Hydrochemical processes in ground water-discharge playas,Central Australia

A large groundwater system in the Amadeus Basin, central Australia, discharges to a chain of playa lakes 500 km long. The playas contain highly concentrated brines; these are sodium-chloride rich waters with appreciable magnesium and sulphate and very low concentrations of calcium and bicarbonate. Gypsum, glauberite, and other evaporite minerals are precipitating in the playas. The groundwaters evolve to brine by concurrent processes of dissolution, evaporative concentration, mineral precipitation, and mineralogical change. Chemical evolution is considered with reference to a concentration factor based on chloride. Ion transfer calculations demonstrate losses of magnesium and bicarbonate throughout, as a result of precipitation. Sodium, potassium, calcium, and sulphate are gained initially as a result of dissolution but lost subsequently as a result of precipitation. Larger playas in the chain, exemplified by Lake Amadeus, have dual shallow and deep groundwater flow paths whereas the smaller playas, exemplified by Spring Lake, have only shallow flow paths. Brines in the larger playas are diluted by deep groundwaters and this is reflected in the degree of saturation attained with respect to particular minerals. Thus, saturation with respect to gypsum and glauberite is attained earlier in Spring Lake than in Lake Amadeus. Saturation with respect to halite is attained in Spring Lake but not in Lake Amadeus. Both playas are undersaturated with respect to hexahydrite and sylvite although these minerals occur in efflorescent crusts in Spring Lake.     

Saline groundwater seepage zones and their impact on soil and water resources in the Spicers Creek catchment,central west,New South Wales,Australia

Saline seepage zone development and hence dryland salinity is a major environmental problem which many arid to semiarid landscapes in Australia are experiencing. Due to the geological complexity of the regional aquifer system and the heterogeneous nature of the local groundwater system, each groundwater seepage zone in the Spicers Creek catchment, central west, New South Wales, Australia possesses different mechanisms which control its development. Saline seepage zones have formed adjacent to a fault zone, and two experimental sites were established through these groundwater discharge zones to understand geochemical processes which have led to the development of soil sodicity, gully erosion and the flushing of salts into the surface water systems. Seepage zone groundwaters contain a distinctive geochemical signature with elevated concentrations of Na, Cl, HCO₃, Ca, Sr, B, As and Li. The mixing of deep saline groundwaters together with ion exchange processes lead to a distinctive seepage zone groundwater chemistry being developed. Altering the landscape features within this rural groundwater system has developed water toxicity for crops, soil sodicity leading to land degradation, and waterlogging problems.     

Advances in discrete element modelling of underground excavations

The paper presents advances in the discrete element modelling of underground excavation processes extending modelling possibilities as well as increasing computational efficiency. Efficient numerical models have been obtained using techniques of parallel computing and coupling the discrete element method with finite element method. The discrete element algorithm has been applied to simulation of different excavation processes, using different tools, TBMs and roadheaders. Numerical examples of tunnelling process are included in the paper, showing results in the form of rock failure, damage in the material, cutting forces and tool wear. Efficiency of the code for solving large scale geomechanical problems is also shown.     

Ammonia Nitrogen at the Water–Sediment Interface in Puck Bay (Baltic Sea)

The magnitude of the exchange flux at the water–sediment interface was determined on the basis of the ammonia concentration gradient at the near-bottom water–interstitial interface and Fick's first law. It was established that in Puck Bay, ammonia almost always passes from the sediment to water. Ammonia flux varied from 5 to 1434 μmol NH₄-N m⁻² day⁻¹. In total,c. 138·2 tonneammonia year⁻¹pass from sediments of Internal Puck Bay to near-bottom water, the equivalent value for External Puck Bay being 686·9 tonne year⁻¹. In total, about 825 tonne ammonia year⁻¹passes from the sediment to near-bottom water of Puck Bay. In interstitial waters, ammonia occurred in concentrations varying over a wide range (3–1084 μmol NH₄-N dm⁻³).The basic factors affecting the magnitude of ammonia concentration in interstitial waters included: oxidation of organic matter, type of sediment, and inflow of fresh underground waters to the region examined.This paper involves preliminary studies only and constitutes a continuation of the studies on ionic macrocomponents and phosphorus in interstitial waters of Puck Bay undertaken previously.     

An exact numerical time integration of scalar equations for undamped structural systems

An exact numerical time integration of scalar equations for undamped structural systems is presented. Typical numerical examples are included to illustrate the use of the proposed procedure.