Kankan diamonds (Guinea) I: from the lithosphere down to the transition zone

Peridotitic inclusions in alluvial diamonds from the Kankan region of Guinea in West Africa are mainly of lherzolitic paragenesis. Nevertheless, extreme Cr₂O₃ contents (max. 17 wt%) in some of the exclusively lherzolitic garnets document that the diamond source experienced a previous stage of melt extraction in the spinel stability field. This initial depletion was followed by at least two metasomatic stages: (1) enrichment of LREE and Sr and (2) introduction mainly of MREE–HREE and other HFSE (Ti, Y, Zr, Hf). The Ti- and HFSE-poor character of stage (1) points towards a CHO-rich fluid or carbonatitic melt, the high HFSE in stage (2) favour silicate melts as enriching agent. Eclogitic inclusions are derived from a large depth interval ranging from the lithosphere through the asthenosphere into the transition zone. The occurrence of negative Eu anomalies in garnet and clinopyroxene from both lithosphere and transition zone suggests a possible relationship to subducted oceanic crust. Lithospheric eclogitic inclusions are derived from heterogeneous sources, that may broadly be divided into a low-Ca group with LREE depleted trace element patterns and a high-Ca group representing a source with negative LREE–HREE slope that is moderately enriched in incompatible elements relative to primitive mantle. High-Ca inclusions of majoritic paragenesis are significantly more enriched in incompatible elements, such as in Sr and LREE. Calculated whole rock compositions require metasomatic enrichment even if a derivation from MORB is assumed. Received: 26 January 2000 / Accepted: 18 May 2000     

Stable isotopic evidence for Middle Pleistocene environmental change from a loess‐paleosol sequence: Kärlich,Germany

Loess‐paleosol sequences are important terrestrial archives of palaeoenvironmental change. Such sequences are rich in pedogenic carbonate, the oxygen and carbon isotopic values of which can provide important palaeoenvironmental information. Although some studies have pioneered the use of O and C isotopes in loess‐paleosol sequences, they are not routinely used as palaeoclimate proxies. In this study we analysed the sedimentology, micromorphology, geochronology and isotopic geochemistry of a Middle Pleistocene loess‐paleosol section, located at Kärlich, Germany. The section studied correlates with the Elsterian glacial (MIS 12) and Holsteinian interglacial (MIS 11). Embedded tephra layers yielded ⁴⁰Ar/³⁹Ar ages of 466±3 ka, 447±1 ka and 361±3 ka. The sedimentology and micromorphology of the sequence record a shift from accretionary loess accumulation (MIS 12) to prolonged pedogenesis at a stable land surface (MIS 11). Soil carbonate δ¹⁸O values record an enrichment of ～3‰ during the accumulation of the loess, reaching peak values comparable with those found in the MIS 11 soil. The δ¹⁸O signal is interpreted as reflecting temperature, highlighting the potential of δ¹⁸O analysis of European loess soil carbonates as a means of reconstructing palaeotemperature history.     

石榴石Lu-Hf、原位独居石U-Pb定年对多期变形的时代制约——以北祁连托勒牧场为例

多期变质变形事件的精确年代限定是造山构造年代学研究的热点问题之一。本文尝试运用面理弯切轴测量技术,结合石榴石Lu-Hf和原位独居石U-Pb定年,厘定北祁连托勒牧场地区石榴石和斜长石斑晶记录的两期构造变形事件:石榴石斑晶生长记录的早期构造变形事件年代为512.3±2.7Ma;斜长石斑晶生长记录的晚期构造变形事件年代不早于481.0±2.3Ma,并推断该期构造变形水平挤压主应力方向为北东-南西。斜长石斑晶内未发现独居石,用于年代学测试的独居石颗粒均位于斜长石斑晶外基质中。显微构造分析认为,独居石生长不早于斜长石斑晶。481.0±2.3Ma的独居石U-Pb年龄,应为斜长石斑晶所记录构造变形的时代下限。结合前人锆石U-Pb定年和Hf同位素研究结果分析认为,获得的512.3±2.7Ma石榴石-全岩Lu-Hf等时线年龄,代表了祁连洋俯冲过程中石榴石的生长时间,后期变质变形作用未对石榴石的Lu-Hf同位素体系产生明显影响。结合显微构造分析,石榴石Lu-Hf定年可为早期构造变形提供有效年代学制约。     

Modes of variability of Southern Hemisphere atmospheric circulation estimated by AGCMs

The seasonal mean variability of the atmospheric circulation is affected by processes with time scales from less than seasonal to interannual or longer. Using monthly mean data from an ensemble of Atmospheric General Circulation Model (AGCM) realisations, the interannual variability of the seasonal mean is separated into intraseasonal, and slowly varying components. For the first time, using a recently developed method, the slowly varying component in multiple AGCM ensembles is further separated into internal and externally forced components. This is done for Southern Hemisphere 500?hPa geopotential height from five AGCMs in the CLIVAR International Climate of the Twentieth Century project for the summer and winter seasons. In both seasons, the intraseasonal and slow modes of variability are qualitatively well reproduced by the models when compared with reanalysis data, with a relative metric finding little overall difference between the models. The Southern Annular Mode (SAM) is by far the dominant mode of slowly varying internal atmospheric variability. Two slow-external modes of variability are related to El Ni?o-Southern Oscillation (ENSO) variability, and a third is the atmospheric response to trends in external forcing. An ENSO-SAM relationship is found in the model slow modes of variability, similar to that found by earlier studies using reanalysis data. There is a greater spread in the representation of model slow-external modes in winter than summer, particularly in the atmospheric response to external forcing trends. This may be attributable to weaker external forcing constraints on SH atmospheric circulation in winter.     

A depositional history of particulate organic carbon in a floodplain lake from the lower Ob’ River, Siberia

Northern, high latitude soils have stored vast amounts of organic carbon (OC) in permafrost and peats for many millennia, however, climate change may mobilize and release this particulate OC (POC) to arctic rivers. Deltaic and floodplain lakes that receive fluvial sediments, primarily during the spring freshet, may provide records of such changes in riverine POC. Here, we examine properties of OC in a sediment core from a lake in the lower floodplain of the Ob’ River, west Siberia, to determine how the properties of OC deposited in this lake varied over many decades and to evaluate use of this sedimentary OC as a recorder of riverine POC load and properties. The core predates the most recent, dramatic changes in arctic climate and hence may serve as a benchmark against which to contrast future variations in fluvial POC discharge. Elemental, stable carbon and radiocarbon isotopic analyses, along with nuclear magnetic resonance (NMR) spectroscopy and molecular-level information (lignin phenol composition), indicate two major sources of OC to most of the sediments in this lake: plant-derived OC and algal-derived OC. However, a mixing model indicates that the nature and ¹⁴C content of these two sources change with depth in the sediment, resulting in three distinct layers: surface horizons, a “high-OC” layer and “mixing” horizons found above and below the high-OC layer. The plant-derived component is significantly aged throughout the core (¹⁴C ages of 1300-3900 years) and appears to derive from primarily local, tundra sources, whereas the algal component is modern. Our analysis suggests that the usual mode of OC deposition, as exemplified by the “mixing” and surface horizons, involved mixing of varying amounts of new algal production (35-65%) with aged permafrost- or peat-derived OC. This deposition was interrupted by an event, such as the collapse of a riverbank, which laid down the compositionally distinct “high-OC” layer in which plant-derived OC mixes with aged mineral-soil-derived OC without clear input from algae. The relative amounts of the plant and algal components in the lake sediments appear to be controlled primarily by local hydrological conditions rather than by river-wide processes, suggesting that comparison of sediment records from multiple lakes within a floodplain will be important to assess changes in POC export by arctic rivers. However, the flux and nature of the higher plant-derived OC may carry important information on the sources and dynamics of OC stored within the drainage basin.     

On the relationships between catchment scale and streamwater mean residence time

The relationship between streamwater mean residence time (MRT) and landscape characteristics is poorly understood. We used tritium (³H) to define our MRT. We tested the hypothesis that baseflow water MRT increases with increasing absolute catchment size at the Maimai catchments. These catchments are simple hydrologic systems relative to many catchments around the world, with uniformly wet climatic conditions, little seasonality, uniform and nearly impermeable bedrock, steep short hillslopes, shallow soils, and well‐characterized hillslope and catchment hydrology. As a result, this is a relatively simple system and an ideal location for new MRT‐related hypothesis testing. Whilst hydrologists have used ³H to estimate water age since the 1960s nuclear testing spike, atmospheric ³H levels have now approached near background levels and are often complicated by contamination from the nuclear industry. We present results for ³H sampled from our set of nested catchments in nuclear‐industry‐free New Zealand. Because of high precision analysis, near‐natural atmospheric ³H levels, and well‐characterized rainfall ³H inputs, we were able to estimate the age of young (i.e. less than 3 years old) waters. Our results showed no correlation between MRT and catchment size. However, MRT was correlated to the median sub‐catchment size of the sampled watersheds, as shown by landscape analysis of catchment area accumulation patterns. These preliminary findings suggest that landscape organization, rather than total area, is a first‐order control on MRT and points the way forward for more detailed analysis of how landscape organization affects catchment runoff characteristics. Copyright © 2003 John Wiley & Sons, Ltd.     

Solar and Heliospheric Observatory/Large Angle Spectrometric Coronagraph Polarimetric Calibration

We present a polarimetric characterization and correction for the Solar and Heliospheric Observatory/Large Angle Spectrometric Coronagraph (SOHO/LASCO) C2 and C3 white light coronagraphs. By measuring the uncorrected polarization angles in solar minimum C2 coronal images, we have determined that the coronagraph acts as an optical phase retarder which converts a small fraction of the incoming radiation polarization from linear to circular. In addition, from the measurements of polarization angle in C3 coronal images we have determined that a component of the instrumentally scattered light in that instrument is polarized. We infer the retardation angle for C2 and compute the corresponding Mueller matrix, and determine the polarized stray light spatial profile in C3. The C2 Mueller matrix and C3 polarized stray light profiles are used to correct for instrumental effects in solar minimum coronal observations to obtain polarized brightness between two and thirty-two solar radii, which show deep polar coronal holes extending to the limit of the field of view.