Toxicity studies of elemental sulfur in marine sediments

Elemental sulfur(ES) is a component essential for proper development of animals, but it can be toxic for aquatic organisms. The objectives of the study reported here included determination of ES concentrations in sediment collected in the area of the Gulf of Gdansk(Baltic Sea) and search for the possible correlations with the ecotoxicity results. Sediment samples were collected from four locations: the Vistula River mouth, in the Port Basin, in the area of discharge of the treated wastewater from the Wastewater Treatment Plant(WWTP) and in the area of the sunken World War Ⅱ s/s 'Stuttgart' shipwreck. The levels of elemental sulfur were determined using a gas chromatograph coupled with a mass spectrometer(GC-MS). Toxicity of marine sediment samples was estimated for three biotest organisms-bioluminescent bacteria Vibrio fischeri, crustacean Heterocypris incongruens, and Synapis alba plant. The highest toxicity of sediments for all indicator organisms was observed in samples taken at the place of the shipwreck(2-100%). The same samples had a high sulfur content(16.7-143.2 μg/g dry weight(d.w.))therefore, it was decided to investigate whether the presence of ES in the sediment in the studied area can have an impact on the results of the ecotoxicity determination in real samples. However, the removal of sulfur from the samples resulted in no significant changes in the level of toxicity of the samples. In this research it could not be confirmed that the presence of elemental sulfur is the only factor responsible for the observed sediment toxicity. It seems that other compounds or their mixtures present in the sediment may have a significant influence on the results obtained.     

The topology and polarization of subbeams associated with the 'drifting' subpulse emission of pulsar B0943+10 – V. A new look at the low-frequency burst-mode emission

This paper reports new observations of pulsar B0943+10 carried out at the Pushchino Radio Astronomy Observatory (PRAO) at the low radio frequencies of 42, 62 and 112 MHz. B0943+10 is well known for its exquisitely regular burst-mode (B-mode) drifting subpulses as well as its weaker and chaotic quiescent mode. Earlier Arecibo investigations at 327 MHz have identified remarkable, continuous changes in its B-mode subpulse drift rate and integrated-profile shape with durations of several hours. These PRAO observations reveal that the changes in profile shape during the B-mode lifetime are strongly frequency dependent – namely the measured changes in the component amplitude ratio are more dramatic at 327 and 112 MHz as compared with those at 62 and 42 MHz. The differences, however, are most marked during the first several tens of minutes after B-mode onset; after an hour or so the profile shape changes tend to be more similar at all four frequencies. We also have found that the linear polarization of the integrated profile increases continuously throughout the lifetime of the B mode, going from hardly 10 per cent just after onset to some 40–50 per cent after several hours. Pulsar B0943+10's B mode thus provides a unique new opportunity to investigate continuous systematic changes in the plasma flow within the polar flux tube. While refraction in the pulsar's magnetosphere may well play some role, we find that the various frequency-dependent effects, both between and within the two modes, can largely be understood geometrically. If the modes and B-mode decay reflect systematic variations in the carousel-'spark' radius and emission height then a specific set of profile and linear polarization changes would be expected.     

Environmental change,hydromorphological reference conditions and the restoration of Polish Carpathian rivers

In the twentieth century Polish Carpathian rivers were considerably modified by channelization and gravel mining, with significant detrimental effects to their ecological integrity, vertical stability of the streambeds and flood hazard to downstream river reaches. Restoration of the rivers is thus necessary to improve their ecological status and re‐establish geomorphic dynamic equilibrium conditions. Various approaches to defining hydromorphological reference conditions, proposed to date in river restoration literature, have serious deficiencies. In particular, environmental changes that took place in the catchments of Carpathian rivers during the twentieth century invalidate the historical state of the rivers as reference for their restoration. This is illustrated by a change from bar‐braided to island‐braided channel pattern that occurred in the past century in unmanaged sections of the Czarny Dunajec in response to a reduction in flow and sediment dynamics of the river. We indicate that reference conditions should be defined as those which exist or would exist under present environmental conditions in the catchment but without human influence on the channel, riparian zone and floodplain of the river which is to be restored. This assumption was tested through the evaluation of hydromorphological river quality of the Czarny Dunajec according to the European Standard EN‐14614. The evaluation confirmed a high‐status hydromorphological quality in an unmanaged channel section, which can thus be used as a reference for restoration of impacted river sections. Copyright © 2012 John Wiley & Sons, Ltd.     

Impact of the azores front propagation on deep ocean particle flux

The Azores Current originating as a branch of the Gulf Stream is a highly dynamic system in the subtropical North Atlantic. The associated front forms the northeastern boundary of the North Atlantic Subtropical Gyre. In this study we analyzed 42 years of assimilated modeled temperature fields to localize the position of the Azores Front at 22°W and observed a fast north- and southward propagation between 30°N and 37°N on monthly to decadal time scales. The North Atlantic Oscillation with correlated changes of the wind direction was identified as one driving mechanism. As the front is acting as a guide for Rossby waves, the signal of the front??s propagation is transferred to the western Atlantic and, among other atmospheric forcing mechanisms, induces a shifting of the Northern Wall of the Gulf Stream with one year delay. Shallower mixed layer depths in the northern frontal region of the Azores Current caused by the rise of the isotherms lead to nutrient supply and primary production different from those found in the southern frontal region of the current system. A high interannual variability is manifested in deep ocean particle flux, derived from a sediment trap in 2000 m water depth at the mooring site KIEL276 (33°N, 22°W) from 1993 to 2008, which is directly related to the phytoplankton bloom in the euphotic zone. This variability is explained by the propagation of the front and strong variations in the catchment areas of the sediment trap due to the associated eddy activity in the frontal region.     

A SIMS zircon age for a biostratigraphically dated Upper Viséan (Asbian) bentonite in the Central-European Variscides (Bardo Unit,Polish Sudetes)

A Lower Carboniferous platform sedimentary sequence (the Paprotnia Beds) in the Bardo Unit of the central Sudetes (NE part of the Bohemian Massif, SW Poland) is biostratigraphically well dated, based on rich macro- and micro-fossil evidence, as Late Viséan (late Asbian, crenistria, Go III α zone). The beds contain several bentonite layers, one of which was dated using the U–Pb SHRIMP method on volcanic zircons and yielded an age of 334 ± 3 Ma. This date fits well to the recently established chronostratigraphic limits of the Viséan, and is consistent with the newest isotopic age constraints of 336.5–332 Ma for the Asbian boundaries.     

Dynamical evolution of triple systems

This article reviews numerical experiments on the three-body problem carried out at the Leningrad University Astronomical Observatory during the past 20 years. Systematic studies of triple systems with negative total energy have yielded the following main results. Most (95%) of the systems decay; the decay always occurs after a close triple approach of the components. In a system with unequal masses, the escaping body usually has the smallest mass. A small fraction (5%) of quasi-stable systems is formed if the angular momentum is non-zero. The qualitative evolution in three-dimensional cases is the same as for planar systems. Small changes in initial conditions sometimes lead to substantial differences in the final outcome. The decay of triple systems is a stochastic process similar to radioactive decay. The estimated mean lifetime is 100 crossing times for equal-mass components and decreases for increasing mass dispersion.A classification of the close triple approaches which lead to immediate escape is given for equal-mass systems as well as for selected sets of unequal components. Detailed studies of close triple approaches by computer simulations reveal that the early evolutions is determined by the initial ratio of the interaction forces. The review concludes by discussing applications of the results to observational problems of stellar and extragalactic systems.