The Isotopic Composition of Noble Gases in Gold Deposits and the Source of Ore- Forming Materials in the Region of North Hebei, China

1IntroductionOnthenorthernmarginoftheNorthChinaplatformislocatedoneofthemostimportantAu Ag polymetallicore concentratedzones,wherethereareavarietyoforetypes .Soithasbeenat tractingeverincreasingattentionofmanygeologists (PeiRongfuetal.,1 998;ShenBaofengetal.,1 994 ;LuSongnianetal.,1 997;HuShouxietal.,1 994 ;ChenYuchuan ,1 999;ZhaiYushengetal.,1 999) .Manyscholarspresentedtheirresearchresultsinvariousaspects.How ever ,thesourceofore formingmaterialshaslongbeenafocusofdiscussion .Studieso…     

冷原子荧光法直接测定海水中痕量汞

用冷原子荧光直接测定海水中的痕量汞,目前在我国还未正式使用.国内外普遍使用的是无焰原子吸收或冷原子吸收法进行直接分析或富集浓缩后进行分析[1,2].但富集法步骤麻烦、装置复杂、容使样品污染,且样品用量大,要消耗大量的试剂和分析时间.本文叙述了利用国产YYG-77型冷原子荧光测汞仪[3,4,5],改进了还原器,使用封闭进样,使整个体系在测量时处于封闭状态,消除了由于空气进入而产生的荧光猝灭;同时对不同的进样方式作了比较实验.通过大量实验,选择了最佳实验条件和适当的反应的体积,取样量改为50毫升,使本方法的检测限由原仪器的0.05微克/升降低到0.002微克/升;精密度为2-5%.每个样品的测定时间只需40-60秒.本方法适于天然海水中痕量汞的测定,也便于海上操作.     

循环流化床燃烧过程自适应双环选择控制系统

本文根据循环流化床燃烧过程的动态特性和现场运行经验 ,提出了 1种符合实际应用的自适应双环选择控制系统。该系统在床层温度不越限的情况下 ,以控制主蒸汽压力稳定为主要目标。当床层温度发生越限时 ,系统自动变换控制策略并调整床层温度恢复到正常 ,这种控制方式有效地减弱了主蒸汽压力与床层温度之间的耦合关系。该系统结构简单、实用 ,具有工程应用价值 ,现场运行收到较好的控制效果     

Experimental study on damage failure mechanical characteristics and crack evolution of water-bearing surrounding rock

Water plays an important role in the mechanical properties of roadway surrounding rocks and poses a great threat to their stability. To study the damage and failure characteristics, and the fracture development laws of surrounding rock, a uniaxial compression test for prefabricated fractures in water-bearing surrounding rock was carried out. Results indicate that water-bearing prefabricated fracture specimens are in better development condition after failure. In water-bearing specimens, the propagation direction is more complex. There are more secondary fissures, and the fracture strength is significantly lower than in dry specimens. When immersed in water, the interior structure of surrounding rock is weakened and softened; thus, the intensity is reduced, and the development and propagation of fractures is promoted. For larger angles of the prefabricated fractures, the compression failure of surrounding rock changes into shear failure. As the angles approach 90°, the shear failure again prevails. Therefore, the strength of the surrounding rock firstly decreases and then increases. A new ultimate stress strength model is developed for fractures caused by shear slip failure in water-bearing surrounding rock. The model results are consistent with the experimental results, and the validity of the model is verified. These results are helpful for deeply understanding the failure process of water-bearing surrounding rock with prefabricated fractures. The proposed model could be used for the evaluation of water-bearing surrounding rock stability in coal mines, as well as dynamic risk monitoring.     

An anionic biopolymer γ-polyglutamate enhanced the microbially induced carbonate precipitation for soil improvement: mechanical behaviors and underlying mechanism

The use of biopolymer to improve the performance of microbially induced carbonate precipitation (MICP)-treated sands is a novel and eco-friendly concept. This work found an anionic biopolymer, γ-polyglutamate (γ-PGA), could significantly improve the performance of MICP-treated sands. Comparing the control with absence of γ-PGA, the concentration of 0.1–9 g/L γ-PGA increased the compressive strength of MICP-treated sands by 1.54–3.96 times and significantly reduced the brittleness. The MICP process analysis and microstructural detection demonstrated that γ-PGA in the specimens provided many nucleation sites and templates for calcite generation, partially kept the bacterial urease activity by replacement of the bacteria as nucleation sites, thereby improving the calcite generation. The γ-PGA also cemented sand grains with calcite through the hydrogen bond-type intermolecular interactions. Both the calcite generation and the hydrogen bond-type intermolecular interactions by γ-PGA played vital roles in enhancing MICP for soil improvement. Additionally, γ-PGA, as a viscoelastic admixture between the crystals and sand grains, effectively dissipated the energy of stress and thus reduced the brittleness of MICP-treated sands. This is the first report on the application of anionic biopolymer to MICP technology. It provides a novel concept in promoting the efficiency and sustainability of MICP.

     

Newly recorded bloom-forming dinoflagellate Gymnodinium impudicum in Haizhou Bay,Yellow Sea,China

Journal of Oceanology and Limnology - With the development of industrialization and aquaculture in Jiangsu and Shandong Provinces along the South Yellow Sea coast, China, eutrophication has greatly...     

海南岛北部晚新生代玄武岩成分演化及成因讨论

板内玄武岩通常具有复杂的成分组成和成因过程。海南岛北部（简称“琼北”）自渐新世始逐渐发育了大量板内玄武岩,岩性跨度大,从石英拉斑玄武岩到橄榄拉斑玄武岩,再到碱性橄榄玄武岩和碧玄岩均有分布。对琼北晚新生代玄武岩虽已开展了广泛的研究,但“琼北晚新生代玄武岩的成分随时间演化规律”这一问题却未引起足够的关注。本文从晚更新世道堂组橄榄玄武岩入手,对其开展了细致的岩石学、矿物学和主微量及Sr- Nd- Pb同位素地球化学的研究;并结合文献中琼北其他时代（组）玄武岩的数据,阐述了琼北晚新生代玄武岩成分随时间演化的规律并对其成因进行了探讨。研究发现,自中—上新世到更新世再到全新世,琼北晚新生代玄武岩呈现从碱性玄武岩过渡到拉斑玄武岩再突变到碱性—强碱性系列的演化规律;中—上新世到更新世这一时期的碱性玄武岩和拉斑玄武岩可能形成于石榴子石二辉橄榄岩由低到高程度的部分熔融作用,而全新世碱性岩则更可能形成于石榴子石辉石岩的部分熔融。琼北晚新生代玄武岩的Sr- Nd- Pb同位素组成揭示其源区地幔以PREMA端元为主,但经历了来自古老陆壳的沉积物不同程度的改造作用。采用“海南地幔柱”模型可以较好地解释琼北晚新生代玄武岩的复杂组成和成因。     

渤中19-6潜山构造带凝析油中轻烃地球化学特征及意义

为了明确渤海湾盆地渤中19-6大气田的地化特征和成因,选取研究区潜山凝析气藏7个凝析油样品进行全油色谱分析,剖析其轻烃组成特征,探讨轻烃参数在该区的地质应用.结果表明:渤中19-6凝析油的Mango轻烃参数K₁和K₂值相对稳定,表明研究区原油成因类型基本一致.C₆~C₈组成中正构烷烃具显著优势,甲基环己烷指数平均为39%;庚烷值与异庚烷值,正庚烷/甲基环己烷（F）比值较高,反映它们较高成熟度;轻烃参数计算原油生成温度为125.8~128.1 ℃,其相对偏低,可能与取样过程中凝析油的相态变化有关;2-甲基戊烷/3-甲基戊烷,2-甲基己烷/3-甲基己烷比值高,K₂值低;凝析油正构烷烃摩尔浓度呈三段式分布,甲苯/正庚烷和原油蜡含量随深度而增加.结合饱和烃参数以及金刚烷参数揭示渤中19-6潜山油气为湖相腐泥Ⅱ₁型母质在高成熟阶段（Ro=1.05%~1.30%）的产物,气藏形成后发生一定程度分馏造成油气组分调整.      

Experiment and Study on Mechanical Property of Sandstone Post-peak Under the Cyclic Loading and Unloading

Engineering research has shown that the surrounding rock of deep roadways experienced many times of post-peak cyclic loading and unloading. So studying on rock mechanical characteristics of post-peak loading and unloading is helpful to control the deep surrounding rocks. The test using RMT-150B rock mechanics testing system, to experiment on the mechanical properties of sandstone of post-peak cyclic loading and unloading. The results show that: the stress–strain curves of post-peak cyclic loading and unloading have significant plastic hysteretic loops. The area of plastic hysteretic loops gloss back. The enveloping outer enclosure of cycle loading curve is the similar as the stress–strain curves of strain softening stage when the samples failure, which shows that post-peak failure of rocks have significant memory. With the increase of cycles, the cumulative deterioration parameters are gradually increased, and the ultimate bearing capacity, elastic of loading section of samples and cumulative deterioration parameters conform with the exponential attenuation function with constant term. With the increase of surrounding pressure, the total energy, dissipated energy and elastic energy of samples are gradually increased. With the increase of cycles, the total energy, dissipated energy and elastic energy of samples all are gradually decreasing, the rate of reduction decreases gradually. The samples exist in vertical splitting and transverse shear combination failure under the post-peak uniaxial cycles, or exist in shear failure under the post-peak triaxial cycles. The shear plane exists slip traces.