Large-scale Mechanical Redistribution of Orthopyroxene and Plagioclase in the Basement Sill, Ferrar Dolerites, McMurdo Dry Valleys, Antarctica: Petrological, Mineral-chemical and Field Evidence for Channelized Movement of Crystals and Melt

The Jurassic Ferrar dolerite sills of the McMurdo Dry Valleys,Antarctica represent the plumbing system for flood basalt eruptionsassociated with the breakup of Gondwana. Among the Ferrar sills,the 350–450 m thick cumulate-textured Basement Sill isdifferentiated into a Lower Marginal Zone (LMZ) gabbronorite,a thick Lower Zone (LZ) orthopyroxene–plagioclase orthocumulatepyroxenite, a strongly layered mela- to leuco-gabbronorite MiddleZone (MZ), a thick Upper Zone (UZ) gabbronorite with ferrogabbroicpods, and an Upper Marginal Zone (UMZ) gabbronorite. Texturesand mineral compositions in the LZ pyroxenite and MZ–UZgabbronorites are nearly identical, the main distinction beingthe greater relative proportion of plagioclase in the MZ–UZgabbronorites, and of pigeonite in the UZ. Most orthopyroxenein the LZ, MZ and UZ occurs as sub-euhedral, normally zonedprimocrysts, commonly with rounded plagioclase inclusions. Plagioclaseis usually sub-euhedral and normally zoned, but can containsodic cores interpreted to be xenocrystic. Orthopyroxene andfeldspar compositions thoughout the sill are generally fairlyuniform, and resemble the compositions of micro-phenocrystsin the chilled margins. We infer that the sill was filled bya c. 1250°C slurry of orthopyroxene + plagioclase phenocrystsor primocrysts that subsequently unmixed in response to buoyancyforces. The LZ websterite contains numerous anorthosite to gabbronoriteschlieren, veins and pipes (< 2 m diameter), which we interpretas fossil segregation channels. Textures and mineral compositionsin these felsic channels are very similar both to UZ and MZgabbronorites, and to the groundmass separating accumulatedorthopyroxene primocrysts in the LZ and MZ. We infer that plagioclase-charged,hydrous pore melt from the pyroxenite may have segregated, pooledand ascended through these conduits to feed growth of the UZgabbronorite. Detailed mapping shows that the pipes are separatedby about 15 m on average. Calculations suggest that this numberdensity of conduits could have drained the LZ cumulates of theirinterstitial melt + plagioclase in about 8 days. Sequences (eachc. 5–10 m thick) of layered leuco-gabbronorite in theMZ could represent intra-cumulate sills that formed from plagioclase-richslurries ascending in segregation channels. Fe–Ti-richpyroxenitic veins and pods (some pegmatitic) and an unusualcoarse-grained plagioclase facies occur at the contacts betweenmassive leuco-gabbronorite layers in the MZ. Discordant ferro-pegmatitepods and dykes occur throughout the UZ. We interpret these Fe-richpegmatoidal rocks as evolved residual melts expelled from thecompacting gabbronoritic cumulates of the MZ and UZ. KEY WORDS: Ferrar; cumulates; differentiation; Antarctica; layering     

Observed Behaviour of Laterally Expanded Stone Column in Soft Soil

The paper describes the behavior of remolded kaolin clay reinforced by stone column as investigated in laboratory. The installation of stone column was simulated by performing lateral expansion at different rates within hollow cylindrical remolded kaolin specimens initially subjected to K0 consolidation path. These specimens were, then, subjected to classical consolidated undrained triaxial tests while recording excess pore pressure values. The objective of the experimental programme was to quantify the effects of consolidation stress and stone column on the undrained Young’s modulus and shear strength of kaolin clay. Obtained results showed a significant improvement in Young’s modulus when the cavity expansion ratio and the consolidation stress increase. It was also found that the increase in undrained shear strength of improved kaolin clay mainly occurred at lower consolidation stress. Another important finding of this study is that the ratio of undrained Young’s modulus to undrained shear stress increases when the consolidation stress decreases. Finally, the paper presents a model developed for the design of stone columns.     

A Review of the IAG GeoPT™ and Certification Programmes,their Protocols,and the Differences between the Original and Potential Modifications to the Certification Protocol

The IAG conducts two programmes, the GeoPT ^? proficiency test and a certification programme that are closely interconnected. Both support the quality control/quality assurance activities of geochemical laboratories. Each derives an estimate of ‘true value’ for a number of samples, but arrives at that estimate, and its uncertainty, differently. This review discusses the history of the two programmes and compares the ‘true values’ and their uncertainties obtained through each. It then considers ‘fitness‐for‐purpose’ issues related to both GeoPT ^? and certification uncertainties. Issues related to potential modification of the IAG protocol for certification are also considered.     

Determination of Rare Earth Elements, Sc, Y, Zr, Ba, Hf and Th in Geological Samples by ICP-MS after Tm Addition and Alkaline Fusion

We present a revised method for the determination of concentrations of rare earth (REE) and other trace elements (Y, Sc, Zr, Ba, Hf, Th) in geological samples. Our analytical procedure involves sample digestion using alkaline fusion (NaOH-Na₂O₂) after addition of a Tm spike, co-precipitation on iron hydroxides, and measurement by sector field-inductively coupled plasma-mass spectrometry (SF-ICP-MS). The procedure was tested successfully for various rock types (i.e., basalt, ultramafic rock, sediment, soil, granite), including rocks with low trace element abundances (sub ng g⁻¹). Results obtained for a series of nine geological reference materials (BIR-1, BCR-2, UB-N, JP-1, AC-E, MA-N, MAG-1, GSMS-2, GSS-4) are in reasonable agreement with published working values.     

System parameters of soil foundations for time domain dynamic analysis

Soil-structure interaction analysis is usually carried out in the frequency domain, because the compliance functions of the half-space are known only in the frequency domain. Since non-linear analysis cannot be carried out in the frequency domain, a system with frequency independent parameters is used to represent the half-space soil medium so that a nonlinear analysis in the time domain becomes possible. The objective of this paper is to propose a system with lumped parameters, which are independent of frequency, to represent the half-space soil medium. The proposed frequency independent system consists of a number of real discrete structure elements; thus the existing dynamic analysis programs may be adoptable with little modification. In this paper, the parameters are found by minimizing the sum of the squares of deviations between the steady-state responses of the theoretical half-space model and those of the lumped parameter system over a specified frequency range. Once the parameters have been found, the lumped parameter system can be used in practical applications for time domain dynamic analysis of either linear or non-linear structures. In comparison with the dynamic response of the theoretical half-space model, the lumped parameter system yields satisfactory results.     

Stabilization of Atmospheric Concentrations of Greenhouse Gases

Given the present commitment of the developed countries according to the Kyoto Protocol, most published scenarios demonstrate that global greenhouse gases concentrations would not be stabilized at any level. In order to stabilize these concentrations, a deeper global involvement is needed. Taking Israel as an example of a `recently-developed' country, we assess the role that such countries could play by assuming voluntary commitments in strengthening global involvement. This case as a model may encourage a global scheme for curbing carbon emissions, in which the more developed countries assume a stronger role and the less developed countries participate according to the principle of common but differentiated responsibility. The scheme builds on the inverse relation that exists between the per capita gross domestic product and the rate of increase of emissions due to economic growth. According to this theoretical scheme, the voluntary commitments assumed by the `recently-developed' countries encourage the more developed countries to deepen their involvement by assuming more stringent reductions of emissions at home and transferring technological and financial means to the less developed countries. The proposed scheme would enable non-Annex I countries, both `recently-developed' countries and less developed countries, to participate much earlier in the net mitigation of greenhouse gases.     

A densification mechanism to model the mechanical effect of methane hydrates in sandy sediments

Recent pore-scale observations and geomechanical investigations suggest the lack of true cohesion in methane hydrate-bearing sediments (MHBSs) and propose that their mechanical behavior is governed by kinematic constrictions at pore-scale. This paper presents a constitutive model for MHBS, which does not rely on physical bonding between hydrate crystals and sediment grains but on the densification effect that pore invasion with hydrate has on the sediment mechanical properties. The Hydrate-CASM extends the critical state model Clay and Sand Model (CASM) by implementing the subloading surface model and introducing the densification mechanism. The model suggests that the decrease of the sediment available void volume during hydrate formation stiffens its structure and has a similar mechanical effect as the increase of sediment density. In particular, the model attributes stress-strain changes observed in MHBS to the variations in sediment available void volume with hydrate saturation and its consequent effect on isotropic yield stress and swelling line slope. The model performance is examined against published experimental data from drained triaxial tests performed at different confining stress and with distinct hydrate saturation and morphology. Overall, the simulations capture the influence of hydrate saturation in both the magnitude and trend of the stiffness, shear strength, and volumetric response of synthetic MHBS. The results are validated against those obtained from previous mechanical models for MHBS that examine the same experimental data. The Hydrate-CASM performs similarly to previous models, but its formulation only requires one hydrate-related empirical parameter to express changes in the sediment elastic stiffness with hydrate saturation.     

Performance of the Nuclear Compton Telescope

On 1 June 2005, the prototype Nuclear Compton Telescope (NCT) flew on a high altitude balloon from Fort Sumner, New Mexico. NCT is a balloon-borne soft γ-ray (0.2–10 MeV) telescope for studying astrophysical sources of nuclear line emission and γ-ray polarization. Our program is designed to develop and test technologies and analysis techniques crucial for the Advanced Compton Telescope; however, our detector design and configuration is also well matched to the focal plane requirements for focusing Laue lenses. The NCT prototype utilizes two, 3D imaging germanium detectors (GeDs) in a novel, ultra-compact design optimized for nuclear line emission in the 0.5–2 MeV range. Our prototype flight provides a critical test of the novel detector technologies, analysis techniques, and background rejection procedures developed for high resolution Compton telescopes.     

Likelihood analysis of repeating in the BATSE catalogue

I describe a new likelihood technique, based on counts-in-cells statistics, that I use to analyze repeating in the BATSE 1B and 2B catalogues. Using the 1B data, I find that repeating is preferred over non-repeating by 4.3:1 odds, with a peak at 5–6 repetitions per source. I find that the post-1B data are consistent with the repeating model inferred from the 1B data, after taking into account the lower fraction of bursts with well-determined positions. Combining the two data sets, I find that the odds favoring repeating over non-repeating are almost unaffected at 4:1, with a narrower peak at 5 repetitions per source. I conclude that the data sets are consistent both with each other and with repeating, and that for these data sets the odds favor repeating. Compton GRO Fellow - NASA grant GRO/PDP 93-08.