Silicon carbide and the infrared excess of carbon stars

This paper reports laboratory investigations on the absorption spectrum of SiC particles in the 10 μm region. The particles had a mean diameter of 0.31 μm. Our experimental results indicate that a large part of the infrared excess observed in carbon stars may be caused by SiC.     

<Superscript>57</Superscript>Fe Mössbauer spectroscopy,X-ray single-crystal diffractometry,and electronic structure calculations on natural alexandrite

Natural alexandrite Al₂BeO₄:Cr from Malyshevo near Terem Tschanka, Sverdlovsk, Ural, Russia, has been characterized by ⁵⁷Fe Mössbauer spectroscopy, electron microprobe, X-ray single-crystal diffractometry and by electronic structure calculations in order to determine oxidation state and location of iron. The sample contains 0.3 wt% of total iron oxide. The ⁵⁷Fe Mössbauer spectrum can be resolved into three doublets. Two of them with hyperfine parameters typical for octahedrally coordinated high-spin Fe³⁺ and Fe²⁺, respectively, are assigned to iron substituting for Al in the octahedral M2-site. The third doublet is attributed to Fe³⁺ in hematite. Electronic structure calculations in the local spin density approximation are in reasonable agreement with experimental data provided that expansion and/or distortion of the coordination octahedra are presumed upon iron substitution. The calculated hyperfine parameters of Fe³⁺ are almost identical for the M1 and M2 positions, but the calculated ligand-field splitting is by far too large for high-spin Fe³⁺ on M1.     

Depth–transport functions and erosion–deposition diagrams as indicators of slope inclination and time-averaged traction forces: applications in tropical reef environments

The trigonometric relationship between slope inclination, the horizontally acting time‐averaged traction force and the vertical depth of transport allows the estimation of one factor, when both others are known. Depth–transport functions can be deduced by comparing the depth distributions of living organisms and their skeletal remains, and this paper simplifies this comparison using foraminifera in which a single test represents an individual. Differences in distribution parameters between living individuals and empty tests allow depth–transport functions to be determined; these functions differ between species at a single transect according to the varying buoyancies of the tests. Within a single species, differences in depth–transport functions between locations are based on either slope inclination or traction intensities. After establishing a mean depth–transport function by averaging species‐characteristic functions, the time‐averaged traction force acting on the studied transect can be calculated. Transport intensities are also estimated using an erosion–deposition diagram that combines the relative frequency distributions of living individuals and empty tests. The proportion of ‘eroded’, ‘parautochthonous’ and ‘allochthonous’ tests mirrors the influence of both slope inclination and traction force for the deposition of empty tests. To test the model, six species of symbiont‐bearing benthic foraminifers were investigated at two transects in front of a NW Pacific coral reef. One transect is distinguished by a strong slope flattening below the steep reef slope (30 m), whereas further steepening characterizes the equivalent part in the other transect. These differences are mirrored in the depth–transport functions as well as in the erosion–deposition diagrams of all species. The time‐averaged traction forces differ in intensities between transects, because of the position of the reef front with respect to the predominant wind direction. However, the form of the functions is identical and distinguished by an increase from the surface to 35 m depth, followed by a decrease down to 105 m. This can be explained by successive onshore and offshore forces acting on the shallow slope, such as the tropical cyclones that cross the region every summer.     

GIOVE-A initial signal analysis

In late December 2005 the GIOVE-A test satellite was launched by the European Space Agency (ESA) to secure the frequencies for the Galileo system and to provide a platform for testing the new navigation signals. We performed an initial assessment of these signals using the 30 m deep space antenna of the DLR ground station in Weilheim (Germany). The antenna gain raised the signals above the noise level, thus allowing a detailed analysis even without knowledge of the ranging codes. The present paper covers the analysis of the L1/E1 signals, which includes a discussion of the spectrum, the time domain signal and a decoding of the spreading codes for the Open Service.     

A Reanalysis and Reinterpretation of Geodetic and Geological Evidence of Glacial-Isostatic Adjustment in the Churchill Region, Hudson Bay

We review the historical, geological, tide-gauge, GPS and gravimetric evidence advanced in favour of, or against, continuing land uplift around Hudson Bay, Canada. We also reanalyse the tide-gauge and GPS data for Churchill using longer time series than those available to previous investigators. The dependence of the mean rate of relative sea-level change obtained from the tide-gauge record on the length and mid-epoch of the observation interval considered is investigated by means of a newly developed linear-trend analysis diagram. For studying the shorter-period variability of the tide-gauge record, the wavelet transform is used. The mean rate of land uplift obtained from GPS is based on a new analysis using IGS solutions of GFZ. To include the post-glacial land uplift, sea-level indicators from the Churchill region representing the relative sea-level history during the past 8000 years are also used. Finally, the values of the four observables are jointly inverted in terms of mantle viscosity. The optimum values are ~3.2 × 10²⁰ Pa s and ~1.6 × 10²² Pa s for the upper- and lower-mantle viscosities, respectively.     

Variability of Fram Strait sea ice export: causes, impacts and feedbacks in a coupled climate model

Analyses of a 500-year control integration of the global coupled atmosphere–sea ice–ocean model ECHAM5.0/MPI-OM show a high variability in the ice export through Fram Strait on interannual to decadal timescales. This variability is mainly determined by variations in the sea level pressure gradient across Fram Strait and thus geostrophic wind stress. Ice thickness anomalies, formed at the Siberian coast and in the Chukchi Sea, propagate across the Arctic to Fram Strait and contribute to the variability of the ice export on a timescale of about 9 years. Large anomalies of the ice export through Fram Strait cause fresh water signals, which reach the Labrador Sea after 1–2 years and lead to significant changes in the deep convection. The associated anomalies in ice cover and ocean heat release have a significant impact on air temperature in the Labrador Sea and on the large-scale atmospheric circulation. This affects the sea ice transport and distribution in the Arctic again. Sensitivity studies, simulating the effect of large ice exports through Fram Strait, show that the isolated effect of a prescribed ice/fresh water anomaly is very important for the climate variability in the Labrador Sea. Thus, the ice export through Fram Strait can be used for predictability of Labrador Sea climate up to 2 years in advance.     

A resin nodule in the Cretaceous Garschella Formation from Langer Köchel (Bavaria, S Germany): possible origin and palaeogeographic provenance

A resin nodule was found in glauconite-rich detrital sediments of the Cretaceous Garschella Formation (Aptian to Albian) outcropping at Langer Köchel (Bavaria, S Germany). Gas chromatographic and mass spectrometric analyses of the fossil resin revealed dealkylation and the total defunctionalisation of its polycyclic constituents. Besides many unspecific components a specific one, agathalene, has survived. Agathalene also presents a strongly degraded product, but may have been derived from its natural precursor agathic acid, which is a very specific constituent (biomarker) of recent and fossil kauri resin. Although agathalene is a far less specific secondary biomarker, it indicates the botanic origin of the fossil resin nodule. Besides other potential producers of agathic acid, precursors of the present-day conifer species Agathis dammara and A. australis were distributed in a wider palaeophytogeographic range than today and might have been the botanical source of kauri resin. In view of the east–west directed Early Cretaceous surface current system of the Tethys ocean, the palaeogeographic provenance of the Werdenfels resin nodule probably was a mainland positioned further to the east or southeast of the Helvetic shelf, to where it was transported probably by driftwood of the resin-producing Agathis sp.     

Uniform Permian 40Ar/39Ar detrital mica ages in the eastern Qaidam Basin (NW China): where is the source?

New single‐grain ⁴⁰Ar/³⁹Ar detrital white‐mica ages from the Lulehe section at the eastern Qaidam Basin yield uniform Permian ages between 250 ± 3 and 279 ± 3 Ma throughout the whole Cenozoic sequence. This is inconsistent with the present hinterland, which is composed of early Palaeozoic metamorphic units with subordinate early Palaeozoic and few Permian granites. The new data indicate that Permian tectonic units are likely more widespread at the north‐eastern margin of the Tibetan plateau as known at present, particularly within the Qilian Mountains. The preferred explanation is that the Qaidam block represents a rigid indenter, which indented during late Tertiary times into early Palaeozoic orogenic units. This is consistent with recent findings of a NW‐trending sinistral Permian ductile shear zone and a dextral, NW‐trending Tertiary fault system close to the north‐eastern margin of the Qaidam Basin.     

A multimodel comparison of centennial Atlantic meridional overturning circulation variability

A mechanism contributing to centennial variability of the Atlantic Meridional Overturning Circulation (AMOC) is tested with multi-millennial control simulations of several coupled general circulation models (CGCMs). These are a substantially extended integration of the 3rd Hadley Centre Coupled Climate Model (HadCM3), the Kiel Climate Model (KCM), and the Max Plank Institute Earth System Model (MPI-ESM). Significant AMOC variability on time scales of around 100?years is simulated in these models. The centennial mechanism links changes in the strength of the AMOC with oceanic salinities and surface temperatures, and atmospheric phenomena such as the Intertropical Convergence Zone (ITCZ). 2 of the 3 models reproduce all aspects of the mechanism, with the third (MPI-ESM) reproducing most of them. A comparison with a high resolution paleo-proxy for Sea Surface Temperatures (SSTs) north of Iceland over the last 4,000?years, also linked to the ITCZ, suggests that elements of this mechanism may also be detectable in the real world.