电离层GPS掩星观测改正TEC反演方法

电离层掩星观测中,当低轨卫星（LEO）轨道高度较低时,轨道以上的电离层电子总含量（TEC）对掩星反演的影响不能忽略.目前,一般采用指数函数等外推方法来处理该问题,对反演结果可能引起较大误差.为提高电离层掩星反演精度,本文研究利用LEO处于非掩星一侧GPS观测数据的改正TEC新反演方法.用三维射线追踪程序计算出电离层掩星观测模拟数据,分别应用改正TEC方法和外推方法进行反演,将反演结果与所用模式值进行比较.结果表明：对于轨道高度约800km的GPS/MET掩星模拟数据,外推方法和改正TEC方法反演结果都与模式值基本一致;对于轨道高度约400km的CHAMP掩星模拟数据,外推方法误差较大,改正TEC方法反演结果与模式值相符得较好.将改正TEC方法应用于GPS/MET实测数据的反演,取得了合理的结果.这些说明,改正TEC算法是一种有效的电离层掩星反演方法,尤其是对于轨道较低的LEO的电离层掩星观测反演特别有用.     

Bedload transport measurements at the Erlenbach stream with geophones and automated basket samplers

In the Erlenbach stream, a pre‐alpine steep channel in Switzerland, sediment transport has been monitored for more than 25 years. Near the confluence with the main valley river, stream flow is monitored and sediment is collected in a retention basin with a capacity of about 2000 m³. The basin is surveyed at regular intervals and after large flood events. In addition, sediment transport has been continuously monitored with piezoelectric bedload impact and geophone sensors since 1986. In 2008–2009, the measuring system in the Erlenbach stream was enhanced by installing an automatic system to obtain bedload samples. Movable metal baskets are mounted on a rail at the downstream wall of the large check dam above the retention basin, and they can be moved automatically into the flow to take bedload transport samples. The wire mesh of the baskets has a spacing of 10 mm to sample all sediment particles coarser than this size (which is about the limiting grain size detected by the geophones). The upgraded measuring system permits to obtain bedload samples over short sampling periods and to measure the grain size distribution of the transported material and its variation over time and with discharge. The analysis of calibration relationships for the geophone measuring system confirms findings from very similar measurements which were performed until 1999 with piezoelectric bedload impact sensors; there is a linear relationship between impulse counts and bedload mass passing over the sensors. Findings from flume experiments are used to discuss the most important factors which affect the calibration of the geophone signal. The bedload transport rates as measured by the moving baskets are among the highest measured in natural streams, with values of the order of several kilograms per meter per second. Copyright © 2012 John Wiley & Sons, Ltd.     

Disturbance regimes at the interface of geomorphology and ecology

Geomorphological processes are an integral part of ecosystem functioning and ecosystem functioning affects geomorphological processes. Increasingly widespread acknowledgement of this simple idea is manifest in a vigorous research community engaged with questions that address the two‐way interaction between biota and geomorphology, at a range of scales and in a variety of terrestrial and aquatic environments. Geomorphological disturbances are a core element of biogeomorphological interest, and although the disciplines of geomorphology and ecology have each developed languages and theories that help to explore, model and understand disturbance events, little attempt has been made to draw together these approaches. Following a brief review of these issues, we introduce thirteen papers that investigate the interactions and feedbacks between geomorphological disturbance regimes and ecosystem functions. These papers reveal the singularity of wildfire impacts, the importance of landsliding for carbon budgeting and of vegetation accumulation for landsliding, the zoogeomorphic role of iconic and ‘Cinderella’ animals in fluvial geomorphology, biophysical interactions in aeolian, fluvial and torrential environments and the utility of living ecosystems as archives of geomorphic events. Most of these papers were first presented in a conference session at the European Geoscience Union General Assembly in 2010 and several others are from recent volumes of Earth Surface Processes and Landforms. Copyright © 2012 John Wiley & Sons, Ltd.     

The use of surface-enhanced Raman scattering (SERS) for detection of PAHs in the Gulf of Gdańsk (Baltic Sea)

A field operable surface enhanced Raman scattering (SERS) sensor system was applied for the first time under real conditions for the detection of polycyclic aromatic hydrocarbons (PAHs) as markers for petroleum hydrocarbons in the Gulf of Gdańsk (Baltic Sea). At six stations, seawater samples were taken, and the sensor system was applied in situ simultaneously. These measurements were compared to the results of conventional GC/MS laboratory analysis of the PAH concentrations in the seawater samples. For a PAH concentration above 150 ng(12PAH)l(-1), there was agreement between the SERS sensor and the GC/MS determinations. A standard addition experiment yielded a PAH concentration of 900 ng l(-1) at the Gdańsk Harbor, which was of the same order as the GC/MS determinations of 12PAHs (200 ng(12PAH)l(-1)). The high SERS detection limit for seawater samples is explained by the competition for PAHs between the sensor membrane and particulate matter surfaces. Thus, the SERS sensor can be applied, e.g., as a non-quantitative alarm sensor for relatively high PAH concentrations in heavily polluted waters. The spectral unmixing procedure applied for Gdańsk Harbor water confirmed the presence of phenanthrene at the highest concentration ([Phe]=140 ngl(-1)) and of Chr (2.7 ng l(-1)), but it did not detect the other PAHs present in the Gdańsk Harbor water, as determined by GC/MS. When compared to the past literature and databases, the SERS spectra indicated the presence of a mixture of molecules consisting of carotenoids, n-alkanes, amines or fatty acids, and benzimidazoles at the coastal station ZN2. The spectra in the offshore direction indicated carboxylic acids. Interpretation of the farthest offshore in situ SERS measurements is difficult, principally due to the limited availability of reference spectra. The detection of the lower PAH concentrations commonly found in Baltic coastal water needs further research and development to obtain better sensitivity of the SERS sensor. However, the high analytical specificity of the SERS sensor also allows the detection of other chemical species that require the development of a SERS/Raman library for specific in situ spectral interpretation.     

The Character and Formation of Elongated Depressions on the Upper Bulgarian Slope

Seafloor elongated depressions are indicators of gas seepage or slope instability. Here we report a sequence of slopeparallel elongated depressions that link to headwalls of sediment slides on upper slope. The depressions of about 250 m in width and several kilometers in length are areas of focused gas discharge indicated by bubble-release into the water column and methane enriched pore waters. Sparker seismic profiles running perpendicular and parallel to the coast, show gas migration pathways and trapped gas underneath these depressions with bright spots and seismic blanking. The data indicate that upward gas migration is the initial reason for fracturing sedimentary layers. In the top sediment where two young stages of landslides can be detected, the slopeparallel sediment weakening lengthens and deepens the surficial fractures, creating the elongated depressions in the seafloor supported by sediment erosion due to slope-parallel water currents.     

Artificial reef effect and fouling impacts on offshore wave power foundations and buoys – a pilot study

Little is known about the effects of offshore energy installations on the marine environment, and further research could assist in minimizing environmental risks as well as in enhancing potential positive effects on the marine environment. While biofouling on marine energy conversion devices on one hand has the potential to be an engineering concern, these structures can also affect biodiversity by functioning as artificial reefs. The Lysekil Project is a test park for wave power located at the Swedish west coast. Here, buoys acting as point absorbers on the surface are connected to generators anchored on concrete foundations on the seabed. In this study we investigated the colonisation of foundations by invertebrates and fish, as well as fouling assemblages on buoys. We examined the influence of surface orientation of the wave power foundations on epibenthic colonisation, and made observations of habitat use by fish and crustaceans during three years of submergence. We also examined fouling assemblages on buoys and calculated the effects of biofouling on the energy absorption of the wave power buoys. On foundations we demonstrated a succession in colonisation over time with a higher degree of coverage on vertical surfaces. Buoys were dominated by the blue mussel Mytilus edulis. Calculations indicated that biofouling have no significant effect in the energy absorption on a buoy working as a point absorber. This study is the first structured investigation on marine organisms associated with wave power devices.     

Exhumed hydrocarbon traps in East Greenland: A comment on Andrews et al. (2020)

In a recent study, Andrews et al. (2020) describe “exhumed hydrocarbon traps” in North-East Greenland. The basic premise for their interpretation is that dark-coloured, pyrobitumen-bearing sandstones represent the remnants of once buried petroleum reservoirs. We do not see the necessary field or analytical evidence to support a model that has strong implications for resource evaluations. Andrews et al. (2020) have not considered previous published information on diagenetic and thermal maturity history of the area. A more probable model would include the intrusion of dykes and sills into a sedimentary succession with immature petroleum source rocks and reservoir-quality sandstones. The heating caused rapid generation of petroleum components and local hydrothermal circulation systems in adjacent porous sandstones. Any petroleum was rapidly destroyed leaving essentially only black grain-coatings and minor particles of pyrobitumen—essentially in one short-lived continuous process. The existence of new plays in the North Atlantic as proposed by Andrews et al. (2020) is in our opinion not substantiated as this requires analytical data from unaltered oils from the less mature parts of the sedimentary succession and considerations of thermal maturity and basin evolution. To draw conclusions that have a serious impact on resource evaluations based on the dark colouration of sandstones without comprehensive analytical data is, in our opinion, ill advised.