Alpine reworking of Ordovician protoliths in the Western Carpathians: Geochronological and geochemical data on the Muráñ Gneiss Complex, Slovakia

Magmatic protoliths of Ordovician age have been identified in the metamorphic rocks of the Muráñ Gneiss Complex, Veporic Unit (Central Western Carpathians). Vapor digestion single zircon U–Pb dating yields an intrusion age of 464 ± 35 Ma (upper intercept) for the granite protolith. A lower intercept age of 88 ± 40 Ma records amphibolite-facies metamorphic overprint in the Cretaceous, during the Alpine orogeny. Geochemical and isotopic data suggest crustal origin of the orthogneiss. Nd_initial are between − 2.6 and − 5.0 and T_DM^Nd between 1.3 and 1.5 Ga (two-step approach). ⁸⁷Sr / ⁸⁶Sr_initial ratios vary between 0.7247 and 0.7120, and a steep REE pattern further constrains the crustal affinity of these rocks. Associated amphibolite bodies have Nd_initial values of 6.5, ⁸⁷Sr / ⁸⁶Sr_initial ratio of 0.7017, and a flat REE pattern. They are interpreted as MORB derived metabasites. Whole-rock Pb isotope analyses define a linear array in a ²⁰⁶Pb / ²⁰⁴Pb vs. ²⁰⁷Pb / ²⁰⁴Pb diagram with an age of ca. 134 Ma, consistent with intense Alpine metamorphism and deformation.

These basement rocks of the Central Western Carpathians are interpreted as Ordovician magmatic rocks intruded at an active margin of Gondwana. They represent the eastern prolongation of Cambro–Ordovician units of the European Variscides, which were part of the peri-Gondwana superterrane and accreted to Laurussia during the Variscan orogeny. Variscan metamorphic overprint is not recorded by the isotopic data of the Muráñ Gneiss Complex. Alpine metamorphism is the most dominant overprint.     

Study of geothermal water intrusion due to groundwater exploitation in the Puebla Valley aquifer system, Mexico

Significant intrusion of geothermal water into fresh groundwater takes place in the Puebla Valley aquifer system, Mexico. The decline in the potentiometric surface due to the overexploitation of the groundwater induces this intrusion. This hydrological system comprises three aquifers located in Plio-Quaternary volcanic sediments and Mesozoic calcareous rocks. The hydraulic balance of the aquifer shows that the annual output exceeds the natural inputs by 12 million m³. Between 1973 and 2002, a drop in the potentiometric surface, with an 80 m cone of depression, was identified in a 5-km-wide area located southwest of the city of Puebla. Chemical analyses performed on water samples since 1990 have shown an increase in total dissolved solids (TDS) of more than 500 mg/L, coinciding with the region showing a cone of depression in the potentiometric surface. A three-dimensional flow and transport model, based on the hydrogeological and geophysical studies, was computed by using the MODFLOW and MT3D software. This model reproduces the evolution of the aquifer system during the last 30 years and predicts for 2010 an additional drawdown in the potentiometric surface of 15 m, and an increase in the geothermal water intrusion.     

A Practical Procedure for the Measurement of Fragmentation by Blasting by Image Analysis

Summary. The operation of a digital image analysis system in a limestone quarry is described. The calibration of the system, required in order to obtain moderately reliable fragmentation values, is done from muckpile sieving data by tuning the image analysis software settings so that the fragmentation curve obtained matches as close as possible the sieving. The sieving data have also been used to extend the fragment size distribution curves measured to sizes below the system’s optical resolution and to process the results in terms of fragmented rock, discounting the material coming from a loose overburden (natural fines) that is cast together with the fragmented rock. Automatic and manual operation modes of the image analysis are compared. The total fragmentation of a blast is obtained from the analysis of twenty photographs; a criterion for the elimination of outlier photographs has been adopted using a robust statistic. The limitations of the measurement system due to sampling, image processing and fines corrections are discussed and the errors estimated whenever possible. An analysis of consistency of the results based on the known amount of natural fines is made. Blasts with large differences in the amount of fines require a differentiated treatment, as the fine sizes tend to be the more underestimated in the image analysis as they become more abundant; this has been accomplished by means of a variable fines adjustment factor. Despite of the unavoidable errors and the large dispersion always associated with large-scale rock blasting data, the system is sensitive to relative changes in fragmentation.     

Will the river Irtysh survive the year 2030? Impact of long-term unsuitable land use and water management of the upper stretch of the river catchment (North Kazakhstan)

The Irtysh river basin all the way from river spring in China across Kazakhstan as far as the Russian part of Siberia is among the most ecologically endangered and affected regions on our planet. The study provides a summary of the historical reasons for anthropological interventions in this area, which began with the construction of plants of the military—industrial complexes in the forties of the last century during World War II. These plants have a major share in extreme high concentrations of heavy metals in surface as well in groundwaters locally. The Semipalatinsk nuclear polygon plays a specific role as a source of contamination of local waters. The release of top secret data enabled us to gain knowledge about serious problems related to high radioactivity of groundwaters, which should spread uncontrollably through a system of secondary fissures activated by nuclear blasts. Another serious problem in this region is the quantitative aspect of contamination. Model simulations of water balance indicate that large industrial development in the spring area in China and continuously increasing water consumption in Kazakhstan may lead to desiccation of the lower stretch of this large river in Siberia during the summer months of 2030.     

Alteration, evaluation and use of extremaduran granite residues

The necessity of eliminating debris from a granite quarry has awakened an interest in applications of by-products, called “marginal arids”, in different fields, like construction and foundations for roadways, restoration, material for the manufacture of artificial rocks, and artesian products etc. Conclusions obtained from the results of tests carried out by X-ray diffraction of granite quarry by-products in Extremadura, Spain, submitted to different treatments, are established. Test pieces from two quarries are analyzed and compared generally and specifically, for commercial use. Finally, conclusions relating to essays in test pieces and mineral dynamics of marginal arid granite are exposed.     

The vulnerability of karst springs—a case study of the Hubelj spring (SW Slovenia)

The hydraulic behaviour of the karst aquifer in the Hubelj spring catchment area (SW Slovenia) was studied by using an indirect research method based on natural tracers. The variations of natural tracers (in precipitation and in groundwater) during the storm event made possible the separation of the Hubelj spring storm hydrograph by the three-component separation technique. The results produced information on the aquifer recharge, storage and discharge processes, as well as on the mechanisms that affected them. They verified the so-called epikarst hypothesis presuming that an important part of a karst aquifer recharge reaches rapidly and intensively from the epikarst zone. It was demonstrated that epikarst water could occupy up to 50% of the spring discharge during precipitation events. This phenomenon could have important consequences on protection and management of the problems of karst aquifers, including engineering problems in karst areas. With this respect the results could give way to new engineering ideas.     

P–T evolution and reaction textures in retrogressed eclogites from Svetlik, the Moldanubian Zone (Czech Republic)

Summary Lenses and pods of mafic rocks from the Monotonous Unit near Svetlik are characterized by eclogite facies mineral assemblages; however some inclusion patterns (oriented quartz rods in clinopyroxene and cuboids of disordered graphite in garnet) that are usually known from ultra-high pressure rocks were also observed in one sample. Conventional thermobarometry yielded maximum P–T conditions of 2.0–2.5 GPa and 750 °C. Decompression and heating at amphibolite and granulite facies conditions resulted in the formation of at least five distinct types of symplectites. These include symplectitic intergrowth of ilmenite and clinopyroxene after titanite, described here for the first time from the Moldanubian Zone. In addition, symplectites of plagioclase and biotite with accessory amounts of spinel after tabular pseudomorphs (after phengite?) are also reported here. Mass balance relations indicate that symplectites of diopside + plagioclase after omphacite and plagioclase + spinel (sapphirine) after kyanite + garnet, formed by nearly isochemical reactions. All other symplectite-forming reactions were allochemical and were accelerated by the presence of fluid in the primary phases. Preserved zoning pattern in garnet with high compositional gradient in some samples suggests that the rocks were affected briefly by granulite facies overprint.     

Reconstructing hydrological variability from testate amoebae analysis in Carpathian peatlands

Peatlands offer the potential for high resolution records of water balance over Holocene timescales, yet this potential is under-exploited in many areas of the world. Within Europe, peatlands are mostly confined to areas north of 55° N, but several areas of southern and eastern Europe contain small peatlands which may be suitable for palaeoclimatic reconstruction. In this paper we test the potential of peatlands in the Carpathian region for deriving quantified estimates of water table changes using testate amoebae analysis. A training set for palaeohydrological reconstruction from testate amoebae assemblages was obtained by collecting surface samples from 13 peatlands, including 9 from Hungary and 4 from Transylvania (Romania). Using a simple measure of mean annual water tables estimated from staining of PVC tape, we found that some peatlands were heavily influenced by runoff and groundwater, and were therefore not suitable as modern analogues of ombrotrophic climatically sensitive sites. The relationship between the testate amoebae assemblages in the modern samples and the environmental variables was explored using CCA. The CCA biplot showed that the most important variables are depth to water table and moisture content, confirming that hydrology is a key control on taxon distribution. pH was a secondary gradient. A transfer function for % moisture and depth to water table was established and applied to fossil assemblages from a sequence from Fenyves-tető, Transylvania, Romania. The reconstructed water table shows a number of variations which have parallels with other palaeoclimatic records from Europe and the North Atlantic prominent phases of higher water tables are associated with the periods 8000–8300 cal BP, 3000–2500 cal BP and after 600 cal BP. We suggest that these were periods of particular intensification of westerly airflow which affected eastern Europe as well as western and central Europe.     

Results from a Multi-disciplinary Sedimentary Pilot Study of Tectonic Lake Iznik (NW Turkey) – Geochemistry and Paleolimnology of the Recent Past

A limnogeological reconnaissance study was carried out on Lake Iznik, located in the southeast of the Marmara region of Turkey, involving a seismic survey and collection of short sediment cores. This lake is located on the middle branch of the North Anatolian Fault Zone (NAFZ), a transform plate boundary between the Eurasian and Anatolian Plates. It is, therefore, tectonically active and offers an opportunity to investigate the interplay of sedimentary and seismo-tectonic processes, as well as climate change and human impact in the region. Short cores of the three sub-basins, maximum length of 35.5 cm, recovered non-laminated, blackish clays and silts with varying amounts of biogenic and minerogenic (allochthonous, autochthonous) material, which documented almost the last 80 years of deposition and environmental history. High sedimentation rates in the deeper core sections are accompanied by changes in land use (conversion of woodland to farmland) in the northern areas of Lake Iznik, which caused the deposition of more weathered material (high K/Na ratios) and higher contents of Mn in the lake. A tendency towards eutrophic conditions within the last 20 years is indicated by high nutrient content (N, TOC, P), decreasing C/N-ratios, and characteristic diatom and cladoceran associations. Also increased pollution is revealed by higher Pb, Cu, and Zn contents and increased supply of human and animal faeces (high coprostanol content) during the last two decades. But simultaneous lower sedimentation rates towards the core tops complicate the reconstruction of recent and past eutrophication and pollution states of Lake Iznik. This requires an extension of the pilot study and deeper sediment cores, to recover non-anthropogenic influenced sediment levels.     

The effect of thermal treatment on the 57Fe Mössbauer spectrum of beryl

Mössbauer spectra (MS) of blue, green and yellow beryl (ideally Be₃Al₂Si₆O₁₈) containing approximately 1% of iron were obtained at 295 and 500 K. Room temperature (RT) spectra of both blue and green samples showed the presence of an asymmetric Fe²⁺ doublet (ΔE _Q~2.7 mm/s, δ~1.1 mm/s), with a very broad low-velocity peak. There is no clear evidence for the presence of a ferric component. The MS of the yellow sample at RT consists of an intense central absorption with parameters typical for Fe³⁺ (ΔE _Q~0.4 mm/s, δ~0.29 mm/s), plus an apparently symmetrical Fe²⁺ doublet. This sample acquires a light-blue shade upon heating in air at about 620 K. Thermal treatments at high temperatures caused no significant changes in the MS, but the green and yellow beryl acquire a blue colour. All these results are interpreted in relation to the existence of channel water and the distribution of iron among the available crystallographic sites.