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91.
Devleena Mani T. Satish Kumar M. A. Rasheed D. J. Patil A. M. Dayal T. Gnaneshwar Rao V. Balaram 《Natural Resources Research》2011,20(1):75-88
The association of iodine with organic matter in sedimentary basins is well documented. High iodine concentration in soils
overlying oil and gas fields and areas with hydrocarbon microseepage has been observed and used as a geochemical exploratory
tool for hydrocarbons in a few studies. In this study, we measure iodine concentration in soil samples collected from parts
of Deccan Syneclise in the west central India to investigate its potential application as a geochemical indicator for hydrocarbons.
The Deccan Syneclise consists of rifted depositional sites with Gondwana–Mesozoic sediments up to 3.5 km concealed under the
Deccan Traps and is considered prospective for hydrocarbons. The concentration of iodine in soil samples is determined using
ICP-MS and the values range between 1.1 and 19.3 ppm. High iodine values are characteristic of the northern part of the sampled
region. The total organic carbon (TOC) content of the soil samples range between 0.1 and 1.3%. The TOC correlates poorly with
the soil iodine (r
2 < 1), indicating a lack of association of iodine with the surficial organic matter and the possibility of interaction between
the seeping hydrocarbons and soil iodine. Further, the distribution pattern of iodine compares well with two surface geochemical
indicators: the adsorbed light gaseous hydrocarbons (methane through butane) and the propane-oxidizing bacterial populations
in the soil. The integration of geochemical observations show the occurrence of elevated values in the northern part of the
study area, which is also coincident with the presence of exposed dyke swarms that probably serve as conduits for hydrocarbon
microseepage. The corroboration of iodine with existing geological, geophysical, and geochemical data suggests its efficacy
as one of the potential tool in surface geochemical exploration of hydrocarbons. Our study supports Deccan Syneclise to be
promising in terms of its hydrocarbon prospects. 相似文献
92.
Prakash Kumar Shrivastava Rajesh Asthana Sandip Kumar Roy 《Journal of the Geological Society of India》2011,78(2):117-123
Recession of the snout of Dakshin Gangotri glacier in the western part of Schirmacher Oasis, East Antarctica has been recorded
over two decades. However, the rate of retreat is not uniform and varies at different locations. The ice wall forming the
western flank of the glacier has shown an average retreat of 17.07 m between 2001 and 2009 while the snout had gone back by
6.94 m (average) during the same period. Before 2001, the snout had shown a complete recession of 3.13 m (average). The snout
occupies valley area receiving less amount of solar radiation as compared to the western wall, which is a vertical cliff receiving
maximum amount of solar radiation. The notable difference in the rate of recession in different parts of the Dakshin Gangotri
glacier overriding Schirmacher Oasis can be attributed to combined effect of natural factors, including meteorological parameters,
ice sheet dynamics and geomorphology of that area. 相似文献
93.
Rainwater plays an important role in scavenging of aerosols and gases from atmosphere, and its chemistry helps to understand the relative contributions of atmospheric pollution sources. The present work is aimed to understand and explain the sources, seasonal patterns and the processes thereof affecting rainwater chemistry in an urban environment of Delhi, India. Rainwater samples (n = 111) collected throughout the year in New Delhi showed alkalinity in general. Eight rainwater samples, collected in late monsoon and winter season, had pH less than 5.6 indicating that Delhi continues to face the prospects of acid rain despite the introduction of compressed natural gas as the clean fuel in city transport. Organic acids could be the possible contributors of acidity in rainwater samples having the fractional acidity (FA) value of 0.174, which is greater than the annual average FA (0.011) and the (Ca2+ + Mg2+ + NH4 +)/(SO4 2? + NO3 ?) ration of more than one. Average acid neutralization factors of cations decrease in the order Ca2+ (1.01) > NH4 + (0.77) > Mg2+ (0.10). However, neutralization by Ca2+ dominates only in summer season as cation-rich dust is transported from the Great Indian Thar Desert to this region by strong summer S–SW winds, while NH4 + dominates in rainwater of other three sampling seasons. Identified dominant sources for soluble ions in rainwater are (1) non-silicate crustal source for carbonates and sulfates of Ca and Mg, (2) emissions from catalytic convertor-fitted vehicles and agriculture fields for NH3 and (3) mixed anthropogenic sources for SO4 2?, NO3 ? and Cl?. Rainwater chemistry showed significant seasonal variations. This could be due to the changes in relative proportions of natural and anthropogenic sources of soluble ions to rainwater. Dominance of anthropogenic sources over crustal sources can result in acidic rains, which can adversely affect the environment and human health in this region. 相似文献
94.
Arsenic is present in groundwater at Siliguri–Jalpaiguri area, West Bengal, India. This is the place where Tista river descending
from the Himalayas meets the alluvial plain. The area represents alluvial fan and floodplains of Tista, Mahananda-Balasan,
Jaladhaka and its tributaries. In the river sediment samples, para- and ferro-magnetic minerals within 0.3–0.05 mm fraction
contain 9–80 ppm of arsenic. The study indicates that iron bearing minerals viz. biotite, hornblende as well as iron coated
grains of the sediment are major contributors towards arsenic budget. Though magnetite as a mineral shows maximum arsenic
content (22 ppm), it is volumetrically not of much significance. Measurement of groundwater collected from tube wells shows
up to 0.05 ppm of arsenic. These arsenic contaminated tube wells occur in a linear fashion along the course of the rivers.
Moreover, localization of contaminated tube wells coincides with the change of channel gradient as observed in longitudinal
section. The study enumerates a cause–effect relationship of arsenic occurrence with river gradient and fluvial sedimentation. 相似文献
95.
Martin?J.?WhitehouseEmail author G.?R.?Ravindra Kumar Andrius?Rim?a 《Contributions to Mineralogy and Petrology》2014,168(2):1042
Zircon crystals from a locally charnockitized Paleoproterozoic high-K metagranite from the Kerala Khondalite Belt (KKB) of southern India have been investigated by high-spatial resolution secondary ion mass spectrometry analysis of U–Th–Pb and rare earth elements (REE), together with scanning ion imaging and scanning ion tomography (depth-profiled ion imaging). The spot analyses constrain the magmatic crystallization age of the metagranite to ca. 1,850 Ma, with ultrahigh-temperature (UHT) metamorphism occurring at ca. 570 Ma and superimposed charnockite formation at ca. 520–510 Ma, while the ion imaging reveals a patchy distribution of radiogenic Pb throughout the zircon cores. Middle- to heavy-REE depletion in ca. 570 Ma zircon rims suggests that these grew in equilibrium with garnet and therefore date the UHT metamorphism in the KKB. The maximum apparent 207Pb/206Pb age obtained from the unsupported radiogenic Pb concentrations is also consistent with formation of the Pb patches during this event. The superimposed charnockitization event appears to have caused additional Pb-loss in the cores and recrystallization of the rims. The results of depth-profiling of the scanning ion tomography image stack show that the Pb-rich domains range in size from <5 nm to several 10 nm (diameter if assumed to be spherical). The occurrence of such patchy Pb has previously been documented only from UHT metamorphic zircon, where it likely results from annealing of radiation-damaged zircon. The formation of a discrete, heterogeneously distributed and subsequently immobile Pb phase effectively arrests the normal Pb-loss process seen at lower grades of metamorphism. 相似文献
96.
Study of subsurface geology in locating arsenic-free groundwater in Bengal delta,West Bengal,India 总被引:1,自引:0,他引:1
Over a large area of the Bengal delta in West Bengal, India, arsenic distribution patterns in groundwater were studied. One
hundred and ten boreholes at different target locations were made, subsurface sediments were logged and analysed, and arsenic
values in sediments vis-à-vis groundwater were compared. The study elucidates the subsurface geology of the western part of
Bengal delta and characterises the sediments that were intersected in different boreholes with contrasting values of arsenic
in groundwater. It reveals an existence of multiple aquifers stacked over each other. Depending on the color and nature of
aquifer-sands and their overlying clay beds six aquifer types (Type-1 to Type-6) are classified and described. Sediment-arsenic
for all the varieties of aquifer sands are near similar but the groundwater-arsenic of these six aquifers varies widely. Type-2
and Type-5 aquifers host arsenic-contaminated groundwater whereas the other four aquifers are arsenic-free. Type-2 and Type-5
aquifers are capped by a grey to dark grey soft organic matter-rich clay unit which makes these aquifers semi-confined to
leaky-confined. These contribute in releasing arsenic from the sediments. The results of this study are employed in a proposed
georemedial measure against this hazardous toxic element. 相似文献
97.
Manish Kumar Bhawna Sharma AL. Ramanathan M. Someshwar Rao Bhishm Kumar 《Environmental Geology》2009,56(6):1171-1181
Present study is an effort to distinguish between the contributions of natural weathering and anthropogenic inputs towards
high salinity and nutrient concentrations in the groundwater of National Capital Territory (NCT) Delhi, India. Apart from
the source identification, the aquifer of entire territory has been characterized and mapped on the basis of salinity in space
and water suitability with its depth. Major element chemistry, conventional graphical plots and specific ionic ratio of Na+/Cl−, SO4
2−/Cl−, Mg2+/Ca2+ and Ca2+/(HCO3
− + SO4
2−) are conjointly used to distinguish different salinization sources. Results suggest that leaching from the various unlined
landfill sites and drains is the prime cause of NO3
− contamination while study area is highly affected with inland salinity which is geogenic in origin. The seasonal water level
fluctuation and rising water level increases nutrients concentration in groundwater. Mixing with old saline sub-surface groundwater
and dissolution of surface salts in the salt affected soil areas were identified as the principle processes controlling groundwater
salinity through comparison of ionic ratio. Only minor increase of salinity is the result of evaporation effect and pollution
inflows. The entire territory has characterized into four groups as fresh, freshening, near freshening and saline with respect
to salinity in groundwater. The salinity mapping suggests that in general, for drinking needs, groundwater in the fresh, freshening
and near freshening zone is suitable up to a depth of 45, 20 and 12 m, respectively, while the saline zones are unsuitable
for any domestic use. In the consideration of increasing demand of drinking water in the area; present study is vital and
recommends further isotopic investigations and highlights the need of immediate management action for landfill sites and unlined
drains. 相似文献
98.
T. Madhavi T. Satish Kumar M. A. Rasheed G. Kalpana D. J. Patil A. M. Dayal 《Journal of the Geological Society of India》2009,74(1):7-15
A study was carried out to test the usefulness of surface geochemical methods as regional evaluation tools in petroliferous
region of the Mehsana block, North Cambay Basin. A suite of 135 soil samples collected from the depth of 2.5 m, were analyzed
for adsorbed light gaseous hydrocarbons and carbon isotopes (δ13Cmethane and δ13Cethane). The light gaseous hydrocarbon analysis show that the concentration ranges 402 ppb, 135 ppb, 70 ppb, 9 ppb and 18 ppb of
C1, C2, C3, iC4 and nC4, respectively. The value of carbon isotopic ranges of methane −29.5 to −43.0‰ (PDB) and ethane −19.1 to −20.9‰ (PDB). This
data, when mapped, indicates patterns coinciding with major known oil and/or gas field of Sobhasan/Linch in this study area.
The existence of un-altered petroliferous microseeps of catagenetic origin is observed in the study area. A regional study,
such as the one described here, can provide important exploration facts concerning the regional hydrocarbon potential in a
block. This method has been confirmed and can be applied successfully in frontier basins. 相似文献
99.
M. S. Rao Gopal Krishan C. P. Kumar P. Purushothaman Sudhir Kumar 《Environmental Earth Sciences》2017,76(4):175
The continuous and large-scale abstraction of groundwater has created a groundwater depletion problem in several parts of the Punjab state including Bist Doab, the interfluve region of Beas and Satluj rivers. In the present study, a few important parameters, viz. water level, stable isotope, EC, temperature, groundwater age, that can be used to fingerprint the over-exploitation of groundwater have been examined. It has been observed that with the increase in over-exploitation, the yield of shallow aquifer is progressively getting reduced and as a result forcing the farmers to sink their wells to deeper depths. With abstraction of deeper aquifer, the storage of old groundwater at the deeper aquifer is declining and getting replaced by induced accelerated inflow of young water from the recharge zone and the overlying shallow aquifer. The signatures of the modern water have been observed in the data analyzed for isotopic, hydro-chemical facies, electrical conductivity and temperature of water from deeper aquifer. The study has identified the usefulness of these parameters for identifying groundwater over-exploitation in the region. Depleting water resource may stagnate the economic progress of the region. The paper provides suitable water resource management strategies to be adopted to improve the sustainability of water resources and economic growth in the region. 相似文献
100.
Sitharam G. Thallak Sireesh Saride Sujit Kumar Dash 《Geotechnical and Geological Engineering》2007,25(5):509-524
This paper presents the results of laboratory model tests carried out to develop an understanding of the behaviour of geocell-reinforced
soft clay foundations under circular loading. Natural silty clay was used in this study. The geocells were prepared using
biaxial polymer grid. The performance of the reinforced bed is quantified using non-dimensional factors i.e., Bearing capacity
improvement factor (If) and Percentage reduction in footing settlement (PRS). The test results demonstrate that the geocell mattress redistributes
the footing load over a wider area thereby improving the performance of the footing. The load carrying capacity of the clay
bed is increased by a factor of up to about 4.5 times that of unreinforced bed. From the pressure-settlement responses, it
is observed that the geocell-reinforced foundation bed behaves as a much stiffer system compared to the unreinforced case
indicating that a substantial reduction in footing settlement can be achieved by providing geocell reinforcement in the soft
clay bed. The maximum reduction in footing settlement obtained with the provision of geocell mattress of optimum size placed
close to the footing is around 90%. Further improvement in performance is obtained with provision of an additional planar
geogrid layer at the base of the geocell mattress. 相似文献