Hydromagnetic stability of some non-dissipative flows subject to non-axisymmetric disturbances

We study the linear stability of nondissipative flow of an electrically conducting fluid subject to non-axisymmetric disturbances in the following cases: (i) the radial flow of an incompressible fluid between two concentric porous circular cylinders in the presence of a radial magnetic field and (ii) axial flow of a compressible fluid between two concentric circular cylinders permeated by a helical magnetic field (0,B ₀(r),B _0z) in a cylindrical coordinate system. It is shown that in case (i), the flow is stable if the Alfvén velocity based on the undisturbed radial magnetic field exceeds the radial velocity due to suction or injection at the cylinder surfaces. In case (ii), it is found that under certain conditions the complex wave speed for an unstable mode lies within a circle of diameterW _max-W _min, whereW _max andW _min are the maximum and minimum values of the axial velocity in the flow region. In the presence of a purely axial magnetic field, however, the complex wave speed for an unstable mode always lies within the above circle.     

Adsorption kinetic control of As(III &; V) mobilization and sequestration by Mangrove sediment

Elevated concentrations of arsenic in the sediment and pore water in the Sundarban wetlands pose an environmental risk. Adsorption and desorption are hypothesized to be the major processes controlling arsenic retention in surface sediment under oxic/suboxic condition. This study aims to investigate sorption kinetics of As(III & V) and its feedback to arsenic mobilization in the mangrove sediment. It ranges from sand to silty clay loam and shows the adsorption of As(III & V) following the Langmuir relation. Estimates of the maximum adsorption capacity are 59.11 ± 13.26 μg g⁻¹ for As(III) and 58.45 ± 8.75 μg g⁻¹ at 30°C for As(V) in the pH range 4 to 8 and salinity 15–30 psu. Extent of adsorption decreases with increasing pH from 4 to 8 and desorption is the rate-limiting step in the reaction of arsenic with sediment. Arsenic in the sediment could be from a Himalayan supply and co-deposited organic matter drives its release from the sediment. Arsenic concentration in the sediment is well below its maximum absorption capacity, suggesting the release of sorbed arsenic in pore water by the microbial oxidation of organic matter in the sediment with less feedback of adsorption.     

Activity-composition relation of jadeite in omphacite pyroxene: Theoretical deductions

Theoretical considerations suggest that the activity coefficient of jadeite in natural multicomponent omphacite pyroxene can be approximated by an expression of the form RTlnγ_jd ? W₁₂ (X_Di + X_Hed) (I ? X_Jd), where W₁₂ is an adjustable interchange parameter in the jadeite-diopside join, and X stands for the mole fraction of the specified component in the pyroxene solid solution. Synthesis of the available experimental and observational data yields W₁₂ ? ? 1400 (± 1400) + 1.16 (± 1.16) cal/mole, suggesting a nearly ideal solution around 1100°C, and negative departure from ideality at low temperature of the jadeite-diopside solid solution.     

Regional and seasonal intercomparison of CMIP3 and CMIP5 climate model ensembles for temperature and precipitation

Regional and seasonal temperature and precipitation over land are compared across two generations of global climate model ensembles, specifically, CMIP5 and CMIP3, through historical twentieth century skills and multi-model agreement, and twenty first century projections. A suite of diagnostic and performance metrics, ranging from spatial bias or model-consensus maps and aggregate time series plots, to measures of equivalence between probability density functions and Taylor diagrams, are used for the intercomparisons. Pairwise and multi-model ensemble comparisons were performed for 11 models, which were selected based on data availability and resolutions. Results suggest little change in the central tendency or variability or uncertainty of historical skills or consensus across the two generations of models. However, there are regions and seasons, at different levels of aggregation, where significant changes, performance improvements, and even degradation in skills, are suggested. The insights may provide directions for further improvements in next generations of climate models, and in the meantime, help inform adaptation and policy.     

Evaluation of phase chemistry and petrochemical aspects of Samchampi-Samteran differentiated alkaline complex of Mikir Hills,northeastern India

The Samchampi-Samteran alkaline complex occurs as a plug-like pluton within the Precambrian granite gneisses of Mikir Hills, Assam, northeastern India and it is genetically related to Sylhet Traps. The intrusive complex is marked by dominant development of syenite within which ijolitemelteigite suite of rocks is emplaced with an arcuate outcrop pattern. Inliers of alkali pyroxenite and alkali gabbro occur within this ijolite-melteigite suite of rocks. The pluton is also traversed by younger intrusives of nepheline syenite and carbonatite. Development of sporadic, lumpy magnetite ore bodies is also recorded within the pluton. Petrographic details of the constituent lithomembers of the pluton have been presented following standard nomenclatorial rules. Overall pyroxene compositions range from diopside to aegirine augite while alkali feldspars are typically orthoclase and plagioclase in syenite corresponds to oligoclase species. Phase chemistry of nepheline is suggestive of Na-rich alkaline character of the complex. Biotite compositions are typically restricted to a uniform compositional range and they belong to ‘biotite’ field in the relevant classification scheme. Garnets (developed in syenite and melteigite) typically tend to be Ti-rich andradite, which on a closer scan can be further designated as melanites. Opaque minerals mostly correspond to magnetite. Use of Lindsley’s pyroxene thermometric method suggests an equilibration temperature from ∼450°–600°C for melteigite/alkali gabbro and ∼400°C for syenite. Critical assessment of other thermometric methods reveals a temperature of equilibration of ∼700°–1350°C for ijolite-melteigite suite of rocks in contrast to a relatively lower equilibration temperature of ∼600°C for syenite. Geobarometric data based on pyroxene chemistry yield an equilibration pressure of 5.32–7.72 kb for ijolite, melteigite, alkali pyroxenite, alkali gabbro and nepheline syenite. The dominant syenite member of the intrusive plug records a much higher (∼11 kb) equilibration pressure indicating a deeper level of intrusion. Major oxide variations of constituent lithomembers with respect to differentiation index (D.I.) corroborate a normal magmatic differentiation. A prominent role of liquid immiscibility is envisaged from field geological, petrographic and petrochemical evidences. Tectonic discrimination diagrams involving clinopyroxene chemistry strongly suggest within plate alkaline affinity for the parental magma which is in conformity with the regional plume tectonics.     

Geothermal reservoirs — A brief review

A brief discussion and review of the geothermal reservoir systems, geothermal energy and modeling and simulation of the geothermal reservoirs has been presented here. Different types of geothermal reservoirs and their governing equations have been discussed first. The conceptual and numerical modeling along with the representation of flow though fractured media, some issues related to non isothermal flow through fractured media, the efficiency of the geothermal reservoir, structure of the numerical models, boundary conditions and calibration procedures have been illustrated. A brief picture of the Indian scenario and some barriers related with geothermal power are discussed and presented thereafter. Finally some gaps of the existing knowledge and recent focuses of research are discussed.     

Isolation of hydrocarbonoclastic bacteria from bilge oil contaminated water

Two bacterial strains, i.e. Pseudomonas mendocina and Ochrobactrum sp. were isolated from bilge oil contaminated water of Mormugao harbour, Goa, India and grown in a culture medium with hexadecane as the sole carbon source. Pseudomonas mendocina was used in further studies as it was the dominant strain. This strain effectively degraded tetradecane, hexadecane and octadecane leaving a residual concentration of about 73 %, 54 % and 40 % respectively in 120 h. Sequence analysis of the dominant bands from the denaturing gradient gel electrophoresis profiles revealed the differences between the genera of bilge oil contaminated sea water and its enrichment culture on hexadecane indicating a shift in community structure based on the type of substrate available. Pseudomonas mendocina amplified for the following catabolic genes namely C23O, nid and ndo. Based on the catabolic gene study the potential of the bacterial strain isolated, i.e. Pseudomonas mendocina seems to be interesting as it will be able to degrade polyaromatic hydrocarbons as well. Physicochemical properties of Pseudomonas mendocina indicates production of exopolysaccharides based on the value of its isoelectric point.     

Vanadium bearing titaniferous magnetite ore bodies of Ganjang,Karbi-Anglong District,Northeastern India

A new occurrence of (syenite-hosted) Vanadium bearing titaniferous magnetite ore body has been reported from Ganjang (26°09′35″ N: 93°20′ E), Karbi-Anglong, Northeastern India. The magnetite ore bodies have lumpy and sporadic occurrences within the host syenite pluton intrusive into gneissic country rocks. Ore microscopic studies reveal that magnetite is often associated with haematite and ilmenite depicting different textural patterns. Critical consideration of several elemental patterns suggests magmatic differentiation to be main ore-forming process. The ore body is suggested to have been formed as late stage segregation from a differentiating alkaline magma in a fluid enriched milieu.     

Cr diffusion in orthopyroxene: Experimental determination, Mn-Cr thermochronology, and planetary applications

We have determined Cr diffusion coefficients (D) in orthopyroxene parallel to the a-, b-, and c-axial directions as a function temperature at f(O₂) corresponding to those of the wüstite-iron (WI) buffer. Diffusion is found to be significantly anisotropic with D(//c) > D(//b) > D(//a), conforming to an earlier theoretical prediction. Increase of f(O₂) from WI buffer conditions to 4.5 log unit above the buffer at 950 and 1050 °C leads to decrease of D(Cr) by a factor of two to three, possibly suggesting significant contribution from an interstitial diffusion mechanism. We have used the diffusion data to calculate the closure temperatures (T_c) of the Mn-Cr decay system in orthopyroxene as a function of initial temperature (T₀), grain size (a) and cooling rate for spherical and plane sheet geometries. We also present graphical relations that permit retrieval of cooling rates from knowledge of the resetting of Mn-Cr ages in orthopyroxene during cooling, T₀ and a. Application of these relations to the Mn-Cr age data of the cumulate eucrite Serra de Magé yields a T_c of 830-980 °C, and cooling rates of 2-27 °C/Myr at T_c and ∼1-13 °C/Myr at 500 °C. It is shown that the cooling of Serra de Magé to the closure temperature of the Mn-Cr system took place at its original site in the parent body, and thus implies a thickness for the eucrite crust in the commonly accepted HED parent body, Vesta, of greater than 30 km. This thickness of the eucrite crust is compatible only with a model of relatively olivine-poor bulk mineralogy in which olivine constitutes 19.7% of the total asteroidal mass.     

Are Majhgawan-Hinota pipe rocks truly group-I Kimberlite?

The diamond bearing pipe rocks in Majhgawan-Hinota (more than four pipes) occur as intrusives in sandstones of Kaimur Group. These Proterozoic (974 ±30-1170 ±20 Ma) intrusive rocks, occupying the southeastern margin of Aravalli craton, were called as ‘micaceous kimberlite’ in tune with the reported kimberlite occurrences from other parts of the world. Judging from the definition of kimberlite, as approved by the IUGS Subcommission on Systematics of Igneous Rocks, it is not justified to call these rocks as ‘micaceous kimberlite’. Rather the mineralogical assemblages such as absence of typomorphic mineral monticellite (primary), abundance of phlogopite cognate, frequent presence of barite and primary carbonate mostly as calcite coupled with ultrapotassic and volatile-rich (dominantly H₂O) nature and high concentration of incompatible elements (such as Ba, Zr, Th, U), low Th/U ratios, low REE and no Eu-anomaly clearly indicate a close similarity with that of South African orangeites. Thus orangeites of Proterozoic age occur outside the Kaapvaal craton of South Africa which are much younger (200 Ma to 110 Ma) in age.