Photosynthetic fractionation of 13C and concentrations of dissolved CO2 in the central equatorial Pacific during the last 255,000 years

Carbon isotopically based estimates of CO2 levels have been generated from a record of the photosynthetic fractionation of 13C [is equivalent to epsilon(p)] in a central equatorial Pacific sediment core that spans the last approximately 255 ka. Contents of 13C in phytoplanktonic biomass were determined by analysis of C37 alkadienones. These compounds are exclusive products of Prymnesiophyte algae which at present grow most abundantly at depths of 70-90 m in the central equatorial Pacific. A record of the isotopic composition of dissolved CO2 was constructed from isotopic analyses of the planktonic foraminifera Neogloboquadrina dutertrei, which calcifies at 70-90 m in the same region. Values of epsilon(p), derived by comparison of the organic and inorganic delta values, were transformed to yield concentrations of dissolved CO2 [is equivalent to c(e)] based on a new, site-specific calibration of the relationship between epsilon(p) and c(e). The calibration was based on reassessment of existing epsilon(p) versus c(e) data, which support a physiologically based model in which epsilon(p) is inversely related to c(e). Values of PCO2, the partial pressure of CO2 that would be in equilibrium with the estimated concentrations of dissolved CO2, were calculated using Henry's law and the temperature determined from the alkenone-unsaturation index U(K/37). Uncertainties in these values arise mainly from uncertainties about the appropriateness (particularly over time) of the site-specific relationship between epsilon(p) and 1/c(e). These are discussed in detail and it is concluded that the observed record of epsilon(p) most probably reflects significant variations in delta pCO2, the ocean-atmosphere disequilibrium, which appears to have ranged from approximately 110 microatmospheres during glacial intervals (ocean > atmosphere) to approximately 60 microatmospheres during interglacials. Fluxes of CO2 to the atmosphere would thus have been significantly larger during glacial intervals. If this were characteristic of large areas of the equatorial Pacific, then greater glacial sinks for the equatorially evaded CO2 must have existed elsewhere. Statistical analysis of air-sea pCO2 differences and other parameters revealed significant (p<0.01) inverse correlations of delta pCO2 with sea surface temperature and with the mass accumulation rate of opal. The former suggests response to the strength of upwelling, the latter may indicate either drawdown of CO2 by siliceous phytoplankton or variation of [CO2]/[Si(OH)4] ratios in upwelling waters.     

Controls on the tectono-magmatic evolution of a volcanic transform margin: the Vøring Transform Margin,NE Atlantic

Ocean bottom seismograph (OBS), multichannel seismic and potential field data reveal the structure of the Vøring Transform Margin (VTM). This transform margin is located at the landward extension of the Jan Mayen Fracture Zone along the southern edge of the Vøring Plateau. The margin consists of two distinctive segments. The northwestern segment is characterized by large amounts of volcanic material. The new OBS data reveal a 30–40 km wide and 17 km thick high-velocity body between underplated continental crust to the northeast and normal oceanic crust in the southwest. The southeastern segment of the mar is similar to transform margins elsewhere. It is characterized by a 20–30 km wide transform margin high and a narrow continent-ocean transition. The volcanic sequences along this margin segment are less than 1 km thick. We conclude from the spatial correspondence of decreased volcanism and the location of the fracture zone, that the amount of volcanism was influenced by the tectonic setting. We propose that (1) lateral heat transport from the oceanic lithosphere to the adjacent continental lithosphere decreased the ambient mantle temperature and melt production along the entire transform margin and (2) that right-stepping of the left-lateral shear zone at the northwestern margin segment caused lithospheric thinning and increased volcanism. The investigated data show no evidence that the breakup volcanism influenced the tectonic development of the southeastern VTM.     

Vulnerability of a public supply well in a karstic aquifer to contamination

To assess the vulnerability of ground water to contamination in the karstic Upper Floridan aquifer (UFA), age-dating tracers and selected anthropogenic and naturally occurring compounds were analyzed in multiple water samples from a public supply well (PSW) near Tampa, Florida. Samples also were collected from 28 monitoring wells in the UFA and the overlying surficial aquifer system (SAS) and intermediate confining unit located within the contributing recharge area to the PSW. Age tracer and geochemical data from the earlier stage of the study (2003 through 2005) were combined with new data (2006) on concentrations of sulfur hexafluoride (SF₆), tritium (³H), and helium-3, which were consistent with binary mixtures of water for the PSW dominated by young water (less than 7 years). Water samples from the SAS also indicated mostly young water (less than 7 years); however, most water samples from monitoring wells in the UFA had lower SF₆ and ³H concentrations than the PSW and SAS, indicating mixtures containing high proportions of older water (more than 60 years). Vulnerability of the PSW to contamination was indicated by predominantly young water and elevated nitrate-N and volatile organic compound concentrations that were similar to those in the SAS. Elevated arsenic (As) concentrations (3 to 19 μg/L) and higher As(V)/As(III) ratios in the PSW than in water from UFA monitoring wells indicate that oxic water from the SAS likely mobilizes As from pyrite in the UFA matrix. Young water found in the PSW also was present in UFA monitoring wells that tap a highly transmissive zone (43- to 53-m depth) in the UFA.     

New fjords,new coasts,new landscapes: The geomorphology of paraglacial coasts formed after recent glacier retreat in Brepollen (Hornsund,southern Svalbard)

Changes in the properties and dynamics of tidewater glacier systems are key indicators of the state of Arctic climate and environment. Calving of tidewater glacier fronts is currently the dominant form of ice mass loss and a major contributor to global sea-level rise. An important yet under-studied aspect of this process is transformation of Arctic landscapes, where new lands and coastal systems are revealed due to the recession of marine-terminating ice masses. The evolution of those freshly exposed paraglacial coastal environments is controlled by nearshore marine, coastal and terrestrial geomorphic processes, which rework glacial-derived sediments to create new coastal paraglacial landforms and landscapes. Here, we present the first study of the paraglacial coasts of Brepollen, one of the youngest bays of Svalbard revealed by ice retreat. We describe and classify coastal systems and the variety of landforms (deltas, cliffs, tidal flats, beaches) developed along the shores of Brepollen during the last 100 years. We further discuss the main modes of sediment supply to the coast in different parts of the new bay, highlighting the fast rate of coastal transformation as a paraglacial response to rapid deglaciation in the Arctic. This study provides an exemplar of likely coastal responses to be anticipated in similar tidewater settings under future climate change. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd     

Responses of humpback whales to a changing climate in the Southern Hemisphere: Priorities for research efforts

Globally, baleen whales were severely depleted by historic whaling. Recovering populations have been observed to alter their behaviour. These changes have been attributed to climate change in some cases and raise concerns over the successful recovery of baleen whale populations. Current data-driven statistical habitat and behavioural models have proven useful for addressing questions of whale distribution changes within their limitations. Given observed changes in oceanic conditions, a new approach to managing baleen whale population recovery is necessary. Model predictions of future whale movements and distributions under climate change scenarios are vital to enable adequate conservation management. This paper presents a new perspective on understanding the impacts of climate change on humpback whales, arguing the need for a system-based multidisciplinary research approach. Our approach includes coupled, mechanistic models based upon robust ecological principles, and integrates key physical, biogeochemical, biological and ecological modules to address long-term changes associated with climate change. To illustrate the need for this system-based multidisciplinary approach, we focus on Southern Hemisphere humpback whales, the recovery of which may be impacted by rapid changes in habitat conditions brought about by anthropogenic climate change.     

Nano‐Powdered Calcium Carbonate Reference Materials: Significant Progress for Microanalysis?

Homogeneity, mass fractions of about forty trace elements and Sr isotope composition of Ca carbonate reference materials (RMs) between original and nano‐powdered pellets are compared. Our results using nanosecond and femtosecond LA‐(MC)‐ICP‐MS show that the nano‐pellets of the RMs MACS‐3NP, JCp‐1NP and JCt‐1NP are about a factor of 2–3 more homogeneous than the original samples MACS‐3, JCp‐1 and JCt‐1, and are therefore much more suitable for microanalytical purposes. With the exception of Si, the mass fractions of the synthetic RM MACS‐3 agree with its fine‐grained analogue MACS‐3NP. Very small, but significant, differences between original and nano‐pellets are observed in the RMs JCp‐1 and JCt‐1 for some trace elements with very low contents, indicating the need for re‐certification. Strontium mass fractions in the analysed RMs are high (1500–7000 mg kg^?1), and their isotope compositions determined by LA‐MC‐ICP‐MS in the original and the nano‐pellets agree within uncertainty limits.     

Turbidite stratigraphy in proglacial lakes: Deciphering trigger mechanisms using a statistical approach

Turbidites embedded in lacustrine sediment sequences are commonly used to reconstruct regional flood or earthquake histories. A critical step for this method to be successful is that turbidites and their trigger mechanisms are determined unambiguously. The latter is particularly challenging for prehistoric proglacial lake records in high-seismicity settings where both earthquake-generated and flood-generated turbidites interrupt the background varved sedimentation. This calls for a new method to allow efficient and objective identification and classification of turbidites. This study examined turbidites in five long (9 to 17 m) sediment cores from Eklutna Lake, a proglacial lake in south-central Alaska, using standard core logging and grain-size data. A novel statistical approach is presented, in which varve-thickness distributions were first analyzed to objectively identify the thickest turbidites and distinguish them from background sedimentation. For each turbidite, a selection of variables were then measured, including: basal grain-size, thickness, magnetic susceptibility and spectrophotometric variables. Triggering mechanisms were discriminated by a combination of principal component analysis and clustering, and by calibration with historical events. Using this approach, a 2250 year long lake-wide event stratigraphy was constructed, with 94 prehistoric events, including 24 earthquake and 70 flood events. Basal grain-size and thickness variables turn out to be the most effective proxies for discrimination. This statistical approach is a powerful and new method to identify turbidites and their triggering mechanisms in long prehistoric sediment records. It opens up new prospects for palaeoseismological, palaeohydrological and palaeoclimate studies in proglacial lakes worldwide.