New Reference Materials and Assessment of Matrix Effects for SIMS Measurements of Oxygen Isotopes in Garnet

Accurate ion microprobe analysis of oxygen isotope ratios in garnet requires appropriate reference materials to correct for instrumental mass fractionation that partly depends on the garnet chemistry (matrix effect). The matrix effect correlated with grossular, spessartine and andradite components was characterised for the Cameca IMS 1280HR at the SwissSIMS laboratory based on sixteen reference garnet samples. The correlations fit a second‐degree polynomial with maximum bias of ca. 4‰, 2‰ and 8‰, respectively. While the grossular composition range 0–25% is adequately covered by available reference materials, there is a paucity of them for intermediate compositions. We characterise three new garnet reference materials GRS2, GRS‐JH2 and CAP02 with a grossular content of 88.3 ± 1.2% (2s), 83.3 ± 0.8% and 32.5 ± 3.0%, respectively. Their micro scale homogeneity in oxygen isotope composition was evaluated by multiple SIMS sessions. The reference δ¹⁸O value was determined by CO₂ laser fluorination (δ¹⁸O_LF). GRS2 has δ¹⁸O_LF = 8.01 ± 0.10‰ (2s) and repeatability within each SIMS session of 0.30–0.60‰ (2s), GRS‐JH2 has δ¹⁸O_LF = 18.70 ± 0.08‰ and repeatability of 0.24–0.42‰ and CAP02 has δ¹⁸O_LF = 4.64 ± 0.16‰ and repeatability of 0.40–0.46‰.     

An analytical study on three‐dimensional versus two‐dimensional water table‐induced flow patterns in a Tóthian basin

Although it has been increasingly acknowledged that groundwater flow pattern is complicated in the three‐dimensional (3‐D) domain, two‐dimensional (2‐D) water table‐induced flow models are still widely used to delineate basin‐scale groundwater circulation. However, the validity of 2‐D cross‐sectional flow field induced by water table has been seldom examined. Here, we derive the analytical solution of 3‐D water table‐induced hydraulic head in a Tóthian basin and then examine the validity of 2‐D cross‐sectional models by comparing the flow fields of selected cross sections calculated by the 2‐D cross‐sectional model with those by the 3‐D model, which represents the “true” cases. For cross sections in the recharge or discharge area of the 3‐D basin, even if head difference is not significant, the 2‐D cross‐sectional models result in flow patterns absolutely different from the true ones. For the cross section following the principal direction of groundwater flow, although 2‐D cross‐sectional models would overestimate the penetrating depth of local flow systems and underestimate the recharge/discharge flux, the flow pattern from the cross‐sectional model is similar to the true one and could be close enough to the true one by adjusting the decay exponent and anisotropy ratio of permeability. Consequently, to determine whether a 2‐D cross‐sectional model is applicable, a comparison of hydraulic head difference between 2‐D and 3‐D solutions is not enough. Instead, the similarity of flow pattern should be considered to determine whether a cross‐sectional model is applicable. This study improves understanding of groundwater flow induced by more natural water table undulations in the 3‐D domain and the limitations of 2‐D models accounting for cross‐sectional water table undulation only.     

The price of spice: Ethnic minority livelihoods and cardamom commodity chains in upland northern Vietnam

The northern uplands of Vietnam are witness to rapidly developing commodity markets for a range of forest and agricultural products. Since the early 1990s the cultivation of black cardamom (Amomum aromaticum) has become a source of cash income for a growing number of ethnic minority households in these uplands. Drawing on ethnographic fieldwork, and utilizing a commodity chain and livelihoods approach, this article investigates the contemporary dynamics surrounding the cultivation, harvesting and trade of dried cardamom fruit from Hmong cultivators in Lao Cai province to consumers elsewhere in Vietnam and beyond to China and the global market. We analyse the spatial and social structures of these commodity chains, drawing attention to a range of mechanisms of access. We find that these mechanisms are reliant upon specific ethnic relations as well as different forms of capital that together sustain economic advantages for particular actors. While focusing on the ethnic minority cultivators active in these commodity chains, we also call for more nuanced understandings of how the trade in forest products fits within local agricultural systems and household livelihood decision making processes in the Vietnam uplands.     

Trace element geochemistry of CR chondrite metal

We report trace element analyses by laser ablation inductively coupled plasma mass spectrometry (LA‐ICP‐MS) of metal grains from nine different CR chondrites, distinguishing grains from chondrule interior (“interior grains”), chondrule surficial shells (“margin grains”), and the matrix (“isolated grains”). Save for a few anomalous grains, Ni‐normalized trace element patterns are similar for all three petrographic settings, with largely unfractionated refractory siderophile elements and depleted volatile Au, Cu, Ag, S. All three types of grains are interpreted to derive from a common precursor approximated by the least‐melted, fine‐grained objects in CR chondrites. This also excludes recondensation of metal vapor as the origin of the bulk of margin grains. The metal precursors were presumably formed by incomplete condensation, with evidence for high‐temperature isolation of refractory platinum‐group‐element (PGE)‐rich condensates before mixing with lower temperature PGE‐depleted condensates. The rounded shape of the Ni‐rich, interior grains shows that they were molten and that they equilibrated with silicates upon slow cooling (1–100 K h^?1), largely by oxidation/evaporation of Fe, hence their high Pd content, for example. We propose that Ni‐poorer, amoeboid margin grains, often included in the pyroxene‐rich periphery common to type I chondrules, result from less intense processing of a rim accreted onto the chondrule subsequent to the melting event recorded by the interior grains. This means either that there were two separate heating events, which formed olivine/interior grains and pyroxene/margin grains, respectively, between which dust was accreted around the chondrule, or that there was a single high‐temperature event, of which the chondrule margin records a late “quenching phase,” in which case dust accreted onto chondrules while they were molten. In the latter case, high dust concentrations in the chondrule‐forming region (at least three orders of magnitude above minimum mass solar nebula models) are indicated.     

Soil property variation mapping through data mining of soil category maps

Spatial information on soil properties is an important input to hydrological models. In current hydrological modelling practices, soil property information is often derived from soil category maps by the linking method in which a representative soil property value is linked to each soil polygon. Limited by the area‐class nature of soil category maps, the derived soil property variation is discontinuous and less detailed than high resolution digital terrain or remote sensing data. This research proposed dmSoil, a data‐mining‐based approach to derive continuous and spatially detailed soil property information from soil category maps. First, the soil–environment relationships are extracted through data mining of a soil map. The similarity of the soil at each location to different soil types in the soil map is then estimated using the mined relationships. Prediction of soil property values at each location is made by combining the similarities of the soil at that location to different soil types and the representative soil property values of these soil types. The new approach was applied in the Raffelson Watershed and Pleasant Valley in the Driftless Area of Wisconsin, United States to map soil A horizon texture (in both areas) and depth to soil C horizon (in Pleasant Valley). The property maps from the dmSoil approach capture the spatial gradation and details of soil properties better than those from the linking method. The new approach also shows consistent accuracy improvement at validation points. In addition to the improved performances, the inputs for the dmSoil approach are easy to prepare, and the approach itself is simple to deploy. It provides an effective way to derive better soil property information from soil category maps for hydrological modelling. Copyright © 2014 John Wiley & Sons, Ltd.     

Evolution and Morphodynamics of a Prograded Beach‐Ridge Foreland,Northern Baffin Island,Canadian Arctic Archipelago

Landward retreat (marine transgression) is a common response of coastal systems to rising relative sea level. However, given sufficient sediment supply, the coast may advance seaward. The latter response of gravel barriers has been recorded in parts of southeastern and northwestern Canada, where seaward‐rising sets of beach ridges are observed in areas of Holocene RSL rise. Cape Charles Yorke, northern Baffin Island, is a 5 km long gravel foreland characterized by seaward‐rising beach‐ridge crest elevations. The prograded morphology of the Cape Charles Yorke foreland is a prime example of coastal response to a combination of rising RSL and abundant sediment supply, an unusual and little‐documented pattern in the Canadian Arctic. The main gravel supply to Cape Charles Yorke is likely from eroding bedrock and raised marine deposits southwest of the foreland. Although not the dominant sediment source, the Cape Charles Yorke delta contributed to the formation of the foreland by sheltering it from easterly storm waves and providing an anchor point for the prograding ridges. The truncation of relict ridges by the modern shoreline suggests a recent regime shift from continuous deposition to predominant erosion. The cause and timing of this shift are unknown but could result from a recent dwindling in sediment supply, increased accommodation space, increased wave energy, and/or an accelerated rise of relative sea level.     

Assessment of gully erosion rates through interviews and measurements: a case study from northern Ethiopia

Gullying has been widespread in the Ethiopian Highlands during the 20th century. It threatens the soil resource, lowers crop yields in intergully areas through enhanced drainage and desiccation, and aggravates flooding and reservoir siltation. Knowing the age and rates of gully development during the last few decades will help explain the reasons for current land degradation. In the absence of historical written or photographic documentation, the AGERTIM method (Assessment of Gully Erosion Rates Through Interviews and Measurements) has been developed. It comprises measurements of contemporary gully volumes, monitoring of gully evolution over several years and semi‐structured interview techniques. Gully erosion rates in the Dogu'a Tembien District, Tigray, Ethiopia, were estimated in three representative case‐study areas. In Dingilet, gullying started around 1965 after gradual environmental changes (removal of vegetation from cropland in the catchment and eucalyptus plantation in the valley bottom); rill‐like incisions grew into a gully, which increased rapidly in the drier period between 1977 and 1990. The estimated evolution of the total gully volume in the other areas show patterns similar to those of the Dingilet gully. Average gully erosion rate over the last 50 years is 6·2 t ha^?1 a^?1. Since 1995, no new gullies have developed in the study area. Area‐specific short‐term gully erosion rates are now on average 1·1 t ha^?1 a^?1. The successful application of the AGERTIM method requires an understanding of the geomorphology of the study area and an integration of the researchers with the rural society. It reveals that rapid gully development in the study area is some 50 years old and is mainly caused by human‐induced environmental degradation. Under the present‐day conditions of ‘normal’ rain and catchment‐wide soil and water conservation, gully erosion rates are decreasing. Copyright © 2006 John Wiley & Sons, Ltd.     

A new approach of selecting real input ground motions for seismic design: The most unfavourable real seismic design ground motions

This paper presents a new way of selecting real input ground motions for seismic design and analysis of structures based on a comprehensive method for estimating the damage potential of ground motions, which takes into consideration of various ground motion parameters and structural seismic damage criteria in terms of strength, deformation, hysteretic energy and dual damage of Park & Ang damage index. The proposed comprehensive method fully involves the effects of the intensity, frequency content and duration of ground motions and the dynamic characteristics of structures. Then, the concept of the most unfavourable real seismic design ground motion is introduced. Based on the concept, the most unfavourable real seismic design ground motions for rock, stiff soil, medium soil and soft soil site conditions are selected in terms of three typical period ranges of structures. The selected real strong motion records are suitable for seismic analysis of important structures whose failure or collapse will be avoided at a higher level of confidence during the strong earthquake, as they can cause the greatest damage to structures and thereby result in the highest damage potential from an extended real ground motion database for a given site. In addition, this paper also presents the real input design ground motions with medium damage potential, which can be used for the seismic analysis of structures located at the area with low and moderate seismicity. The most unfavourable real seismic design ground motions are verified by analysing the seismic response of structures. It is concluded that the most unfavourable real seismic design ground motion approach can select the real ground motions that can result in the highest damage potential for a given structure and site condition, and the real ground motions can be mainly used for structures whose failure or collapse will be avoided at a higher level of confidence during the strong earthquake. Copyright © 2007 John Wiley & Sons, Ltd.     

Low calcification rates and calcium carbonate production in Porites panamensis at its northernmost geographic distribution

Porites panamensis is a hermatypic coral present in the eastern Pacific Ocean. Skeletal growth parameters have been reported, but studies of the relationship between annual calcification rates and environmental controls are scarce. In this study, we investigated three aspects of the annual calcification rates of P. panamensis: growth parameters among three P. panamensis populations; the sea surface temperature as a calcification rate control spanning a latitudinal gradient; and calcium carbonate production among three sites. Growth parameters varied among the sites due to the colony growth form. Massive colonies in the north showed a higher calcification rate than encrusting colonies in the south (mean: 1.22–0.49 g CaCO₃ · cm^?2 · yr^?1), where variations in calcification rates were related to growth rate (0.91–0.38 cm · yr^?1) rather than to skeletal density differences (overall mean ± SD, 1.31 ± 0.04 g CaCO₃ · cm^?3). Our results showed a positive linear relationship between annual calcification rates and sea surface temperatures within these P. panamensis populations. Differences were related to distinct oceanographic environments (within and at the entrance of the Gulf of California) with different sea surface temperature regimes and other chemical properties. Different populations calcified under different environmental conditions. Calcium carbonate production was dependent upon the calcification rate and coral cover and so carbonate production was higher in the north (coral cover 12%) than in the south (coral cover 3.5). Thus, the studied sites showed low calcium carbonate production (0.25–0.43 kg CaCO₃ · m^?2 · yr^?1). Our results showed reduced calcification rates, regional temperature regime control over calcification rates, different growth forms, low coral cover and low calcium carbonate production rates in P. panamensis.