Lake Floor Morphology and Sediment Architecture of Lake Torneträsk,Northern Sweden

Here we present datasets from a hydroacoustic survey in July 2011 at Lake Torneträsk, northern Sweden. Our hydroacoustic data exhibit lake floor morphologies formed by glacial erosion and accumulation processes, insights into lacustrine sediment accumulation since the beginning of deglaciation, and information on seismic activity along the Pärvie Fault. Features of glacial scouring with a high‐energy relief, steep slopes, and relative reliefs of more than 50 m are observed in the large W‐basin. The remainder of the lacustrine subsurface appears to host a broad variety of well preserved formations from glacial accumulation related to the last retreat of the Fennoscandian ice sheet. Deposition of glaciolacustrine and lacustrine sediments is focused in areas situated in proximity to major inlets. Sediment accumulation in distal areas of the lake seldom exceeds 2 m or is not observable. We assume that lack of sediment deposition in the lake is a result of different factors, including low rates of erosion in the catchment, a previously high lake level leading to deposition of sediments in higher elevated paleodeltas, tributaries carrying low suspension loads as a result of sedimentation in upstream lakes, and an overall low productivity in the lake. A clear off‐shore trace of the Pärvie Fault could not be detected from our hydroacoustic data. However, an absence of sediment disturbance in close proximity to the presumed fault trace implies minimal seismic activity since deposition of the glaciolacustrine and lacustrine sediments.     

Colloidal Stability and Toxicity of Gold Nanoparticles and Gold Chloride on <Emphasis Type="Italic">Chlamydomonas reinhardtii</Emphasis>

Here we have examined interactions of gold nanoparticles differing in primary particle size and coating with the green algae Chlamydomonas reinhardtii as function of the colloidal stability of the particles in the experimental media used for toxicity studies. Interactions of dissolved Au³⁺ ions with algae were also examined. Included endpoints were photosynthetic yield and algal growth. Morphological and structural effects were examined microscopically and by flow cytometry. The results indicate no significant toxicity of gold nanoparticles to C. reinhardtii. Analysis of published data suggests toxicity of gold nanoparticles on algal growth to relate rather to particular coatings than to the gold core.     

Evaluation of the accuracy of the EIGEN-1S and -2 CHAMP-derived gravity field models by satellite crossover altimetry

Since the advent of CHAMP, the first in a series of low-altitude satellites being almost continuously and precisely tracked by GPS, a new generation of long-wavelength gravitational geopotential models can be derived. The accuracy evaluation of these models depends to a large extent on the comparison with external data of comparable quality. Here, two CHAMP-derived models, EIGEN-1S and EIGEN-2, are tested with independent long-term-averaged single satellite crossover (SSC) sea heights from three altimetric satellites (ERS-1, ERS-2 and Geosat). The analyses show that long-term averages of crossover residuals still are powerful data to test CHAMP gravity field models. The new models are tested in the spatial domain with the aid of ERS-1/-2 and Geosat SSCs, and in the spectral domain with latitude-lumped coefficient (LLC) corrections derived from the SSCs. The LLC corrections allow a representation of the satellite-orbit-specific error spectra per order of the models spherical harmonic coefficients. These observed LLC corrections are compared to the LLC projections from the models variance–covariance matrix. The excessively large LLC errors at order 2 found in the case of EIGEN-2 with the ERS data are discussed. The degree-dependent scaling factors for the variance-covariance matrices of EIGEN-1S and –2, applied to obtain more realistic error estimates of the solved-for coefficients, are compatible with the results found here.     

The history of water salinity in the Pearl River estuary,China, during the Late Quaternary

This research reconstructed the Late Quaternary salinity history of the Pearl River estuary, China, from diatom records of four sedimentary cores. The reconstruction was produced through the application of a diatom–salinity transfer function developed based on 77 modern surface sediment samples collected across the estuary from shallow marine environment to deltaic distributaries. The statistical analysis indicates that the majority of sediment samples from the cores has good modern analogues, thus the reconstructions are reliable. The reconstructed salinity history shows the older estuarine sequence formed during the last interglacial was deposited under similar salinity conditions to the younger estuarine sequence, which was formed during the present interglacial. Further analysis into the younger estuarine sequence reveals the interplays between sea level, monsoon‐driven freshwater discharge, and deltaic shoreline movement, key factors that have influenced water salinity in the estuary. In particular, a core from the delta plain shows the effects of sea‐level change and deltaic progradation, while cores from the mouth region of the estuary reveal changes of monsoon‐driven freshwater discharge. This study demonstrates the advantages of quantitative salinity reconstructions to improve the quality of reconstruction and allow direct comparison with other quantitative records and the instrumentally observed values of salinity. Copyright © 2010 John Wiley & Sons, Ltd.     

Late-Quaternary supply of terrigenous organic matter to the Congo deep-sea fan (ODP site 1075): implications for equatorial African paleoclimate

Late-Quaternary sections (about 1 Ma) from the Congo deep-sea fan (ODP Leg 175, site 1075) were used to reconstruct the terrigenous organic matter supply to the easternmost equatorial Atlantic Ocean. Variations in quantity and quality of the riverine organic matter reflect the interaction between the paleoclimatic development within the continental catchment area and the paleoceanographic conditions in the Congo river plume. To characterize the delivery of organic matter from terrigenous and marine sources, we used elemental and bulk carbon isotopic analyses, Rock-Eval pyrolysis, lignin chemistry, and organic petrology. High-amplitude fluctuations occurring about every 15-25 ka reveal a mainly precessional control on organic sedimentation. Results from Rock-Eval pyrolysis indicate a mixed kerogen type III/II, as would be anticipated in front of a major river. Fluctuations in T_max from Rock-Eval pyrolysis demonstrate pronounced cyclic changes in the delivery of low- and high-mature organic matter. Contribution of the low-mature organic fraction was strongest during warm climates supporting enhanced marine production offshore of the Congo. Organic petrological observations confirm the existence of abundant terrigenous plant tissues, both non-oxidized (vitrinite) and oxidized (inertinite). Charcoal-like organic matter (fusinite) is attributed to periods of increased bush fires in the continental hinterland, and implies more arid climatic conditions. Results from ratios of specific phenolic lignin components suggest that terrigenous organic matter in Late-Quaternary sections of site 1075 mainly derives from non-woody angiosperm tissue, i.e., grasses and leaves. Correlation between the amount of specific lignin phenols and the bulk '¹³C_org signature fosters the conclusion that an appreciable amount of the terrigenous organic fraction derives from C4 plant matter. This may cause an underestimation of the terrigenous proportion of bulk organic matter when assessments are based on bulk carbon isotopic signatures alone.     

Thermodynamic characterization of boltwoodite and uranophane: Enthalpy of formation and aqueous solubility

Boltwoodite and uranophane are uranyl silicates common in oxidized zones of uranium ore deposits. An understanding of processes that impact uranium transport in the environment, especially pertaining to the distribution of uranium between solid phases and aqueous solutions, ultimately requires determination of thermodynamic parameters for such crystalline materials. We measured formation enthalpies of synthetic boltwoodites, K(UO₂)(HSiO₄)·H₂O and Na(UO₂)(HSiO₄)·H₂O, and uranophane, Ca(UO₂)₂(HSiO₄)₂·5H₂O, by high temperature oxide melt solution calorimetry. We also studied the aqueous solubility of these phases from both saturated and undersaturated conditions at a variety of pH. The combined data permit the determination of standard enthalpies, entropies and Gibbs free energies of formation for each phase and analysis of its potential geological impact from a thermodynamic point of view.     

Cambridge deep Ocean geophone

We describe recent mechanical andeelectronic modifications to the Cambridge Ocean Bottom Hydrophone system, enabling it to record in addition three geophone channels from a deployed, disposable geophone package. Examples of data from seismic refraction experiments show good correspondence between records of ground motion detected by the hydrophone and the vertical geophone. Seismic signals are undistorted by noise from instrument related sources. Clear examples of P to S conversions just below the receiver are observed. Improved recording conditions are achieved by deploying the geophones in a small pressure vessel as far away as possible from the main instrument package.     

Adoption of the arctic search and rescue agreement: A shift of the arctic regime toward a hard law basis?

This paper examines the Arctic Search and Rescue Agreement—the first legally-binding instrument negotiated and adopted under the auspices of the Arctic Council—and analyzes its implications for the current Arctic regime. Led by the Arctic Council, the Arctic regime was established in a soft law format. However, the soft law nature and restricted mandates of the Arctic Council have limited its capacity to respond to new issues emerging from climate change, particularly those related to the exploitation of oil and gas reserves, commercial shipping through the region, effects on wildlife, and impacts on indigenous peoples' homelands and culture. The adoption of the Agreement represents a new approach for the Arctic States to respond to these new challenges. At the same time, it does not imply that a legally-binding instrument is necessarily preferable for every issue, and importantly, the new Arctic Agreement does not establish new institutional relationships, suggesting satisfaction among the Arctic States with the existing arrangements. Thus, although the Arctic regime is undoubtedly changing, this change should not be treated today as a shift from soft to hard law. What is more certain is that the Arctic Council will continue to function as a cooperative forum where the Arctic States can address these challenges, and its importance will only increase in coming years.     

Reconstructing tsunami run-up from the characteristics of tsunami deposits on the Thai Andaman Coast

Tsunamis can leave deposits on the land surface they inundate. The characteristics of tsunami deposits can be used to calculate tsunami run-up height and velocity. This paper presents a reconstruction of tsunami run-up from tsunami deposit characteristics in a simple mathematical model. The model is modified and applied to reconstruct tsunami run-ups at Ao Kheuy beach and Khuk Khak beach, Phangnga province, Thailand. The input parameters are grain-size and maximum run-up distance of the sediment. The reconstructed run-up heights are 4.16–4.91 m at Ao Kheuy beach and 5.43–9.46 m at Khuk Khak beach. The estimated run-up velocities (maximum velocity) at the still water level are 12.78–19.21 m/s. In the area located 70–140 m inland to the end of run-up inundation, estimated mean run-up velocities decrease from approximately 1.93 m/s to 0 m/s. Reasonably good agreements are found between reconstructed and observed run-up heights. The tsunami run-up height and velocity can be used for risk assessment and coastal development programs in the tsunami affected area. The results show that the area from 0 to 140 m inland was flooded by high velocity run-ups and those run-up energies were dissipated mainly in this area. The area should be designated as either an area where settlement is not permitted or an area where effective protection is provided, for example with flood barriers or forest.     

Carbon Sequestration and Release from Antarctic Lakes: Lake Vida and West Lake Bonney (McMurdo Dry Valleys)

Perennial ice covers on many Antarctic lakes have resulted in high lake inorganic carbon contents. The objective of this paper was to evaluate and compare the brine and CO₂ chemistries of Lake Vida (Victoria Valley) and West Lake Bonney (Taylor Valley), two lakes of the McMurdo Dry Valleys (East Antarctica), and their potential consequences during global warming. An existing geochemical model (FREZCHEM-15) was used to convert measured molarity into molality needed for the FREZCHEM model, and this model added a new algorithm that converts measured DIC into carbonate alkalinity needed for the FREZCHEM model. While quite extensive geochemical information exists for ice-covered Taylor Valley lakes, such as West Lake Bonney, only limited information exists for the recently sampled brine of >25 m ice-thick Lake Vida. Lake Vida brine had a model-calculated pCO₂ = 0.60 bars at the field pH (6.20); West Lake Bonney had a model-calculated pCO₂ = 5.23 bars at the field pH (5.46). Despite the high degree of atmospheric CO₂ supersaturation in West Lake Bonney, it remains significantly undersaturated with the gas hydrate, CO₂·6H₂O, unless these gas hydrates are deep in the sediment layer or are metastable having formed under colder temperatures or greater pressures. Because of lower temperatures, Lake Vida could start forming CO₂·6H₂O at lower pCO₂ values than West Lake Bonney; but both lakes are significantly undersaturated with the gas hydrate, CO₂·6H₂O. For both lakes, simulation of global warming from current subzero temperatures (?13.4 °C in Lake Vida and ?4.7 °C in West Lake Bonney) to 10 °C has shown that a major loss of solution-phase carbon as CO₂ gases and carbonate minerals occurred when the temperatures rose above 0 °C and perennial ice covers would disappear. How important these Antarctic CO₂ sources will be for future global warming remains to be seen. But a recent paper has shown that methane increased in atmospheric concentration due to deglaciation about 10,000 years ago. So, CO₂ release from ice lakes might contribute to atmospheric gases in the future.