Lead orthophosphates—IV Formation and stability in the environment

Experimental and predicted thermochemical constants are used to assess the formation and stability of lead phosphates in soil and sedimentary environments. For the chemical conditions likely to be encountered in oxidizing environments, the stability fields of pyromorphites [Pb₅(PO₄)₃X, X = OH^?, Cl^?, Br^? and F^?] and plumbogummite [PbAl₃(PO₄)₂(OH)₅-H₂O] predominate strongly over those of the other secondary lead minerals. The theoretical phase relationships together with several field observations are used as the basis for suggesting that the interaction of lead and phosphorus (to form pyromorphites and plumbogummite in particular) is an important buffer mechanism controlling the migration and fixation of lead in the environment. Calculations using the concentrations of lead and phosphate ions in serum indicate that the solubility of lead phosphates may be the limiting factor with regard to lead ion concentration in human body. The removal of lead from wastewater by precipitation as lead chloropyromorphite is considered a spin-off of possible industrial interest.     

THE PALEOSEISMIC SURFACE RUPTURE AT SOUTH OF CENTRAL ALTYN TAGH FAULT AND ITS TECTONIC IMPLICATION

In this study, we described a 14km-long paleoearthquakes surface rupture across the salt flats of western Qaidam Basin, 10km south of the Xorkol segment of the central Altyn Tagh Fault, with satellite images interpretation and field investigation methods. The surface rupture strikes on average about N80°E sub-parallel to the main Altyn Tagh Fault, but is composed of several stepping segments with markedly different strike ranging from 68°N~87°E. The surface rupture is marked by pressure ridges, sub-fault strands, tension-gashes, pull-apart and faulted basins, likely caused by left-lateral strike-slip faulting. More than 30 pressure ridges can be distinguished with various rectangular, elliptical or elongated shapes. Most long axis of the ridges are oblique(90°N~140°E)to, but a few are nearly parallel to the surface rupture strike. The ridge sizes vary also, with heights from 1 to 15m, widths from several to 60m, and lengths from 10 to 100m. The overall size of these pressure ridges is similar to those found along the Altyn Tagh Fault, for instance, south of Pingding Shan or across Xorkol. Right-stepping 0.5~1m-deep gashes or sub-faults, with lengths from a few meters to several hundred meters, are distributed obliquely between ridges at an angle reaching 30°. The sub-faults are characterized with SE or NW facing 0.5~1m-high scarps. Several pull-apart and faulted basins are bounded by faults along the eastern part of the surface rupture. One large pull-apart basins are 6~7m deep and 400m wide. A faulted basin, 80m wide, 500m long and 3m deep, is bounded by 2 left-stepping left-lateral faults and 4 right-stepping normal faults. Two to three m-wide gashes are often seen on pressure ridges, and some ridges are left-laterally faulted and cut into several parts, probably owing to the occurrence of repetitive earthquakes. The OSL dating indicates that the most recent rupture might occur during Holocene.
Southwestwards the rupture trace disappears a few hundred meters north of a south dipping thrust scarp bounding uplifted and folded Plio-Quaternary sediments to the south. Thrust scarps can be followed southwestward for another 12km and suggest a connection with the south Pingding Shan Fault, a left-lateral splay of the main Altyn Tagh Fault. To the northeast the rupture trace progressively veers to the east and is seen cross-cutting the bajada south of Datonggou Nanshan and merging with active thrusts clearly outlined by south facing cumulative scarps across the fans. The geometry of this strike-slip fault trace and the clear young seismic geomorphology typifies the present and tectonically active link between left-lateral strike-slip faulting and thrusting along the eastern termination of the Altyn Tagh Fault, a process responsible for the growth of the Tibetan plateau at its northeastern margin. The discrete relation between thrusting and strike-slip faulting suggests discontinuous transfer of strain from strike-slip faulting to thrusting and thus stepwise northeastward slip-rate decrease along the Altyn Tagh Fault after each strike-slip/thrust junction.     

阿尔金断裂带对青藏高原北部生长、隆升的制约

大量的同位素年代学证据表明(古)阿尔金断裂带可能形成于三叠纪,后又经历了侏罗纪、白垩纪的强烈左旋走滑活动,自印度板块与欧亚大陆碰撞后阿尔金断裂再次活动。主要的走滑活动发生在:(1)245~220Ma;(2)180~140Ma;(3)120~100Ma;(4)90~80Ma;(5)60~45Ma;(6)渐新世至中新世;(7)上新世至更新世以及(8)全新世。沿阿尔金断裂带,伴随左旋走滑活动形成一系列的逆冲断裂和正断裂,反映走滑过程中伴随隆升作用的存在,并且形成自北向南包括祁连山、大雪山、党河南山、柴北缘山、祁漫塔格山和昆仑山,表明阿尔金断裂带制约着青藏高原北部的生长和隆升。阿尔金断裂带东、西两端的白垩纪和新生代火山活动是断裂走滑活动的响应。     

Oxygen isotope speedometry in granulite facies garnet recording fluid/melt–rock interaction (Sør Rondane Mountains,East Antarctica)

In situ analysis of a garnet porphyroblast from a granulite facies gneiss from Sør Rondane Mountains, East Antarctica, reveals discontinuous step‐wise zoning in phosphorus and large δ¹⁸O variations from the phosphorus‐rich core to the phosphorus‐poor rim. The gradually decreasing profile of oxygen isotope from the core (δ¹⁸O = ~15‰) to the rim (δ¹⁸O = ~11‰) suggests that the ¹⁸O/¹⁶O zoning was originally step‐wise, and modified by diffusion after the garnet rim formation at ~800°C and 0.8 GPa. Fitting of the ¹⁸O/¹⁶O data to the diffusion equation constrains a duration of the high‐T event (~800°C) to c. 0.5–40 Ma after the garnet rim formation. The low δ¹⁸O value of the garnet rim, together with the previously reported low δ¹⁸O values in metacarbonates, indicates regional infiltration, probably along a detachment fault, of low δ¹⁸O fluid/melt possibly derived from meta‐mafic to ultramafic rocks.     

Biotite Reference Materials for Secondary Ion Mass Spectrometry 18O/16O Measurements

Five new biotite reference materials were calibrated at the SwissSIMS laboratory (University of Lausanne) for oxygen isotope determination by secondary ion mass spectrometry (SIMS) and are available to the scientific community. The oxygen isotope composition of the biotites, UNIL_B1 to B5, was determined by laser‐heating fluorination to be 11.4 ± 0.11‰, 8.6 ± 0.15‰, 6.1 ± 0.04‰, 7.1 ± 0.05‰ and 7.6 ± 0.04‰, respectively. SIMS analyses on spots smaller than 20 μm gave a measurement repeatability of 0.3‰ (2 standard deviation, 2s). The matrix effect due to solid solution in natural biotite could be expressed as a linear function of X_Mg and X_F for biotite. No effect was found for different crystallographic orientations. SIMS analysis allows the oxygen isotope composition of biotite to be measured with a measurement uncertainty of 0.3–0.4‰ (2s) for biotites with similar major element compositions. A measurement uncertainty of 0.5‰ (2s) is realistic when F poor biotites (lower than 0.2% m/m oxides) within the compositional range of X_Mg of 0.3–0.9 were compared from different sessions. The linear correlation with F content offers a reasonable working curve for F‐rich biotites, but additional reference materials are needed to confirm the model.     

New Reference Materials and Assessment of Matrix Effects for SIMS Measurements of Oxygen Isotopes in Garnet

Accurate ion microprobe analysis of oxygen isotope ratios in garnet requires appropriate reference materials to correct for instrumental mass fractionation that partly depends on the garnet chemistry (matrix effect). The matrix effect correlated with grossular, spessartine and andradite components was characterised for the Cameca IMS 1280HR at the SwissSIMS laboratory based on sixteen reference garnet samples. The correlations fit a second‐degree polynomial with maximum bias of ca. 4‰, 2‰ and 8‰, respectively. While the grossular composition range 0–25% is adequately covered by available reference materials, there is a paucity of them for intermediate compositions. We characterise three new garnet reference materials GRS2, GRS‐JH2 and CAP02 with a grossular content of 88.3 ± 1.2% (2s), 83.3 ± 0.8% and 32.5 ± 3.0%, respectively. Their micro scale homogeneity in oxygen isotope composition was evaluated by multiple SIMS sessions. The reference δ¹⁸O value was determined by CO₂ laser fluorination (δ¹⁸O_LF). GRS2 has δ¹⁸O_LF = 8.01 ± 0.10‰ (2s) and repeatability within each SIMS session of 0.30–0.60‰ (2s), GRS‐JH2 has δ¹⁸O_LF = 18.70 ± 0.08‰ and repeatability of 0.24–0.42‰ and CAP02 has δ¹⁸O_LF = 4.64 ± 0.16‰ and repeatability of 0.40–0.46‰.