Determination of Gold in Twenty Geochemical Reference Samples by Flameless Atomic Absorption Spectrometry

After acid digestion, gold is extracted with MIBK and determinated by flameless atomic absorption spectrometry. The results for six USGS reference samples and fourteen French geochemical standards are presented and discussed. The agreement with working values for these standards is in the range of pm 5%.     

A ternary solid solution model for omphacite and its application to geothermobarometry of eclogites from the Middle Adula nappe (Central Alps, Switzerland)

A ternary solid solution model for omphacite with the end-members jadeite (NaAlSi₂O₆), diopside (CaMgSi₂O₆) and hedenbergite (CaFeSi₂O₆) was derived from experimental data from the literature. The subregular solution model, fitted by linear programming, is best suited to omphacites with very little aegirine component in common eclogites. Applying this solution model to the calculation of equilibrium phase diagrams of eclogites from the Adula nappe (Central Alps, Switzerland) results in large stability fields for common eclogite assemblages (garnet+omphacite+quartz+H₂O±kyanite). Within this field the compositions of garnet and omphacite show very little variation. A precise determination of the peak-pressure and temperature is not possible. The occurrence of amphibole, overgrowing the peak-pressure assemblage in fresh eclogite, suggests retrograde re-equilibration, still under eclogite facies conditions. The computation of isopleths for garnet and pyroxene end-members allows the estimation of the pressure and temperature conditions of this re-equilibration event (19–21  kbar, c .  700 °C).     

Oceanographic Change and Terrestrial Human Impacts in a Post A.D. 1400 Sediment Record from the Southwest Iceland Shelf

Environmental proxies of soil erosion on Iceland, and oceanographic conditions on the adjacent shelf, were measured on a 50 cm box core taken from the southwest Iceland shelf in 1993 during cruise 93030 of the Canadian ship, CSS Hudson. These data, covering the last several centuries, are compared with the documentary record of sea-ice changes around Iceland since A.D. 1600. The site is under the influence of the Irminger Current, which carries warm, saline, Atlantic water northward along the shelf. Because of the relative warmth of this current, sea ice rarely occurs off southwest Iceland, even during the most severe sea-ice intervals of the historical record. In severe sea-ice years, however, the ice drifts clockwise around Iceland from the northeast and east and, in rare cases, reaches the southern coasts (Ogilvie, 1992). The chronology of the core was established by converting the basal radiocarbon date to calendar years and assuming a linear sedimentation rate from the base of the core to the year of collection, 1993. Organic carbon, stable C and O isotope ratios, planktonic foraminiferal assemblages, and sediment magnetic parameters were measured on samples from the core, plotted against calendar years and compared to the Icelandic sea-ice index. The environmental proxies suggest that increased soil erosion, reduced salinity, and, possibly, decreased marine productivity prevailed during the severe sea-ice interval lasting from the last quarter of the eighteenth century to around 1920. Such a situation could develop with climatic cooling, increased storminess, and loss of vegetation cover to stabilise the soil. Although the core site generally lies outside the sea-ice limits, the evidence clearly shows the influence of sea ice and fresh water, and is sensitive to the overall climatic deterioration manifested by the sea-ice record.     

GEOLOGY OF NORTHERN CHIHLI AND EASTERN MONGOLIA.

During the last spring (April-May 1924), we have, F. Licent and I crossed the Northern Chihli and the eastern part of the Inner Mongolia.     

High-grade metamorphic processes which influence Archaean gold deposits, with particular reference to Big Bell, Australia

Abstract Mineralogical and geochemical evidence indicates that partial melting and desulphidation have occurred in the Big Bell gold deposit. Decarbonation may also have occurred, to account for the lack of a carbonate alteration halo; this is compatible with the present data, but difficult to test. The Big Bell deposit consists of auriferous sulphide-bearing (‘lode’;) schists with muscovite and K-feldspar, and surrounding biotite schists, all derived by intense premetamorphic alteration of rocks of mafic composition. Assemblages which include cordierite-sillimanite-K-feldspar-garnet-biotite-quartz suggest peak metamorphic conditions of 4–5 kbar, and 650–700° C, based on phase relations, geobaro-meters and garnet-biotite Fe-Mg exchange partitioning. Partial melting occurred at peak metamorphism, particularly in the altered mafic rocks in and around the deposit, and its occurrence may have been essential to the preservation of the deposit. Melting greatly limited the importance of devolatilization reactions, resulting in negligible aqueous fluids and no means of removing appreciable gold. Minor gold loss may have accompanied desulphidation. A diversity of complex metamorphic assemblages occurs around the mine, compared to the assemblages developed regionally; variable bulk rock composition influences this contrast, but there is no evidence of higher metamorphic grades at the mine, nor that this might have been the prime control on the different assemblages in this narrow belt. It is suggested that the Big Bell and Hemlo deposits are the higher metamorphic grade equivalents of the more abundant greenschist facies gold deposits within Archaean greenstone belts. This interpretation is favoured by the host rock setting and geochemical characteristics of Big Bell. Alternative models that suggest that this class of deposit is a new type must account for the absence of high-grade equivalents of the greenschist facies deposits and also the lack of low-grade equivalents of the Big Bell/Hemlo type. Archaean gold deposits in high-grade metamorphic terrains have undergone a series of processes that are not recorded in the more typical gold deposits of the greenschist facies.     

1998年4-5月地球同步轨道MeV电子通量增强事件

采用GOES9卫星观测的能量大于2MeV和大于4MeV电子通量和行星际飞船ACE太阳风参数的高时间分辨率资料,以及磁暴指数Dst资料,分析了1998年4-5月期间地球同步轨道电子通量增强事件的时间和能量响应特征及其与行星际太阳风参数、磁暴和亚暴等扰动条件的对应关系.结果表明,地球同步轨道相对论性（MeV）电子通量增强事件有明显的周日变化,中午极大和午夜极小.4月22日和5月5日开始的两次大事件中,能量大于2MeV电子通量中午极大值上升到最大值的时间尺度分别约为4天和1天,中午极大值高于背景水平的持续时间分别为13天（4月22日-5月4日）和16天（5月4日-20日）以上.每次MeV电子通量增强事件的能量范围不完全相同.两次大事件的上升段都对应于磁暴的恢复相,与太阳风动压脉冲、高速流脉冲和负Bz分量关系密切.     

井间电磁成像系统应用研究

井间电磁（EM）成像系统的技术目标是实现井间电学特性的直接测量,并提供井间电阻率的二维及三维图像.从1997年开始,胜利油田与美国EMI公司合作,开展了EM技术的应用与研究,主要是通过大型、系统的现场试验,在大井间距的条件下,进一步验证仪器的性能,进行油藏研究的适用性和可行性分析;以系统的现场实测数据为依据,加快成像处理方法和软件的开发;开展穿透金属套管井的EM试验,探讨金属套管条件下的电阻率成像方法。两年来,利用EMI提供的XBH2000型测量系统,对胜利油田典型的低电阻率砂泥岩剖面,成功地进行了3对井、10个井次的试验。试验证明了仪器性能的可靠,取得了测量重复性好、系统完整的井间EM数据.并反演得到电阻率成像,在分析井间油气分布和油层开采动态方面,取得了良好的地质效果.