Palaeovariations in the East-Asian Monsoon Regime Geochemically Recorded in Varved Sediments of Lake Sihailongwan (Northeast China, Jilin Province). Part 2: a 200-Year Record of Atmospheric Lead-210 Flux Variations and its Palaeoclimatic Implications

Palaeovariations of the atmospheric ²¹⁰Pb flux in Northeast China (Long Gang area, Jilin province), quantified by high resolution ²¹⁰Pb measurements on seasonally laminated sediments of Lake Sihailongwan are presented on decadal scale. The mean flux of unsupported ²¹⁰Pb between 1790 and 1970 for the centre of the lake basin is 517 Bq m⁻² yr⁻¹ with maximum deviations between −23% and +27% of this value. Flux rates above this average were found between 1783 and 1813, around 1836, and between 1860 and 1901. The mean ²¹⁰Pb^exc flux rates derived were clearly lower around 1821, 1908, 1930, and 1953. The ²¹⁰Pb^exc flux reached its minimum of 344 Bq m⁻² yr⁻¹ during the period 1977–1982. The atmospheric flux of unsupported ²¹⁰Pb is correlated with the precipitation frequency during the summer monsoon and shows coinciding variability with geochemical proxies that document the groundwater inflow into the lake. Al₂O₃-rich dust of remote provenance scavenged by wet-deposition in the rainy season is the major carrier of the atmospheric ²¹⁰Pb^exc flux.     

Impact angle influence in high velocity dust collisions during planetesimal formation

We have examined the influence of impact angle in collisions between small dust aggregates and larger dust targets through laboratory experiments. Targets consisted of μm-sized quartz dust and had a porosity of about 67%; the projectiles, between 1 and 5 mm in diameter, were slightly more compact (64% porosity). The collision velocity was centered at 20 m/s and impact angles range from 0° to 45°. At a given impact angle, the target gained mass for projectiles smaller than a threshold size, which decreases with increasing angle from about 3 mm to 1 mm. The fact that growth is possible up to the largest angles studied supports the idea of planetesimal formation by sweep-up of small dust aggregates.     

Bioassessment Techniques for Monitoring of Eutrophication and Nutrient Limitation in Coastal Ecosystems

Bioassesment by the use of the macroalga, Ulva lactuca L., was carried out in the Limfjord, Denmark, to assess the significance of nitrogen and phosphorus as limiting factors for primary production during 1985, 1993, 1994 and 1995 and for the detection of changes in eutrophication levels.

Minimum and critical tissue concentrations for nitrogen and phosphorus in macroalgae were identified. The concentrations of nitrogen were generally below the critical concentration level in June–October in 1985, 1993, and 1995 but in 1994 nitrogen was only limiting for primary production in short periods. Only in early spring in 1985 and 1993 were the tissue concentrations of phosphorus below the critical concentration level, whereas in 1994 up to 3–4 months showed phosphorus limited growth, indicating that significant changes in limitation patterns can occur between different years.

It was concluded that the use of biomonitoring techniques is well suited as a bioassessment method for direct detection and for providing a time-integrated measure of nutrient availability in coastal waters, and thus for assessing ecosystem health with regard to eutrophication. It is recommended that biomonitors and the concept of critical tissue concentrations should be used in environmental management and incorporated in future monitoring programmes.     

Wind-driven diversion of summer river runoff preconditions the Laptev Sea coastal polynya hydrography: Evidence from summer-to-winter hydrographic records of 2007–2009

This paper examines the role of atmospheric forcing in modifying the pathways of riverine water on the Laptev Sea shelf, using summer-to-winter hydrographic surveys from 2007 to 2009. Over the two consecutive winter seasons of 2007–2008 and 2008–2009 in the area of the winter coastal polynya, our data clearly link winter surface salinity fields to the previous summer conditions, with substantially different winter salinity patterns preconditioned by summer atmospheric forcing. In the summer of 2007, dominant along-shore westerly winds in the cyclonic regime force the Lena River runoff to flow eastward. In contrast, in the summer of 2008, dominant along-shore easterly winds over the East Siberian Sea and on-shore northerly winds over the Laptev Sea in the anticyclonic regime lock the riverine water in the vicinity of the Lena Delta. Over the coastal polynya area in the southeastern Laptev Sea these patterns precondition a surface salinity difference of 8–16 psu between the winters of 2008 and 2009. Overall, this indicates a residence time of at least half a year for riverine water on the Laptev Sea shelf. Future climate change associated with an enhanced summer cyclonicity over the eastern Arctic may turn more riverine water eastward along the eastern Siberian coast, resulting in weaker vertical density stratification over the Laptev Sea shelf, with possible impact on the efficiency of vertical mixing and polynya dense water production.     

Feeding Monsters – A Study of Active Galaxies

We present new interferometric observations of the molecular gas distribution and kinematics in the nuclei of different active galaxies at high angular resolution and high sensitivity carried out with the IRAM Plateau de Bure interferometer (PdBI). The observations cover galaxies in a redshift range of 0.03–1.4. We have so far observed five different active galaxies: NGC3718, NGC1068, HE1029–1831, 3C48 and Q0957+561. The first two objects belong to the NUGA (NUclei of GAlaxies) project – an international collaboration mainly between Spain, France and Germany – containing about 30 Seyfert and LINER galaxies. Both are at the same distance of 14Mpc and show a warped gas and dust disk. The new mosaic map of NGC3718 corrected for short-spacing effects with IRAM 30 m observations well demonstrates the existence of the warped gas disk with several secondary maxima in the projected gas distribution caused by orbit crowding effects. Based on these new data we have improved recent simulations of the warped disk in NGC3718. HE1029–1831 and 3C48 are nearby QSOs. HE1029–1831 is taken out of the Cologne nearby QSO sample. The maps of the integrated CO(1–0) and CO(2–1) emission clearly show that the molecular gas is mostly related to the central bulge with a non-negligible fraction distributed along the bar known from optical observations. Our new CO data of 3C48 unveil new information about the kinematics of its molecular gas complementing and improving further studies based on previous infrared observations and detailed multi-particle simulations. Finally, new measurements of the CO(1–0) line in Q0957+561 – a highly-red-shifted, gravitationally lensed quasar – will be presented as a link to earlier evolutionary stages of active galaxies and their hosts.     

Fluid geochemistry in the Ivigtut cryolite deposit, South Greenland

The 1.27 Ga old Ivigtut (Ivittuut) intrusion in South Greenland is world-famous for its hydrothermal cryolite deposit [Na₃AlF₆] situated within a strongly metasomatised A-type granite stock. This detailed fluid inclusion study characterises the fluid present during the formation of the cryolite deposit and thermodynamic modelling allows to constrain its formation conditions.Microthermometry revealed three different types of inclusions: (1) pure CO₂, (2) aqueous-carbonic and (3) saline-aqueous inclusions. Melting temperatures range between − 23 and − 15 °C for type 2 and from − 15 to − 10 °C for type 3 inclusions. Most inclusions homogenise between 110 and 150 °C into the liquid.Stable isotope compositions of CO₂ and H₂O were measured from crushed inclusions in quartz, cryolite, fluorite and siderite. The δ¹³C values of about − 5‰ PDB are typical of mantle-derived magmas. The differences between δ¹⁸O of CO₂ (+ 21 to + 42‰ VSMOW) and δ¹⁸O of H₂O (− 1 to − 21.7‰ VSMOW) suggest low-temperature isotope exchange. δD (H₂O) ranges from − 19 to − 144‰ VSMOW. The isotopic composition of inclusion water closely follows the meteoric water line and is comparable to Canadian Shield brines. Ion chromatography revealed the fluid's predominance in Na, Cl and F. Cl/Br ratios range between 56 and 110 and may imply intensive fluid–rock interaction with the host granite.Isochores deduced from microthermometry in conjunction with estimates for the solidification of the Ivigtut granite suggest a formation pressure of approximately 1–1.5 kbar for the fluid inclusions. Formation temperatures of different types of fluid inclusions vary between 100 and 400 °C. Thermodynamic modelling of phase assemblages and the extraordinary high concentration in F (and Na) may indicate that the cryolite body and its associated fluid inclusions could have formed during the continuous transition from a volatile-rich melt to a solute-rich fluid.     

Zircon M257 ‐ a Homogeneous Natural Reference Material for the Ion Microprobe U‐Pb Analysis of Zircon

We introduce and propose zircon M257 as a future reference material for the determination of zircon U‐Pb ages by means of secondary ion mass spectrometry. This light brownish, flawless, cut gemstone specimen from Sri Lanka weighed 5.14 g (25.7 carats). Zircon M257 has TIMS‐determined, mean isotopic ratios (2s uncertainties) of 0.09100 ± 0.00003 for ²⁰⁶pb/²³⁸U and 0.7392 ± 0.0003 for ²⁰⁷pb/²³⁵U. Its ²⁰⁶pb/²³⁸U age is 561.3 ± 0.3 Ma (unweighted mean, uncertainty quoted at the 95% confidence level); the U‐Pb system is concordant within uncertainty of decay constants. Zircon M257 contains ～ 840 μg g^?1 U (Th/U ～ 0.27). The material exhibits remarkably low heterogeneity, with a virtual absence of any internal textures even in cathodoluminescence images. The uniform, moderate degree of radiation damage (estimated from the expansion of unit‐cell parameters, broadening of Raman spectral parameters and density) corresponds well, within the “Sri Lankan trends”, with actinide concentrations, U‐Pb age, and the calculated alpha fluence of 1.66 × 10¹⁸ g^?1. This, and a (U+Th)/He age of 419 ± 9 Ma (2s), enables us to exclude any unusual thermal history or heat treatment, which could potentially have affected the retention of radiogenic Pb. The oxygen isotope ratio of this zircon is 13.9%o VSMOW suggesting a metamorphic genesis in a marble or calc‐silicate skarn.     

Importance of geological information for assessing drain flow in a Danish till landscape

There has, in recent years, been an increasing interest in developing nutrient load mitigation measures focussing on tile drains. To plan the location of such tile drain measures, it is important to know where in the landscape drain flow is generated and to understand the key factors governing drain flow dynamics. In the present study, we test two approaches to assess spatial patterns in drain flow generation and thereby assess the importance of including geological information. The approaches are the widely used topographical wetness index (TWI), based solely on elevation data, and hydrological models that include the subsurface geology. We set‐up an ensemble of 20 hydrological models based on 20 stochastically generated geological models to predict drain flow dynamics in the clay till Norsminde catchment in Denmark and test the results against TWI. We find that the hydrological models predict observed daily drain flow reasonably well. High drain flow volumes were found in stream valleys and in wetlands and lower drain flow volumes in the more hilly parts of the catchment. In spite of the apparent connection to the landscape, there was no statistically significant correlation between TWI and drain flow at grid scale (100 × 100 m). TWI was therefore not found to be a sufficient index on its own to assess where drain flow is generated, especially in the highlands of the catchment. The geology below 3 m was found to have a large impact on the drain flow, and correlations between sand percentage in the subsurface geology and drain flow volume were found to be statistically significant. Geological uncertainty therefore give rise to uncertainty on simulated drain flow, and this uncertainty was found to be high at the model grid scale but decreasing with increasing scale.     

Catchment chemostasis revisited: Water quality responds differently to variations in weather and climate

Solute concentrations in streamflow typically vary systematically with stream discharge, and the resulting concentration–discharge relationships are important signatures of catchment biogeochemical processes. Solutes derived from mineral weathering often exhibit decreasing concentrations with increasing flows, suggesting dilution of a kinetically limited weathering flux by a variable flux of water. However, previous work showed that concentration–discharge relationships of weathering‐derived solutes in 59 headwater catchments were much weaker than this simple dilution model would predict. Instead, catchments behaved as chemostats, with rates of solute production and/or mobilization that were nearly proportional to water fluxes, on both event and interannual timescales. Here, we re‐examine these findings using data for a wider range of solutes from 2,186 catchments, ranging from ~10 to >1,000,000 km² in drainage area and spanning a wide range of lithologic and climatic settings. Concentration–discharge relationships among this much larger set of larger catchments are broadly consistent with the previously described chemostatic behaviour, at least on event and interannual timescales for weathering‐derived solutes. Among these same catchments, however, site‐to‐site variations in mean concentrations of weathering‐derived solutes exhibit strong negative correlations with long‐term average precipitation and discharge, reflecting strong climatic control on long‐term leaching of the critical zone. We use multiple regression of site characteristics including discharge to identify potential controls on long‐term mean concentrations and find that lithologic and land cover controls are significant predictors for many analytes. The picture that emerges is one in which, on event and interannual timescales, weathering‐derived stream solute concentrations are chemostatically buffered by groundwater storage and fast chemical reactions, but each catchment's chemostatic “set point” reflects site‐to‐site differences in climatically driven evolution of the critical zone. In contrast to these weathering products, some nutrients and particulates are often near‐chemostatic across all timescales, and their long‐term mean concentrations correlate more strongly with land use than climatic characteristics.