Dissolved trace metals in the surface waters of Puget Sound

Employing clean and quantitative techniques, a marine monitoring programme succeeded in detecting large surface elevations in the concentrations of dissolved Cu, Zn and Pb in the marine surface waters of Puget Sound adjacent to Seattle and Tacoma, Washington. Physical mixing with cleaner waters was the controlling factor in reducing the dissolved concentrations of Cu downstream of these contaminated regions. Comparisons between Puget Sound waters and coastal waters adjacent to Puget Sound suggest that a portion of this Cu, Zn and Pb pollution is being advected out of Puget Sound. The low Ni and Cd concentrations found in this study indicate that these trace metals are not a significant pollution problem in the main basin of Puget Sound.     

Dynamic recrystallization and chemical evolution of clinoamphibole from Senja,Norway

Clinoamphibole from a mylonitic amphibolite exhibits microstructures characteristic of dynamic recrystallization, including porphyroclasts in a finer grained matrix of needle-shaped amphibole. The matrix amphibole defines an LS fabric and porphyroclasts have core and mantle structures with a core containing undulose to patchy extinction and (100) deformation twinning surrounded by a mantle of recrystallized grains. In addition intragranular grains also occur within the cores. TEM analyses of the porphyroclasts reveal that they contain a wide variety of lattice defects including high densities (5 × 10⁸cm^–2) of free dislocations and dislocation arrays, dissociated dislocations, stacking faults, and (100) micro-twins. TEM also shows that matrix grains and intragranular grains have relatively low defect densities, and that the intragranular new grains occur at localities in the porphyroclasts characterized by high densities of dislocations. These observations along with the chemical and orientation relationships between the recrystallized grains and porphyroclasts indicate that the new grains may have formed by heterogeneous nucleation and that further growth probably occurred by both strain assisted and chemically induced grain boundary migration or liquid film migration. This recrystallization event is interpreted to be synkinematic based on the fact that no recrystallization textures are present in the matrix grains and that the matrix grains define an LS fabric. However, the low defect densities in the matrix grains and the lack of intracrystalline strain in other phases indicate that post-kinematic recovery processes were active.     

Using Simple Dilution Models to Predict New Zealand Estuarine Water Quality

A tool based on simple dilution models is developed to predict potential nutrient concentrations and flushing times for New Zealand estuaries. Potential nutrient concentrations are the concentrations that would occur in the absence of nutrient uptake or losses through biogeochemical processes, and so represent the pressure on a system due to nutrient loading. The dilution modelling approach gives a single time- and space-averaged concentration as a function of flow and nutrient input, with the capability to include seasonal nutrient and flow differences. This tool is intended to be used to identify estuaries likely to be highly sensitive to current nutrient loads based on their physical attributes, or to quickly compare the effects of different land-use scenarios on estuaries. The dilution modelling approach is applied both to a case study of a single New Zealand estuary, and used in a New Zealand-wide assessment of 415 estuaries. For the NZ-wide assessment, annual nutrient loads to each estuary were obtained from a GIS-based land-use model. Comparison with measured data shows that the predicted potential nitrate concentrations are significantly correlated with, but higher than, measured nitrate values from water quality sampling time series. This is consistent with expectations given that the measured concentrations include the effects of nitrogen uptake and loss. The estuary dilution modelling approach is currently incorporated into the GIS-land use model, and is also available as a web-app for assessing eutrophication susceptibility of New Zealand estuaries.     

JONSWAP's parameters: Sorting out the inconsistencies

The original prognostic equations for the JONSWAP-spectrum contained inconsistencies. A subsequent paper (Hasselmann et al., 1976, J. phys. Oceanogr.6, 200–208) attempted to regularise the situation. This paper shows that there were still inconsistencies in the prognostic equations giving overestimations of the first moment of the spectrum and consequently the significant wave height. The prognostic equations are reworked systematically and results presented. It is shown that variable σ_a, σ_b and γ must be used to achieve consistent results     

Phytoplankton abundance and contributions to suspended particulate matter in the Ohio,Upper Mississippi and Missouri Rivers

Main channel habitats of the Ohio, Missouri, and Upper Mississippi Rivers were surveyed during the summers of 2004, 2005 and 2006 using a probability-based sampling design to characterize inter-annual and inter-river variation in suspended chlorophyll a (CHLa) and related variables. Large (fivefold) differences in CHLa were observed with highest concentrations in the Upper Mississippi (32.3 ± 1.8 μg L⁻¹), intermediate values in the Missouri (19.7 ± 1.1 μg L⁻¹) and lowest concentrations in the Ohio (6.8 ± 0.5 μg L⁻¹). Inter-annual variation was small in comparison to inter-river differences suggesting that basin-specific factors exert greater control over river-wide CHLa than regional-scale processes influencing climate and discharge. The rivers were characterized by variable but generally low light conditions as indicated by depth-averaged underwater irradiance <4 E m⁻² day⁻¹ and high ratios of channel depth to euphotic depth (>3). Despite poor light conditions, regression analyses revealed that TP was the best single predictor of CHLa (R ² = 0.40), though models incorporating both light and TP performed better (R ² = 0.60). Light and nutrient conditions varied widely within rivers and were inversely related, suggesting that riverine phytoplankton may experience shifts in resource limitation during transport. Inferred grazing and sedimentation losses were large yet CHLa concentrations did not decline downriver indicating that growth and loss processes were closely coupled. The contribution by algae to suspended particulate organic matter in these rivers (mean = 41%) was similar to that of lakes (39%) but lower relative to reservoirs (61%).     

Relation of CME Speed and Magnetic Helicity in CME Source Regions on the Sun during the Early Phase of Solar Cycles 23 and 24

To investigate the relations between coronal mass ejection (CME) speed and magnetic field properties measured in the photospheric surface of CME source regions, we selected 22 disk CMEs in the rising and early maximum phases of the current Solar Cycle 24. For the CME speed, we used two-dimensional (2D) projected speed observed by the Large Angle and Spectroscopic Coronagraph onboard the Solar and Heliospheric Observatory (SOHO/LASCO), as well as a 3D speed calculated from the triangulation method using multi-point observations. Two magnetic parameters of CME source regions were considered: the average of magnetic helicity injection rate and the total unsigned magnetic flux. We then classified the selected CMEs into two groups, showing: i) a monotonically increasing pattern with one sign of helicity (group A: 16 CMEs) and ii) a pattern of significant helicity injection followed by its sign reversal (group B: 6 CMEs). We found that: 1) 3D speed generally shows better correlations with the magnetic parameters than the 2D speed for 22 CME events in Solar Cycle 24; 2) 2D speed and the magnetic parameters of 22 CME events in this solar cycle have lower values than those of 47 CME events in Solar Cycle 23; 3) all events of group B in Solar Cycle 24 occur only after the beginning of the maximum phase, a trend well consistent with that shown in Solar Cycle 23; 4) the 2D speed and the helicity parameter of group B events continue to increase in the declining phase of Solar Cycle 23, while those of group A events abruptly decrease in the same period. Our results indicate that the two CME groups have a different tendency in the solar cycle variations of CME speed and the helicity parameters. Active regions that show a complex helicity evolution pattern tend to appear in the maximum and declining phases, while active regions with a relatively simple helicity evolution pattern appear throughout the whole solar cycle.     

One-dimensional Shear Velocity Structure of Northern Africa from Rayleigh Wave Group Velocity Dispersion

—?Rayleigh wave group velocity dispersion measurements from 10?s to 160?s periods have been made for paths traversing Northern Africa. Data were accumulated from the IRIS DMC, GEOSCOPE, and MEDNET seismic networks covering the years 1991–1997. The group velocity measurements are made including the effects of debiasing for instantaneous period and a single-iteration, mode-isolation (phase match) filter. The curves are grouped by tectonic province and compared to tomographic model-based curves in an effort to test and validate the tomographic models. Within each tectonic category (rift, orogenic zone, or craton) group velocity curves from various provinces are similar. Between tectonic categories, however, there are marked differences. The rift related paths exhibit the lowest group velocities observed, and cratonic paths the fastest. One-dimensional shear velocity inversions are performed, and while highly nonunique, the ranges of models show significant differences in upper mantle velocities between the tectonic provinces.¶This work is part of a larger project to determine group velocity maps for North Africa and the Middle East. The work presented here provides important tools for the validation of tomographic group velocity models. This is accomplished by comparing group velocity curves calculated from the tomographic models with carefully selected high-quality group velocity measurements. The final group velocity models will be used in M _s measurements, which will contribute to the m _b :M _s discriminant important to the Comprehensive Nuclear-Test-Ban Treaty (CTBT). The improved shear wave velocity models provided by this study also contribute to the detection, location, and identification of seismic sources.