Comparison of continuous and discontinuous constitutive models to simulate concrete behaviour under mixed‐mode failure conditions

The paper presents detailed FE simulation results of concrete elements under mixed‐mode failure conditions according to the so‐called shear‐tension test by Nooru‐Mohamed, characterized by curved cracks. A continuous and discontinuous numerical two‐dimensional approach was used. In order to describe the concrete's behaviour within continuum mechanics, two different constitutive models were used. First, an elasto‐plastic model with isotropic hardening and softening was assumed. In a compression regime, a Drucker–Prager criterion with a non‐associated flow rule was used. In turn, in a tensile regime, a Rankine criterion with an associated flow rule was adopted. Second, an isotropic damage constitutive model was applied with a single scalar damage parameter and different definitions of the equivalent strain. Both constitutive laws were enriched by a characteristic length of micro‐structure to capture properly strain localization. As an alternative approach, the extended finite element method was used. Our results were compared with the experimental ones and with results of other FE simulations reported in the literature. Copyright © 2015 John Wiley & Sons, Ltd.     

Mercury mobility and bioavailability in soil from contaminated area

The mobility and bioavailability of mercury in the soil from the area near a plant using elemental mercury for manufacturing thermometers, areometers, glass energy switches and other articles made of technical glass has been evaluated. Mercury has been determined by sequential extraction method and with additional thermo desorption stage to determine elemental mercury. The procedure of sequential extraction involves five subsequent stages performed with the solutions of chloroform, deionized water, 0.5 M HCl, 0.2 M NaOH and aqua regia. The mean concentration of total mercury in soil was 147 ± 107 μg g⁻¹ dry mass (range 62–393), and the fractionation revealed that mercury was mainly bound to sulfides 56 ± 8% (range 45–66), one of the most biounavailable and immobile species of mercury in the environment. The fractions that brought lower contribution to the total mercury content were semi-mobile humic matter 22 ± 9% (range 11–34) and elemental mercury 17 ± 5% (range 8–23). The contributions brought by the highly mobile and toxic organomercury compounds were still lower 2.3 ± 2.7% (range 0.01–6.5). The lowest contributions brought the acid-soluble mercury 1.5 ± 1.3% (range 0.1–3.5) and water-soluble mercury 1.0 ± 0.3% (range 0.6–1.7). The surface layer of soil (0–20 cm) was characterized by higher mercury concentrations than that of the subsurface soil (60–80 cm), but the fractional contributions were comparable. The comparison of mercury fractionation results obtained in this study for highly polluted soils with results of fractionation of uncontaminated or moderately contaminated samples of soil and sediments had not shown significant statistical differences; however, in the last samples elemental mercury is usually present at very low concentrations. On the basis of obtained correlation coefficients it seems that elemental mercury soils from “Areometer” plant are contaminated; the main transformation is its vaporization to atmosphere and oxidation to divalent mercury, probably mainly mediated by organic matter, and next bound to humic matter and sulfides.     

The assessment of environmental pollution caused by mining and metallurgy wastes from highly polluted post-industrial regions in Southern Poland

Stored metallurgy and mining wastes contain relatively high amounts of potentially toxic elements. To monitor the distribution of contaminants originating from dumps, the chemical and physical properties of the wastes must be characterised. In this study, the chemical properties of wastes deposited in two different locations in Southern Poland (Szklary and Zloty Stok) were evaluated. Heaps located in Zloty Stok contain wastes from gold mineralisation comprising arsenic while wastes in Szklary originate from a factory that produced an iron-nickel alloy. In Szklary the total concentrations of Ca, Mg, Fe, Zn, Mn, Cr, Co, Cu, Ni, Tl, Ag, Cd and Pb were determined, while in Zloty Stok also As is an important contaminant. To assess the risk of contamination of the surrounding environment and to select the proper method for removing the contaminants, information on the distribution of elements between operationally defined phases must be obtained. For this purpose, a six-step sequential extraction was used. The mobility of most elements in the wastes from Szklary and Zloty Stok was relatively low; however, the large amount of As, 40–180 mg L^?1, that could be released to environment in case of Zloty Stok was high. The results of fractionation studies indicated that Ag, Cd, Tl, Co, Cu, Cr, Pb, Zn and Mn may be released into environment under low pH and low redox potential conditions, which can be induced by bacterial activity.     

Investigation of X-Ray Flares with Long Rising Phases

We have used Yohkoh and GOES X-ray observations to investigate flares with a long rising phase. We have found that a characteristic feature of such flares is a long time interval, Δ t ≥ 20 min, between the temperature maximum and the maximum of the emission measure. We have carried out detailed analysis for 10 limb flares of this type. Time variation of the heating function, E_H(t), has been determined for their loop-top X-ray kernels. The time variation of E_H(t), together with the temperature–density diagnostic diagrams, have been used to explain the large value of the time interval, Δ t. The main point is that for these flares the heating function E_H(t) decreases so slowly after the temperature maximum, that for the long time, Δ t, the energy flux reaching flare foot points is sufficient to maintain significant chromospheric evaporation. Investigation of the flare evolution in the temperature–density diagnostic diagrams allowed us to work out a new method of determination of the density for flare kernels. This method can be applied to all the kernels for which their altitudes can be estimated. The advantage of this method is that for the density determination it is not necessary to assume what is the extension of the emitting plasma along the line of sight.     

Effects of heated water discharge on the evaporation from a river surface

The investigations concerned the effects of thermal waters on the river evaporation process and the development of formulae, based on standard hydrological and meteorological data, for determination of evaporation from the Vistula river.     

Ionic surfactants adsorption on heterogeneous surfacesAdsorption de tensioactifs ioniques sur les surfaces hétérogènes

The adsorption of surfactants from aqueous solution is a phenomenon of major importance in applications ranging from ore flotation and paint technology to enhanced oil recovery. As this paper will illustrate, the process is very complex and of high scientific interest; its results can be extended to the retention of organic compounds (humic and fulvic acids, pollutants...) on solids in the biosphere. For a good understanding of the mechanisms involved in surfactants adsorption at the hydrophilic solid–aqueous solution interface, thermodynamic models have to take into account: (i) the physical chemistry of the surfactant in aqueous solution for choosing the appropriate reference phase, (ii) the surface heterogeneity of the adsorbing solid, (iii) the intensity of normal adsorbate–adsorbent bonds responsible for adsorption, (iv) the intensity of lateral bonds that favour the formation of surface aggregates through cooperative process and finally, (v) suitable theoretical models to describe adsorption phenomena. Once this has been achieved, two systems can be discussed: systems characterised by strong normal adsorbate–adsorbent bonds, currently used in ore flotation, which lead, in the case of heterogeneous surfaces, to the formation of lamellar aggregates at monolayer concentration and bilayer formation for higher concentrations. Systems characterised by weak normal adsorbate–adsorbent bonds, currently used in enhanced oil recovery and hydrocarbon (bio)remediation, which correspond to: (i) formation of globular micelles at the solid surface near the CMC when the temperature is higher than the Krafft point, (ii) formation of bilayered lamellar aggregates in the opposite case, (iii) three-dimensional condensation on substrate (T<T_Krafft) if the ionic surfactant interacts with cations in the bulk. To cite this article: J.-M. Cases et al., C. R. Geoscience 334 (2002) 675–688.     

Acoustic emission and sorptive deformation induced in coals of various rank by the sorption-desorption of gas

Simultaneous measurements of acoustic emission (AE) and expansion/contraction of coal samples subjected to gas sorption-desorption processes were conducted on high-and medium-rank coal. The aim of this study was to examine the influence of the coal rank and type of sorbate on measured AE and strain characteristics. The experimental equipment employed in this study consisted of a pressure vessel and associated pressurisation and monitoring units. The arrangement of pressure-vacuum valves permitted the coal sample to be pressurised and depressurised. Carbon-dioxide and methane were used as sorbats.     

Seismic doublets and multiplets at Polish coal and copper mines

The following criteria for selection of doublets at Polish coal mines were accepted: the difference in magnitude (based on seismic moment) of two events not larger than 0.15, the distance between their hypocenters not greater than 150 m, and the time interval between their occurrence not longer than 10 days. Similarly, the criteria for seismic events at copper mines are: the difference in magnitude not exceeding 0.15, the distance not greater than 200 m, and the time interval not longer than 20 days. Seismic events from the Wujek and Ziemowit coal mines that occurred between 1993 and 1995, and seismic events from the Polkowice copper mine that occurred between 1994 and 1996 and from the Rudna copper mine that occurred between 1994 and 2004 were considered. Their source parameters and focal mechanisms were known in most cases from previous studies. Altogether 108 seismic pairs from coal mines and 118 pairs from copper mines were found, forming doublets, triplets and quadruplets, within the magnitude range from 0.7 to 3.5. The distance and time intervals between two events forming pairs are not dependent on magnitude of these events. The focal mechanism of seismic events forming pairs is similar in over 60 percent of pairs at coal mines and in about one third of pairs at copper mines. Spatial distributions of doublets in particular sections of coal and copper mines display dominant linear trends, characteristic for a given area, which are often in conformity with the direction of nodal planes determined by fault plane solution of one or both the events forming a doublet. In such cases, the rupture plane can be discriminated among the nodal planes.     

Induction vector estimates in the Polish-Czechoslovak part of the Carpathians

u¶rt;um ¶rt;a ma ua m u¶rt;uu n mam amu n aum auau ¶rt;a a n -a am anam.