A wave model for the Great Barrier Reef

A new wind wave generation model, WAMGBR, is presented that has been adapted from WAM especially for use in the complex geometry of the Great Barrier Reef. A technique (reef parameterization) has been presented that incorporates sub-grid scale dissipation caused by coral reefs. Three other improvements to WAM have been proposed. An explicit/implicit finite difference scheme has been implemented that allows for more efficient modelling (longer time steps) while maintaining diffusive characteristics that are at least as good as those of WAM. An offset in discrete angles creates more uniform diffusive characteristics. And, a transformed spherical coordinate system allows for more efficient grid sizes and smaller grid dependent refraction. Comparisons between modelling techniques and between model and measured data show that WAMGBR produces very good results in the difficult challenge of modelling both non-cyclonic and tropical cyclone waves in the geographically complex environment of the Great Barrier Reef.     

Kimberlites: Their relation to mantle hotspots

Available age data support the hypothesis that kimberlite intrusions are formed by mantle hotspots. The hypothesis has been tested by inverting the volcanic traces formed by three hotspots to determine the post-Triassic motions of Africa, South America, and North America relative to these hotspots. Then, using these motions, the kimberlites intruded on these continents within the last 150 m.y. are relocated to their place of origin in the present hotspot reference frame. The result indicates that a majority of the kimberlites formed within 5° of a mantle hotspot. Statistical analysis shows that this kimberlite/hotspot correlation is significant at above the 90% level.     

The variability of the large-amplitude internal wave field on the Australian North West Shelf

Observations are presented of large-amplitude internal waves (LAIWs) generated by the steepening of the internal tide on the Australian North West Shelf (NWS) over a 4-month period extending from strongly stratified summer conditions to weakly stratified winter conditions. The observations are from a site in water depth of 124 m where current and temperature measurements were made from a fixed vertical mooring and a benthic L-shaped spatial array. The observations show the LAIWs at this site to be characterized by strong seasonal variability, with energetic LAIWs of depression being dominant during summer and weaker LAIWs of elevation being dominant during the winter months as the stratification weakens, the upper mixed layer deepens, and the thermocline is close to the bottom. Waves were also seen to propagate from a range of directions towards the observation site. Modeling using the Regional Ocean Modeling System (ROMS v2.1) revealed that internal tide generation in the area occurred at water depths of between 400 and 600 m along an arc of approximately 120 km in length, some 70 km to the northwest of our experimental site. The results demonstrate both the 3D nature as well as the seasonal variation of the LAIW field.     

Molecular distribution, 13C‐isotope,and enantiomeric compositions of carbonaceous chondrite monocarboxylic acids

The water‐soluble organic compounds in carbonaceous chondrite meteorites constitute a record of the synthetic reactions occurring at the birth of the solar system and those taking place during parent body alteration and may have been important for the later origins and development of life on Earth. In this present work, we have developed a novel methodology for the simultaneous analysis of the molecular distribution, compound‐specific δ¹³C, and enantiomeric compositions of aliphatic monocarboxylic acids (MCA) extracted from the hot‐water extracts of 16 carbonaceous chondrites from CM, CR, CO, CV, and CK groups. We observed high concentrations of meteoritic MCAs, with total carbon weight percentages which in some cases approached those of carbonates and insoluble organic matter. Moreover, we found that the concentration of MCAs in CR chondrites is higher than in the other meteorite groups, with acetic acid exhibiting the highest concentration in all samples. The abundance of MCAs decreased with increasing molecular weight and with increasing aqueous and/or thermal alteration experienced by the meteorite sample. The δ¹³C isotopic values of MCAs ranged from ?52 to +27‰, and aside from an inverse relationship between δ¹³C value and carbon straight‐chain length for C₃–C₆ MCAs in Murchison, the ¹³C‐isotopic values did not correlate with the number of carbon atoms per molecule. We also observed racemic compositions of 2‐methylbutanoic acid in CM and CR chondrites. We used this novel analytical protocol and collective data to shed new light on the prebiotic origins of chondritic MCAs.     

The amino acid composition of the Sutter's Mill CM2 carbonaceous chondrite

We determined the abundances and enantiomeric compositions of amino acids in Sutter's Mill fragment #2 (designated SM2) recovered prior to heavy rains that fell April 25–26, 2012, and two other meteorite fragments, SM12 and SM51, that were recovered postrain. We also determined the abundance, enantiomeric, and isotopic compositions of amino acids in soil from the recovery site of fragment SM51. The three meteorite stones experienced terrestrial amino acid contamination, as evidenced by the low d/l ratios of several proteinogenic amino acids. The d/l ratios were higher in SM2 than in SM12 and SM51, consistent with rain introducing additional l‐ amino acid contaminants to SM12 and SM51. Higher percentages of glycine, β‐alanine, and γ‐amino‐n‐butyric acid were observed in free form in SM2 and SM51 compared with the soil, suggesting that these free amino acids may be indigenous. Trace levels of d +l‐ β‐aminoisobutyric acid (β‐AIB) observed in all three meteorites are not easily explained as terrestrial contamination, as β‐AIB is rare on Earth and was not detected in the soil. Bulk carbon and nitrogen and isotopic ratios of the SM samples and the soil also indicate terrestrial contamination, as does compound‐specific isotopic analysis of the amino acids in the soil. The amino acid abundances in SM2, the most pristine SM meteorite analyzed here, are approximately 20‐fold lower than in the Murchison CM2 carbonaceous chondrite. This may be due to thermal metamorphism in the Sutter's Mill parent body at temperatures greater than observed for other aqueously altered CM2 meteorites.     

An investigation of sand–dust storm events and land surface characteristics in China using NOAA NDVI data

Observations from 560 weather stations in China show that sand–dust storms occur most frequently in April in north China. The region consists of Sub-dry Mid Temperate, Dry Mid Temperate, Sub-dry South Temperate and Dry South Temperate Zones and much of the land surface is desert or semi-desert: it is relatively dry with minimal rainfall and a high annual mean temperature. In most regions of China, the annual mean frequency of sand–dust events decreased sharply between 1980 and 1997 and then increased from 1997 to 2000. Statistical analyses demonstrate that the frequency of sand–dust storms correlates highly with wind speed, which in turn is strongly related to land surface features; on the other hand, a significant correlation between storm events and other atmospheric quantities such as precipitation and temperature was not observed. Accordingly, land surface cover characteristics (vegetation, snowfall and soil texture) may play a significant role in determining the occurrence of sand–dust storms in China. Analysis of Normalized Difference Vegetation Index derived from National Oceanic and Atmospheric Administration and Empirical Orthogonal Function show that since 1995 surface vegetation cover in large areas of Northern China has significantly deteriorated. Moreover, a high correlation is shown to exist among the annual occurrence of sand–dust storms, surface vegetation cover and snowfall. This suggests that the deterioration of surface vegetation cover may strongly influence the occurrence of sand–dust storms in China. Soils with coarse and medium textures are found to be more associated with sand–dust storms than other soils.     

Lunar atmospheric H2 detections by the LAMP UV spectrograph on the Lunar Reconnaissance Orbiter

We report on the detection of H₂ as seen in our analysis of twilight observations of the lunar atmosphere observed by the LAMP instrument aboard NASA’s Lunar Reconnaissance Orbiter. Using a large amount of data collected on the lunar atmosphere between September 2009 and March 2013, we have detected and identified, the presence of H₂ in the native lunar atmosphere, for the first time. We derive a surface density for H₂ of 1.2 ± 0.4 × 10³ cm⁻³ at 120 K. This is about 10 times smaller than originally predicted, and several times smaller than previous upper limits from the Apollo era data.     

Composition and petrology of HED polymict breccias: The regolith of (4) Vesta

We have done petrologic and compositional studies on a suite of polymict eucrites and howardites to better understand regolith processes on their parent asteroid, which we accept is (4) Vesta. Taking into account noble gas results from companion studies, we interpret five howardites to represent breccias assembled from the true regolith: Elephant Moraine (EET) 87513, Grosvenor Mountains (GRO) 95535, GRO 95602, Lewis Cliff (LEW) 85313, and Meteorite Hills (MET) 00423. We suggest that EET 87503 is paired with EET 87513, and thus is also regolithic. Pecora Escarpment (PCA) 02066 is dominated by melt‐matrix clasts, which may have been formed from true regolith by impact melting. These meteorites display a range in eucrite:diogenite mixing ratio from 55:45 to 76:24. There is no correlation between degree of regolith character and Ni content. The Ni contents of howardite, eucrite, and diogenites (HEDs) are mostly controlled by the distribution of coarse chondritic clasts and metal grains, which in some cases resulted from individual, low‐velocity accretion events, rather than extensive regolith gardening. Trace element compositions indicate that the mafic component of HED polymict breccias is mostly basalt similar to main‐group eucrites; Stannern‐trend basaltic debris is less common. Pyroxene compositions show that some trace element‐rich howardites contain abundant debris from evolved basalts, and that cumulate gabbro debris is present in some breccias. The scale of heterogeneity varies considerably; regolithic howardite EET 87513 is more homogeneous than fragmental howardite Queen Alexandra Range (QUE) 97001. Individual samples of a given howardite can have different compositions even at roughly 5 g masses, indicating that obtaining representative meteorite compositions requires multiple or large samples.