New thermal triaxial apparatus for unsaturated soils using the osmotic method

The study of the temperature effects on the behaviour of saturated and unsaturated soils on triaxial paths requires the development of a new triaxial experimental device of 3.5 MPa of confining pressure and equipped with a heating collar-controlled temperature. In addition to this case of the unsaturated soils, a special pedestal is developed, so as to impose suctions up to 9 MPa using an osmotic solution of polyethylene glycol (PEG) 6000 through a permeable semi-membrane. Measurements of the degree of saturation and the variation of volume during tests induce various problems, primarily related to the thermal dilation of the osmotic solution and the cell-water system. These problems have been solved by carrying out a preliminary calibration. The applicability of this new apparatus concerns environmental geotechnics and geological engineering such as the design and behaviour of engineered barriers as well as the behaviour of the receiving layers of storage sites like radioactive waste.     

Distribution and geological control of mud volcanoes and other fluid/free gas seepage features in the Mediterranean Sea and nearby Gulf of Cadiz

Existing knowledge on the distribution of mud volcanoes (MVs) and other significant fluid/free gas-venting features (mud cones, mud pies, mud-brine pools, mud carbonate cones, gas chimneys and, in some cases, pockmark fields) discovered on the seafloor of the Mediterranean Sea and in the nearby Gulf of Cadiz has been compiled using regional geophysical information (including multibeam coverage of most deepwater areas). The resulting dataset comprises both features proven from geological sampling, or in situ observations, and many previously unrecognized MVs inferred from geophysical evidence. The synthesis reveals that MVs clearly have non-random distributions that correspond to two main geodynamic settings: (1) the vast majority occur along the various tectono-sedimentary accretionary wedges of the Africa-Eurasia subduction zone, particularly in the central and eastern Mediterranean basins (external Calabrian Arc, Mediterranean Ridge, Florence Rise) but also along its westernmost boundary in the Gulf of Cadiz; (2) other MVs characterize thick depocentres along parts of the Mesozoic passive continental margins that border Africa from eastern Tunisia to the Levantine coasts, particularly off Egypt and, locally, within some areas of the western Mediterranean back-arc basins. Meaningfully accounting for MV distribution necessitates evidence of overpressured fluids and mud-rich layers. In addition, cross-correlations between MVs and other GIS-based data, such as maps of the Messinian evaporite basins and/or active (or recently active) tectonic trends, stress the importance of assessing geological control in terms of the presence, or not, of thick seals and potential conduits. It is contended that new MV discoveries may be expected in the study region, particularly along the southern Ionian Sea continental margins.     

Selected contributions from the 11th Gas in Marine Sediments International Conference of September 2012, Nice: an introduction

This Introduction presents an overview of selected contributions from the 11th Gas in Marine Sediments International Conference held on the 4–7 September 2012 in Nice, France, and published in this special issue of Geo-Marine Letters under the guest editorship of Catherine Pierre, Patrice Imbert and Jean Mascle. These cover fluid seepage dynamics at widely varying spatiotemporal scales in a giant buried caldera of the Caspian Sea, mud volcanoes and pockmarks in the Mediterranean and adjoining Gulf of Cadiz, as well as Lake Baikal, pockmarks of shallower waters along the Atlantic French coast and in Baltic Sea lagoons, deepwater pockmarks and cold seeps on the Norwegian margin and the Hikurangi Margin of New Zealand, asphalt seepage sites offshore southern California, and the tectonically controlled southern Chile forearc. We look forward to meeting all again at the 12th Gas in Marine Sediments conference scheduled for 1–6 September 2014 in Taipei, Taiwan.     

Spatial and temporal variations in trace metal concentrations in surface sediments of the Marennes Oléron Bay. Relation to hydrodynamic forcing

Sediments quality assessment is of priority concern to provide a comprehensible overview of ecological and chemical state of an ecosystem. The Marennes-Oléron Bay, hosting the largest oyster production in France, is influenced by the historic polymetallic pollution of the Gironde Estuary. Despite, management efforts and decreasing emissions in the Gironde watershed, Cd levels in oysters from the bay are close to consumption limit (5 μg g⁻¹ dw, EC no. 466/2001). In this context, the aim of the study was to assess the priority metal (Ni, Cu, Zn, As, Ag, Cd, Hg, Pb and Th) concentrations in sediment within the Bay, by investigating spatial and temporal distribution variations and the role of hydrodynamic forcing. For that we selected three sites (east, west and south) characterizing different environments of the Bay and we observed metal concentrations, grain size distribution, bed elevation and wave activities during a year survey. The sampling strategy pointed out both spatial and temporal metal concentrations variability in sediment. In general, metal enrichments were close to geochemical background. The eastern part of the Bay, largely influenced by the Charente river particulate deposition, presented constant concentrations over the survey. In contrast, in the western part, bed elevation was strongly influenced by hydrodynamic forcing especially wave activities, and metal distribution showed constant metal concentrations except very located Cd minor enrichment related to the Gironde influence via the Antioche Strait (north). The southern part was disconnected from the rest of the Bay and showed minor to very located moderately severe Cd enrichment, related to the Gironde water discharges via the Maumusson Strait (south). Thus, the multi-disciplinary approach was relevant to characterize the interactions between hydrodynamic forcing on the environment and sediments and their metal quality state which (i) were close to geochemical background over a year for Ni, Cu, Zn, As, Ag, Hg and Pb (i) which presented enrichment of Cd in the western and southern part.     

A Simplified Dimensionless Model of the Passive Diffusion of Gases and Solutes in Groundwater Through Polymer Tubing

The dissolution of gases, such as oxygen, in groundwater is a means to provide electron acceptors required for the biological degradation of organic contaminants in aquifers. The use of polymeric emitters for passive gas diffusion in groundwater significantly increases the efficiency of oxygen transfer to the groundwater compared to conventional sparging. A critical parameter for the design of polymeric emitters is the diffusion coefficient (D) of the polymer tubing used to construct the emitters. Wilson and Mackay (1995) proposed a mathematical model (WM model) for the analysis of laboratory passive diffusion experiments aimed at characterizing D. Their analytical solution is obtained in Laplace space and its inversion requires the use of a numerical approximation technique. This article proposes an alternative to the WM model by simplifying it as a dimensionless ordinary differential equation (ODE) which is solved using simple integration. The validity of the dimensionless solution is discussed and the latter plotted into charts to provide easy‐to‐use analytical tools applicable to gas or solute diffusion in groundwater.     

Short‐term versus medium‐term monitoring for detecting gully‐erosion variability in a Mediterranean environment

This study investigates how medium‐term gully‐development data differ from short‐term data, and which factors influence their spatial and temporal variability at nine selected actively retreating bank gullies situated in four Spanish basin landscapes. Small‐format aerial photographs using unmanned, remote‐controlled platforms were taken at the gully sites in short‐term intervals of one to two years over medium‐term periods of seven to 13 years and gully change during each period was determined using stereophotogrammetry and a geographic information system. Results show a high variability of annual gully retreat rates both between gullies and between observation periods. The mean linear headcut retreat rates range between 0·02 and 0·26 m a^–1. Gully area loss was between 0·8 and 22 m² a^–1 and gully volume loss between 0·5 to 100 m³ a^–1, of which sidewall erosion may play a considerable part. A non‐linear relationship between catchment area and medium‐term gully headcut volume change was found for these gullies. The short‐term changes observed at the individual gullies show very high variability: on average, the maximum headcut volume change observed in 7–13 years was 14·3 times larger than the minimum change. Dependency on precipitation varies but is clearly higher for headcuts than sidewalls, especially in smaller and less disturbed catchments. The varying influences of land use and human activities with their positive or negative effects on runoff production and connectivity play a dominant role in these study areas, both for short‐term variability and medium‐term difference in gully development. The study proves the value of capturing spatially continuous, high‐resolution three‐dimensional data using small‐format aerial photography for detailed gully monitoring. Results confirm that short‐term data are not representative of longer‐term gully development and demonstrate the necessity for medium‐ to long‐term monitoring. However, short‐term data are still required to understand the processes – particularly human activity at varying time scales – causing fluctuations in gully erosion rates. Copyright © 2011 John Wiley & Sons, Ltd.     

Cluster analysis of a regional-scale soil geochemical dataset in northern California

A regional-scale soil geochemical study was conducted within a 22,000 km² area in northern California including the Sierra Nevada, Sacramento Valley, and northern Coast Range. Over 1300 soil samples were chemically analyzed for 42 elements. The distribution of distinct groups of elements demonstrates the interplay of geologic, hydrologic, geomorphologic and anthropogenic factors; however, it is difficult to fully appreciate the complexity of geochemical transport and weathering processes on a landscape-scale in an area of very complex geology with such a large dataset containing more than 40 variables. To examine the data from a perspective of multi-element groupings, cluster analyses were applied to the dataset. The analysis identified several groups of elements whose spatial patterns could be related to specific geologic sources.     

Palynological Analysis of Amber-Bearing Clay from the Lower Cretaceous of Central Lebanon

An amber-bearing lignitic layer of sandy clay from the Lower Cretaceous of Central Lebanon (Mderej-Hammana)yielded a well-preserved,moderately variegated palynoflora,which origin is mixed between land plants and marine microflora.Its detailed analysis led to fulfill its inventory,to propose a paleoenvironmental reconstruction,and to draw the paleoclimate which prevailed over the region:an estuarian area under a rather humid,temperate climate;a variety of ferns grew near the shore-side and in the inward l...