Experimental constraints on the volatility of germanium,zinc, and lithium in Martian basalts and the role of degassing in alteration of surface minerals

The surface of Mars is enriched in Cl and S which is linked to volcanic activity and degassing. Similarly, elevated Ge and Zn levels in Gale crater sedimentary bedrock indicate a magmatic source for these elements. To constrain the relative effects of Cl and S on the outgassing of these trace metals and chemical characteristics of primary magmatic vapor deposits incorporated to Martian surface, we conducted a set of degassing and fumarolic alteration experiments. Ge is found to be more volatile than Zn in all experiments. In S-bearing runs, the loss of Ge and Zn was less than any other experiments. In Cl-only runs, degassing of Zn was more than twice that of Ge within the first 10 min and percent loss increased for both elements with increasing time. In Cl + S runs, S-induced reduction of GeO₂ and ZnO to metallic Ge and Zn switches the preference of chloride formation from Zn to Ge. Up to 90% of Ge and Zn loss in the 1-h no volatile-added (NVA) experiments might be due to the small amounts of Cl contamination in NVA mixes via other oxides used for synthesis. Alteration experiments show different phases between 1-h and 24-/72-h runs. In 1-h runs, anhydrite and langbeinite dominate while in 24-/72-h runs halite and sylvite dominate the condensate assemblages. S-bearing phases form as the intermediate products of fumarolic deposition, while chlorides are common when the system is allowed to cool gradually. One-hour exposure was sufficient to form alteration phases and vapor deposits such as NaCl, KCl, CaSO₄, and langbeinites on the Martian analog minerals. These salts were identified in Martian meteorites and in situ measurements. Our results provide evidence that volcanic degassing along with fumarolic alteration could be a potential source for the enrichment and varying abundances of Cl, S, Fe, Zn, Ge in Martian surface, as well as a cause for Ge depletion in shergottites.     

Advancements in the U.S. army corps of engineers hydrographic survey capabilities: The SHOALS system

In an effort to modernize its hydrographic survey capabilities, the U.S. Army Corps of Engineers has undertaken a joint development program with Canada to construct and field test an operational prototype airborne lidar bathymeter system. The construction and field verification effort of this program began March 1990 with field tests scheduled for winter 1993. The system will be built by Optech, Inc., based on their design of the LARSEN 500, the only commercial lidar system currently producing bathymetric surveys.

The Scanning Hydrographic Operational Airborne Lidar Survey (SHOALS) system will operate out of a medium‐sized helicopter such as the Bell 212 at approximately 200 meters altitude where the laser scanning system generates a swath width of just over 140 meters. System requirements dictate a laser operating at 200 Hz in both the blue‐green wave length for maximum water depth penetration and the infrared for surface interface recognition. Each laser shot strikes the water surface at a known location where its energy is partially reflected back to the receiver and partially transmitted through the water column. Transmitted energy undergoes scattering and absorption along its path to the bottom where the remaining energy is then reflected back to the receiver.

The Transceiver, Positioning, Acquisition, Control and Display, and Ground Based Data Processing subsystems make up the SHOALS system. These subsystems have been designed, constructed, and currently are being laboratory tested prior to total system integration and field testing. This article presents the system's design and discusses system use following development.     

Identifying transboundary aquifers in need of international resource management in the Southern African Development Community region

Transboundary aquifer (TBA) management, in part, seeks to mitigate degradation of groundwater resources caused either by an imbalance of abstraction between countries or by cross-border pollution. Fourteen potential TBAs were identified within a hydrogeological mapping programme based on simple hydrogeological selection criteria for the Southern African Development Community (SADC) region. These have been reassessed against a set of data associated with five categories: (1) groundwater flow and vulnerability (which is perceived as the over-arching influence on the activity level of each TBA), (2) knowledge and understanding, (3) governance capability, (4) socio-economic/water-demand factors, and (5) environmental issues. These assessments enable the TBAs to be classified according to their need for cross-border co-operation and management. The study shows that only two of the 14 TBAs have potential to be the cause of tension between neighbouring states, while nine are potentially troublesome and three are unlikely to become problematic even in the future. The classification highlights the need to focus on data gathering to enable improved understanding of the TBAs that could potentially become troublesome in the future due to, for example, change in demographics and climate.     

Integrating the LISFLOOD‐FP 2D hydrodynamic model with the CAESAR model: implications for modelling landscape evolution

Landscape evolution models (LEMs) simulate the geomorphic development of river basins over long time periods and large space scales (100s–1000s of years, 100s of km²). Due to these scales they have been developed with simple steady flow models that enable long time steps (e.g. years) to be modelled, but not shorter term hydrodynamic effects (e.g. the passage of a flood wave). Nonsteady flow models that incorporate these hydrodynamic effects typically require far shorter time steps (seconds or less) and use more expensive numerical solutions hindering their inclusion in LEMs. The recently developed LISFLOOD‐FP simplified 2D flow model addresses this issue by solving a reduced form of the shallow water equations using a very simple numerical scheme, thus generating a significant increase in computational efficiency over previous hydrodynamic methods. This leads to potential convergence of computational cost between LEMs and hydrodynamic models, and presents an opportunity to combine such schemes. This paper outlines how two such models (the LEM CAESAR and the hydrodynamic model LISFLOOD‐FP) were merged to create the new CAESAR‐Lisflood model, and through a series of preliminary tests shows that using a hydrodynamic model to route flow in an LEM affords many advantages. The new model is fast, computationally efficient and has a stronger physical basis than a previous version of the CAESAR model. For the first time it allows hydrodynamic effects (tidal flows, lake filling, alluvial fans blocking valley floor) to be represented in an LEM, as well as producing noticeably different results to steady flow models. This suggests that the simplification of using steady flow in existing LEMs may bias their findings significantly. Copyright © 2013 John Wiley & Sons, Ltd.     

Review of methods used to estimate catchment response time for the purpose of peak discharge estimation

Abstract

Large errors in peak discharge estimates at catchment scales can be ascribed to errors in the estimation of catchment response time. The time parameters most frequently used to express catchment response time are the time of concentration (T_C), lag time (T_L) and time to peak (T_P). This paper presents a review of the time parameter estimation methods used internationally, with selected comparisons in medium and large catchments in the C5 secondary drainage region in South Africa. The comparison of different time parameter estimation methods with recommended methods used in South Africa confirmed that the application of empirical methods, with no local correction factors, beyond their original developmental regions, must be avoided. The T_C is recognized as the most frequently used time parameter, followed by T_L. In acknowledging this, as well as the basic assumptions of the approximations T_L = 0.6T_C and T_C ≈ T_P, along with the similarity between the definitions of the T_P and the conceptual T_C, it was evident that the latter two time parameters should be further investigated to develop an alternative approach to estimate representative response times that result in improved estimates of peak discharge at these catchment scales.

Editor Z.W. Kundzewicz; Associate editor Qiang Zhang     

Diamonds from Jagersfontein (South Africa): messengers from the sublithospheric mantle

The diamond population from the Jagersfontein kimberlite is characterized by a high abundance of eclogitic, besides peridotitic and a small group of websteritic diamonds. The majority of inclusions indicate that the diamonds are formed in the subcratonic lithospheric mantle. Inclusions of the eclogitic paragenesis, which generally have a wide compositional range, include two groups of eclogitic garnets (high and low Ca) which are also distinct in their rare earth element composition. Within the eclogitic and websteritic suite, diamonds with inclusions of majoritic garnets were found, which provide evidence for their formation within the asthenosphere and transition zone. Unlike the lithospheric garnets all majoritic garnet inclusions show negative Eu-anomalies. A narrow range of isotopically light carbon compositions (δ¹³C −17 to −24 ‰) of the host diamonds suggests that diamond formation in the sublithospheric mantle is principally different to that in the lithosphere. Direct conversion from graphite in a subducting slab appears to be the main mechanism responsible for diamond formation in this part of the Earth’s mantle beneath the Kaapvaal Craton. The peridotitic inclusion suite at Jagersfontein is similar to other diamond deposits on the Kaapvaal Craton and characterized by harzburgitic to low-Ca harzburgitic compositions.