representing future climate in California. Scenarios (6) and (7) reduced population-weighted PM_2.5 mass concentrations by ~9 % and PM_2.5 elemental carbon (EC) concentrations by ~30 % relative to base-case predictions.     

Stable carbon isotope variations in northwest Europe during the last glacial–interglacial transition

Stable carbon isotope data that span part of the last glacial–interglacial transition (ca. 14-9 ka ¹⁴C BP; ca. 15–11 ka cal. BP), and which derive from organ-specific plant macrofossils recovered from two lake sediment profiles in the UK and one in Norway, are compared. The recorded temporal variations show similar trends, which, over a millennial time-scale appear to parallel the main drift in δ¹⁸O as determined for the GRIP ice-core. It is postulated that some smaller scale variations in the δ¹³C profiles may reflect the shorter term oscillations in δ¹⁸O values evident in the GRIP record, although this is less certain. Overall, however, the results suggest that stable carbon isotope measurements based on organ-specific terrestrial plant macrofossils may provide (i) a means for establishing correlations between terrestrial successions and (ii) additional paleoenvironmental information, as the apparent ‘shadowing’ of the GRIP record indicates a common forcing mechanism for both Greenland δ¹⁸O and northwest European δ¹³C variations. From the evidence available we suggest that the recorded δ¹³C variations reflect fluctuations in air temperature and/or changes in water vapour pressure in the atmosphere. © 1997 John Wiley & Sons, Ltd.     

Silicic differentiates of abyssal oceanic magmas: Evidence for late-magmatic vapor transport of potassium

Massive, nearly holocrystalline dolerites from DSDP Hole 417D contain from 0.5 to 1.5% of granophyric patches composed mainly of Na-plagioclase and quartz. These patches are compositionally similar to other crystalline silicic rocks from oceanic spreading centers and differ from rarer abyssal silicic glasses. Crystalline varieties withSiO₂60wt.% generally haveNa/K>10, whereas silicic glasses have Na/K in the range 3–6. While crystal fractionation readily accounts for the Na₂O and K₂O contents of abyssal silicic glasses, both the 417D granophyres and other crystalline abyssal silicic rocks have much lower K₂O than that predicted by any reasonable crystal-liquid fractionation model. We propose that high-temperature vapor phase transport is responsible for removal of potassium during late-stage crystallization of these rocks. This allows for the formation of cogenetic silicic glassy and crystalline rocks with greatly different Na/K ratios. These observations and interpretations lead to a more confident assignment of high Na/K silicic rocks of oceanic and ophiolitic environments to a cogenetic origin with basaltic oceanic crust.     

On error bounds and initialization in satellite orbit theories

The order of magnitude of the error is investigated for a first-order von Zeipel theory of satellite orbits in an axisymmetric force field, i.e., first-order long period and short-period effects are included along with second order secular rates. The treatment is valid for zero eccentricity and/or inclination. In the case where initial position and velocity vectors are known, the in-track position error over time intervals of order 1/J ₂ is kept at 0(J ₂ ²), like the other position errors and velocity errors, by calibration of the mean motion with the aid of the energy integral. The results are specifically applicable to accuracy comparisons of the Brouwer orbit prediction method with numerical integration. A modified calibration is presented for the general asymmetric force field which includes tesseral harmonics.     

Key Design Elements of Building Pressure Cycling for Evaluating Vapor Intrusion—A Literature Review

Building pressure cycling (BPC) is becoming an increasingly important tool for studying vapor intrusion. BPC has been used to distinguish subslab and indoor sources of vapor intrusion as well as to define reasonable worst case volatile organic compound mass discharge into a structure. Analyses have been performed both semi-quantitatively with concentration trends and quantitatively with more rigorous flux calculation and source attribution methods. This paper reviews and compares the protocols and outcomes from multiple published applications of this technology to define the key variables that control performance. Common lessons learned are identified, including those that help define the range of building size and type to which BPC is applicable. Differences in test protocols are discussed, recognizing that the complexity of the test protocol required depends on the particular objectives of each project. Research gaps are identified and tabulated for future validation studies and applications.