Isotopic,trace element and nutrient characterization of coastal waters from Ubatuba inner shelf area,south-eastern Brazil

Stable isotopes, tritium, radium isotopes, radon, trace elements and nutrients data were collected during two sampling campaigns in the Ubatuba coastal area (south-eastern Brazil) with the aim of investigating submarine groundwater discharge (SGD) in the region. The isotopic composition (δD, δ¹⁸O, ³H) of submarine waters was characterised by significant variability and heavy isotope enrichment. The stable isotopes and tritium data showed good separation of groundwater and seawater groups. The contribution of groundwater in submarine waters varied from a few % to 17%. Spatial distribution of ²²²Rn activity concentration in surface seawater revealed changes between 50 and 200 Bq m⁻³ which were in opposite relationship with observed salinities. Time series measurements of ²²²Rn activity concentration in Flamengo Bay (from 1 to 5 kBq m⁻³), obtained by in situ underwater gamma-spectrometry showed a negative correlation between the ²²²Rn activity concentration and tide/salinity. This may be caused by sea level changes as tide effects induce variations of hydraulic gradients, which increase ²²²Rn concentration during lower sea level, and opposite, during high tides where the ²²²Rn activity concentration is smaller. The estimated SGD fluxes varied during 22–26 November between 8 and 40 cm d⁻¹, with an average value of 21 cm d⁻¹ (the unit is cm³/cm² per day). The radium isotopes and nutrient data showed scattered distributions with offshore distance and salinity, which implies that in a complex coast with many small bays and islands, the area has been influenced by local currents and groundwater–seawater mixing. SGD in the Ubatuba area is fed by coastal contaminated groundwater and re-circulated seawater (with small admixtures of groundwater), which claims for potential environmental concern with implications on the management of freshwater resources in the region.     

Oxygen compounds in Titan's stratosphere as observed by Cassini CIRS

We have investigated the abundances of Titan's stratospheric oxygen compounds using 0.5 cm⁻¹ resolution spectra from the Composite Infrared Spectrometer on the Cassini orbiter. The CO abundance was derived for several observations of far-infrared nadir spectra, taken at a range of latitudes (75° S-35° N) and emission angles (0°-60°), using rotational lines that have not been analysed before the arrival of Cassini at Saturn. The derived volume mixing ratios for the different observations are mutually consistent regardless of latitude. The weighted mean CO volume mixing ratio is 47±8 ppm if CO is assumed to be uniform with latitude. H₂O could not be detected and an upper limit of 0.9 ppb was determined. CO₂ abundances derived from mid-infrared nadir spectra show no significant latitudinal variations, with typical values of 16±2 ppb. Mid-infrared limb spectra at 55° S were used to constrain the vertical profile of CO₂ for the first time. A vertical CO₂ profile that is constant above the condensation level at a volume mixing ratio of 15 ppb reproduces the limb spectra very well below 200 km. This is consistent with the long chemical lifetime of CO₂ in Titan's stratosphere. Above 200 km the CO₂ volume mixing ratio is not well constrained and an increase with altitude cannot be ruled out there.     

Old, Low-Mass, Metal-Rich (SMR) Stars

The authors of this paper try to disentangle the many problems arisen from a new enlarged sample of nearby low-mass,metal-rich-stars. These stars have reliable absolute magnitudes, deduced from Hipparcos parallaxes, precise bolometric corrections, effective temperatures and metal abundances from high resolution detailed spectroscopic analyses. Their ages have been derived from a grid of isochrones calculated with up to date physics. The main goal of this paper is to determine the ages of the slightly evolved SMR stars. Among those with well determinated ages about 80% of them have intermediate ages of (2 to 5 Gyr), but only 20% have ages of 8 Gyr or more. Nevertheless, the existence of very old metal-rich stars is confirmed. This revised version was published online in July 2006 with corrections to the Cover Date.     

Topodata: Brazilian full coverage refinement of SRTM data

This work presents the selection of a set of geostatistical coefficients suitable for a unified SRTM data refinement from 3″ to 1″ through kriging over the entire Brazilian territory. This selection aimed at data potential for geomorphometric derivations, given by the preservation of detailed geometric characteristics of the resulting digital elevation models (DEM), which are sensitive to refining procedures. The development contained a long-term experimentation stage, when data refinement through kriging was locally developed to support distinct regional projects, followed by a unified selection stage, where the acquired experience was applied to select a single and unified interpolation scheme. In this stage, the selected geostatistical models with promising performances were tested for unified refinement on 40 Brazilian areas with distinct geological settings. Tested areas encompass reliefs varying from mountainous to plain. The effects of data preparation were observed on the perception of patterns (texture and roughness), as well as of singularities (edges, peaks, thalwegs etc.). Results were evaluated mainly through the examination of shaded reliefs, transects and perspectives observed in different scales. Terrains with low slopes and small amplitudes had their DEM promptly affected by the refining methods, as opposed to mountainous terrains. The evaluation, unambiguously confirmed by all consulted interpreters, converged into a refining model with outstanding performance in all tested conditions.     

Inversion of time-dependent nuclear well-logging data using neural networks

The purpose of this work was to investigate a new and fast inversion methodology for the prediction of subsurface formation properties such as porosity, salinity and oil saturation, using time‐dependent nuclear well logging data. Although the ultimate aim is to apply the technique to real‐field data, an initial investigation as described in this paper, was first required; this has been carried out using simulation results from the time‐dependent radiation transport problem within a borehole. Simulated neutron and γ‐ray fluxes at two sodium iodide (NaI) detectors, one near and one far from a pulsed neutron source emitting at ～14 MeV, were used for the investigation. A total of 67 energy groups from the BUGLE96 cross section library together with 567 property combinations were employed for the original flux response generation, achieved by solving numerically the time‐dependent Boltzmann radiation transport equation in its even parity form. Material property combinations (scenarios) and their correspondent teaching outputs (flux response at detectors) are used to train the Artificial Neural Networks (ANNs) and test data is used to assess the accuracy of the ANNs. The trained networks are then used to produce a surrogate model of the expensive, in terms of computational time and resources, forward model with which a simple inversion method is applied to calculate material properties from the time evolution of flux responses at the two detectors. The inversion technique uses a fast surrogate model comprising 8026 artificial neural networks, which consist of an input layer with three input units (neurons) for porosity, salinity and oil saturation; and two hidden layers and one output neuron representing the scalar photon or neutron flux prediction at the detector. This is the first time this technique has been applied to invert pulsed neutron logging tool information and the results produced are very promising. The next step in the procedure is to apply the methodology to real data.     

Dynamical studies of cluster pairs in the Magellanic Clouds

We performed N -body simulations of star cluster encounters with Hernquist's TREECODE in a CRAY YMP-2E computer under different initial conditions (relative positions and velocities, cluster sizes, masses and concentration degrees). The total number of particles per simulation ranged from 1024 to 20480. These models are compared with a series of isodensity maps of cluster pairs in the Magellanic Clouds. Evidence is found that during the interactions, transient morphological effects such as an expanded halo, isophotal deformation and isophotal twisting can occur as a result of tidal effects and dynamical friction. The simulations also show that different outcomes are possible depending on the initial parameters: (i) long-standing changes of concentration degree can occur after the collision; (ii) one member can disaggregate; or (iii) the pair can coalesce into a single cluster with a distinct structure compared with the original ones. These simulations can reproduce a wide range of morphological structures in observed cluster pairs.     

A general correspondence principle for time-domain electromagnetic wave and diffusion fields

A general correspondence principle is presented that relates any time-domain electromagnetic diffusion field to an electromagnetic wavefield in a 'corresponding' configuration. The principle applies to arbitrarily inhomogeneous and anisotropic media and arbitrary transmitters and receivers. For the correspondence between the two types of electromagnetic fields to hold, the electric conductivity in the diffusive case and the permittivity in the wavefield case should have the same spatial variation, while the permeability distributions in space in the two cases are to be identical. Essential steps in the derivation of the correspondence principle are the use of the time Laplace transformation of causal signals, taken at real, positive values of the transform parameter, the Schouten-Van der Pol theorem in the theory of the Laplace transformation, and the reliance upon Lerch's theorem of the uniqueness of the interrelation between causal field quantities and their time-Laplace-transform representations at real, positive values of the transform parameter. Correspondence is then established between the tensorial Green's functions in the two cases, where the Green's functions are the point-receiver responses (either electric or magnetic field) to point-transmitter excitations (either electric- or magnetic-current source).
Through the correspondence principle, all transient electromagnetic wavefields (where losses are neglected) have as a counterpart a transient diffusive electromagnetic field (where the electric displacement current is neglected). The interrelation yields the tool to compare quantitatively the potentialities of the two types of fields in transient electromagnetic geophysical prospecting.
Finally, a general medium-parameter scaling law for time-domain electromagnetic wavefields is presented.     

Arctic freshwater ostracods from modern periglacial environments in the Lena River Delta (Siberian Arctic,Russia): geochemical applications for palaeoenvironmental reconstructions

The aim of this study is to describe ostracods from freshwater habitats in the Siberian Arctic in order to estimate the present-day relationships between the environmental setting and the geochemical properties of ostracod calcite. A special focus is on the element ratios (Mg/Ca, Sr/Ca), and the stable isotope composition (δ¹⁸O, δ¹³C), in both ambient waters and ostracod calcite. The most common species are Fabaeformiscandona pedata and F. harmsworthi with the highest frequency in all studied waters. Average partition coefficients D(Sr) of F. pedata are 0.33 ± 0.06 (1σ) in females, and 0.32 ± 0.06 (1σ) in males. A near 1:1 relationship of δ¹⁸O was found, with a mean shift of Δ_mean = 2.2‰ ± 0.5 (1σ) to heavier values in ostracod calcite of F. pedata as compared to ambient waters. The shift is not dependent on δ¹⁸O_water, and is caused by metabolic (vital) and temperature effects. Temperature-dependence is reflected in the variations of this shift. For ostracod calcite of F. pedata a vital effect as compared to inorganic calcite in equilibrium was quantified with 1.4‰. Results of this study are valuable for the palaeoenvironmental interpretation of geochemical data of fossil ostracods from permafrost deposits.