An urban neighborhood temperature and energy study from the CAPITOUL experiment with the Solene model

A methodology is proposed to analyze the radiative and thermal exchanges between a small urban neighborhood and the atmosphere based on the use of the thermoradiative model SOLENE and radiometric measurements to optimize the effective values of its constant parameters. Applied to the center of Toulouse, France, the optimization data are building surface temperatures measured with handheld radiometers and a downward-facing pyranometer during one of the intense observation periods of the CAnopy and Particles Interactions in TOulouse Urban Layer (CAPITOUL) experimental campaign. The quality of the simulations is assessed by comparing, without any other model adjustment, the model outputs for two diurnal cycles (1?day in summer and 1?day in winter) against two independent experimental datasets from fixed permanent radiometers and from sensors measuring the solar, infrared and sensible heat fluxes to the atmosphere at the top of a mast 30?m above the roofs. These simulations allow us to further analyze the separate contributions of the different surface classes, roofs, facades and pavement to these fluxes and to compare them with their counterparts observed over a neighborhood of Marseilles city center during a previous experiment. The partition is remarkably similar in Toulouse and Marseilles: 6–7% for the solar radiation, 73–76% for the infrared radiation and 17–20% for the sensible heat flux. The contribution of roofs to the infrared flux appears proportional to their plan area proportion (built density) but not the contributions to the other two fluxes. The contributions of facades to all three fluxes are roughly proportional to their fraction of the total surface area.     

FeO*-Al2O3-TiO2-Rich Rocks of the Tertiary Bana Igneous Complex, West Cameroon

FeO*‐Al₂O₃‐TiO₂‐rich rocks are found associated with transitional tholeiitic lava flows in the Tertiary Bana plutono‐volcanic complex in the continental sector of the Cameroon Line. These peculiar rocks consist principally of iron‐titanium oxides, aluminosilicates and phosphates, and occur as layers 1–3 m thick occupying the upper part of lava flows on the southwest (site 1) and northwest (site 2) sites of the complex. Mineral constituents of the rocks include magnetite, ilmenite, hematite, rutile, corundum, andalusite, sillimanite, cordierite, quartz, plagioclase, alkali feldspar, apatite, Fe‐Mn phosphate, Al phosphate, micas and fine mixtures of sericite and silica. Texturally and compositionally, the rocks can be subdivided into globular type, banded type, and Al‐rich fine‐gained massive type. The first two types consist of dark globule or band enriched in Fe‐Ti oxides and apatite and lighter colored groundmass or bands enriched in aluminosilicates and quartz, respectively. The occurrence of andalusite and sillimanite and the compositional relations of magnetite and ilmenite in the FeO*‐Al₂O₃‐TiO₂‐rich rocks suggest temperatures of crystallization in a range of 690–830°C at low pressures. The Bana FeO*‐Al₂O₃‐TiO₂‐rich rocks are characterized by low concentrations of SiO₂ (25–54.2 wt%), Na₂O + K₂O (0–1%), CaO (0–2%) and MgO (0–0.5%), and high concentrations of FeO* (total iron as FeO, 20–42%), Al₂O₃ (20–42%), TiO₂ (3–9.2%), and P₂O₅ (0.26–1.30%). TiO₂ is positively correlated with Al₂O₃ and inversely correlated with FeO*. The bulk rock compositions cannot be derived from the associated basaltic magma by crystal fractionation or by partial melting of the mantle or lower crustal materials. In ternary diagrams of (Al₂O₃)?(CaO + Na₂O + K₂O)?(FeO*+ MnO + MgO) and (SiO₂)?(FeO*)?(Al₂O₃), the compositional field of the rocks is close to that of laterite and is distinct from the common volcanic rocks, suggesting that the rocks are derived from lateritic materials by recrystallization when the materials are heated by the basaltic magmas. A hydrothermal origin is discounted because the rocks contain high‐temperature mineral assemblages and lack sulfide minerals. It is proposed that the FeO*‐Al₂O₃‐TiO₂‐rich rocks of the Bana complex were formed by pyrometamorphism of laterite by the heat of basaltic magmas.     

On the driving force of cation exchange in clays: Insights from combined microcalorimetry experiments and molecular simulation

We study the origin of the ionic exchange enthalpy in montmorillonite clays using microcalorimetry measurements and molecular simulation. We first determine the standard reaction enthalpy for well-defined interlayer water contents. We then show by a detailed analysis based on thermodynamic cycles that replacing Na⁺ ions by Cs⁺ in the interlayer of montmorillonite clays is an endothermic process, and that the overall exchange is exothermic only because it is dominated by the exothermic replacement of Cs⁺ by Na⁺ in the aqueous phase. This conclusion from ionic exchange enthalpies supports the one of a recent study of the ionic exchange free energy by Teppen and Miller [Teppen B. J. and Miller D. M. (2006) Hydration energy determines isovalent cation exchange selectivity by clay minerals. Soil Sci. Soc. Am. J.70(1), 31-40] and contradicts long-held views on the role of ion-clay interactions in determining the ionic exchange thermodynamics. This calls for a paradigm shift for the origin of this exchange: The driving force is the “hydrophobicity” of Cs⁺ compared to Na⁺ and not its affinity for clay surfaces.     

Stratigraphic organisation,spatial distribution,palaeoenvironmental reconstruction,and demise of Lower Cretaceous (Barremian-lower Aptian) carbonate platforms of the Western Pontides (Black Sea region,Turkey)

Barremian-Lower Aptian platform carbonates (“Urgonian limestones”) of the northern margin of the Istanbul zone extend from Zonguldak to the Kurucasile area along the Black Sea coast. New stratigraphic data on the “Inpiri” Formation of the Inpiri-Kurucasile area are based on the identification of calcareous algae, foraminifera, and rudists. They show that this lithostratigraphic unit is stratigraphically and lithologically equivalent to the Ökü?medere Formation from Zonguldak. Some of the biostratigraphic markers are reported for the first time in Anatolia. Foraminifera are represented by several forms with a significant biostratigraphic potential used to distinguish the Barremian from the lower Aptian. Lower Aptian beds also yield relatively advanced caprinid rudists.The Ökü?medere Formation is relatively thin, terrigeneous-rich, and rudist-free or rudist-poor in the Kurucasile sector, and thick, terrigeneous-poor, and rudist-rich from Amasra to Zonguldak, with a set of marker beds including either charophytes or Palorbitolina and capped by a coral unit underlying ammonite bearing marls. Terrigeneous-rich carbonates from the eastern sector are interpreted as marginal marine coastal, infralittoral environments and grade distally, northward, to marly basinal sediments. By contrast “Urgonian type” limestones from the Zonguldak-Amasra region possess a wide extent and no transition to coastal or basinal sediments has been observed. A transition from a typical platform westward to a mixed siliciclastic-carbonate ramp eastward was controlled by both the nature of the adjacent exposed area and tectonic factors affecting the overall continental margin that is a northward downwarping. The exposed area was flanked southward by a belt of coastal siliciclastics grading southward and eastward to deep water sediments of the Ulus basin. In mid-Bedoulian time, carbonate platform demise from the western region was drowned below deeper marly sediments whereas the eastern siliscilastic-carbonate ramp was buried below coastal clastics.     

Accurate hypocentre locations in the Middle-Durance Fault Zone, South-Eastern France

A one-dimensional velocity model and station corrections for the Middle-Durance fault zone (south-eastern France) were computed by inverting P-wave arrival times recorded on a local seismic network of 8 stations. A total of 93 local events with a minimum of 6 P-phases, RMS 0.4 s and a maximum gap of 220° were selected. Comparison with previous earthquake locations shows an improvement for the relocated earthquakes. Tests were carried out to verify the robustness of inversion results in order to corroborate the conclusions drawn from our findings. The obtained minimum 1-D velocity model can be used to improve routine earthquake locations and represents a further step toward more detailed seismotectonic studies in this area of south-eastern France.     

Recent geological and hydrological activity on Mars: The Tharsis/Elysium corridor

The paradigm of an ancient warm, wet, and dynamically active Mars, which transitioned into a cold, dry, and internally dead planet, has persisted up until recently despite published Viking-based geologic maps that indicate geologic and hydrologic activity extending into the Late Amazonian epoch. This paradigm is shifting to a water-enriched planet, which may still exhibit internal activity, based on a collection of geologic, hydrologic, topographic, chemical, and elemental evidences obtained by the Viking, Mars Global Surveyor (MGS), Mars Odyssey (MO), Mars Exploration Rovers (MER), and Mars Express (MEx) missions. The evidence includes: (1) stratigraphically young rock materials such as pristine lava flows with few, if any, superposed impact craters; (2) tectonic features that cut stratigraphically young materials; (3) features with possible aqueous origin such as structurally controlled channels that dissect stratigraphically young materials and anastomosing-patterned slope streaks on hillslopes; (4) spatially varying elemental abundances for such elements as hydrogen (H) and chlorine (Cl) recorded in rock materials up to 0.33 m depth; and (5) regions of elevated atmospheric methane. This evidence is pronounced in parts of Tharsis, Elysium, and the region that straddles the two volcanic provinces, collectively referred to here as the Tharsis/Elysium corridor. Based in part on field investigations of Solfatara Crater, Italy, recommended as a suitable terrestrial analog, the Tharsis/Elysium corridor should be considered a prime target for Mars Reconnaissance Orbiter (MRO) investigations and future science-driven exploration to investigate whether Mars is internally and hydrologically active at the present time, and whether the persistence of this activity has resulted in biologic activity.     

Mid- to late Holocene environmental and climatic changes in New Caledonia, southwest tropical Pacific, inferred from the littoral plain Gouaro-Déva

Multiproxy analysis of three littoral cores from western New Caledonia supports the hypothesis that the main controlling factors of environmental changes are sea-level change, ENSO variability and extra-tropical phenomena, such as the Medieval Warm Period (MWP) marked by a tendency for La Niña-like conditions in the tropical Pacific. The record starts during the late Holocene sea-level rise when the terrestrial vegetation indicated wet and cool conditions. The site was a coastal bay definitely transformed into a freshwater swamp at around 3400 cal yr BP, after the rapid drawdown of sea level to its current level. Sediments and foraminiferal assemblages indicated subsequent episodes of freshwater infillings, emersion or very high-energy conditions, likely related to climatic changes and mostly controlled by ENSO variability. Between 2750 and 2000 cal yr BP, relatively dry and cool climate prevailed, while wetter conditions predominated between ca. 1800 and 900 cal yr BP. The Rhizophoraceae peak between ca. 1080 and 750 cal yr BP, coeval with the MWP, may indicate a global phenomenon. Microcharcoal particles present throughout the record increased after 1500 cal yr BP, suggesting an anthropogenic source. From ca. 750 cal yr BP the appearance of current type of vegetation marks the human impact.     

Basic concepts of the crystallization from aqueous solutions: The example of aluminum oxy(hydroxi)des and aluminosilicates

This overview features the chemical background on condensation phenomena of the aluminum cation in aqueous solution. The formation of polycationic molecular clusters and nanosized solid phases of aluminum oxy(hydroxi)des is interpreted with illustrative mechanisms, building a bridge between solution chemistry and solid-state chemistry. The formation of the main structural types of aluminosilicates (zeolites, clays, imogolite) is also illustrated through the aqueous chemistry of aluminum and silicates.     

The Ufa indenter: stratigraphic and geophysic evidences for an actual indentation of the Southern Urals by the East European craton

Study of the altitudes of the lowest part of the Upper Cretaceous–Eocene and Aktschagylian–Quaternary stratigraphic ensembles known on the western slope of the Southern Urals evidences the existence of an East–West elongated dome which follows the N53° latitude. This ridge is superimposed at depth with the remnants of the Sernovodsk–Abdulino Aulacogen and with the Belaya tear fault, which support the existence of a recent rejuvenation of these old structures. North of these disruptions the Southern Urals display a clear bent towards the East. Detailed microstructural studies show that this curvature is associated with a typical stress pattern which suggests the existence of an indentation of the fold belt by the East European craton. The hypothesis of an Ufa indenter is not supported by an equivalent East–West deep fault north of the bend. However, a long N100° magnetic anomaly, interpreted as a shear zone, suggests that the indenter is a reality. Quaternary uplift and crustal thickening at its front as well as seismological data support our interpretation. It is not stressed that the curvature of the Urals observed at 56° latitude results solely from this recent indentation. It is only assumed that the actual indentation is rejuvenating a former unevenness which existed before in the East European craton. Study of the inner part of the indenter shows that this type of structure is not necessarily rigid and undeformed. Some of the structures described on the URSEIS deep seismic line could be much younger than previously expected.     

Inverse Modelling for Identification of Multiple-Point Releases from Atmospheric Concentration Measurements

An inverse modelling methodology is proposed for the identification of multiple-point sources releasing similar tracer, in which influences from the various emissions are merged in each detector’s measurement. The identification is addressed from a limited merged set of atmospheric concentration measurements. The methodology is blended with the natural information provided by the geometry of the monitoring network in terms of the weight functions that interpret the associated visibility/illumination of the monitoring network. The release parameters, locations and intensities of the multiple-point sources are estimated by minimizing the objective function within the least squares framework. The methodology has been successfully applied to identify the two- and three- point simultaneous emissions from synthetic measurements generated by the model without noise or with controlled noise artificially added, and from pseudo-real measurements generated from the Indian Institute of Technology low wind diffusion experiment by combining several of single-point release runs. With the synthetic measurements, all the release parameters are retrieved exactly as those prescribed in all the runs. With the pseudo-real measurements, the release locations are retrieved with an average error of 13 m and intensities are estimated on an average within a factor of 1.5. In a sensitivity analysis, it is shown that the incurred errors in the retrieval of the two- and three-point sources with the pseudo-real data correspond to the 10–30 % Gaussian distributed random noise in the observations. Theoretical and computational comparisons are given between the weighted and non-weighted classical formulations. In addition, an alternative strategy is proposed in order to reduce the computational time required in the source estimation.