Permselective Membrane Fouling During Azo Dye Wastewater Treatment

A Na‐montmorillonite membrane wastewater renovation prototype system was developed to specifically treat an ionic azo dye. Efficiency of this prototype system was limited to membrane fouling. Fouling rates were not consistently uniform owing to steric effects and competition for exchange sites. The decrease in solute rejection with time can be attributed to the decrease in the relative permeability of the compacted Na‐montmorillonite membrane to the dye with time due to fouling. This decrease occurs probably as a two‐step nucleation–growth mechanism with the nucleation part dependent in part on solvent flux, number of nucleation sites on the membrane, and sorbed mass part that controls solute flux and organic polymerization. The effect of concentration polarization was significant since the flux was higher than the mass‐transfer coefficient. The low diffusion coefficient of the ionic azo dye resulted in low mass transfer coefficients. The most important macromolecular solution properties to be considered for pilot systems may include high concentration‐dependent viscosity, possible non‐Newtonian fluid behavior, and low and concentration‐dependent self‐diffusivity amongst other factors. For pilot systems, the greater the quantity of large macromolecules in the ambient water, the greater the necessity of reducing the permselectivity of the membrane to prevent significant polarization.     

Three‐dimensional architecture and hydrostratigraphy of cross‐cutting buried valleys using airborne electromagnetics,glaciated Central Lowlands,Nebraska, USA

Buried valleys are characteristic features of glaciated landscapes, and their deposits host important aquifers worldwide. Understanding the stratigraphic architecture of these deposits is essential for protecting groundwater and interpreting sedimentary processes in subglacial and ice‐marginal environments. The relationships between depositional architecture, topography and hydrostratigraphy in dissected, pre‐Illinoian till sheets is poorly understood. Boreholes alone are inadequate to characterize the complex geology of buried valleys, but airborne electromagnetic surveys have proven useful for this purpose. A key question is whether the sedimentary architecture of buried valleys can be interpreted from airborne electromagnetic profiles. This study employs airborne electromagnetic resistivity profiles to interpret the three‐dimensional sedimentary architecture of cross‐cutting buried valleys in a ca 400 km² area along the western margin of Laurentide glaciation in North America. A progenitor bedrock valley is succeeded by at least five generations of tunnel valleys that become progressively younger northward. Tunnel‐valley infills are highly variable, reflecting under‐filled and over‐filled conditions. Under‐filled tunnel valleys are expressed on the modern landscape and contain fine sediments that act as hydraulic barriers. Over‐filled tunnel valleys are not recognized in the modern landscape, but where they are present they form hydraulic windows between deep aquifer units and the land surface. The interpretation of tunnel‐valley genesis herein provides evidence of the relationships between depositional processes and glacial landforms in a dissected, pre‐Illinoian till sheet, and contributes to the understanding of the complex physical hydrology of glacial aquifers in general.     

Rocket observation of atomic oxygen and night airglow: Measurement of concentration with an improved resonance fluorescence technique

An improved resonant fluorescence instrument for measuring atomic oxygen concentration was developed to avoid the Doppler effect and the aerodynamic shock effect due to the supersonic motion of a rocket. The shock effect is reduced by adopting a sharp wedge-shaped housing and by scanning of the detector field of view to change the distance between the scattering volume and the surface of the housing. The scanning enables us to determine absolute values of atomic oxygen concentration from relative variation of the scattered light signal due to the self-absorption. The instrument was calibrated in the laboratory, and the numerical simulation reproduced the calibration result. Using the instrument, the altitude profile of atomic oxygen concentration was observed by a rocket experiment at Uchinoura (31°N) on 28 January 1992. The data obtained from the rocket experiment were not perfectly free from the shock effect, but errors due to the effect were reduced by the data analysis procedure. The observed maximum concentration was 3.8× 10¹¹ cm⁻³ at altitudes around 94 km. The systematic error is estimated to be less than ±0.7×10¹¹ cm⁻³ and the relative random error is less than±0.07× 10¹¹ cm⁻³at the same altitudes. The altitude profile of the OI 557.7-nm airglow was also observed in the same rocket experiment. The maximum volume emission rate was found to be 150 photons cm⁻³ s⁻¹ at 94 km. The observed altitude profiles are compared with the MSIS model and other in situ observations.     

Petrology,geochronology,and geophysical characterization of Mesoproterozoic rocks in central Illinois,USA

The Precambrian basement rocks of the Eastern Granite-Rhyolite Province(EGRP)in central Illinois(midcontinent region of North America)exhibit a complex history of early volcanism,granite emplacement,and intrusion of mafic rocks.A comprehensive suite of dedicated petrographic analyses,geophysical logs,and drill core from four basement-penetrating wells,two-dimensional and three-dimensional seismic reflection data,and U-Pb age data from the Illinois Basin–Decatur Project(IBDP)and Illinois Carbon Capture Storage(ICCS)Project site provide new constraints for interpreting the Precambrian basement of the Illinois Basin.These new data reveal the basement to be compositionally and structurally complex,having typical EGRP felsic volcanic rocks intruded by the first reported gabbro in the Precambrian basement in Illinois.Zircons(n?29)from rhyolite give a U-Pb weighted mean average age of 14679 Ma.Zircons(n?3)from a gabbro dike that intrudes the rhyolite yield a concordia age of 107312 Ma,which corresponds to Grenville-age extension and represents the first Grenville-age rock in Illinois and in the EGRP.A high-resolution three-dimensional seismic reflection volume,coincident with the four wells,provides a context for interpreting the petrological data and implies a high degree of heterogeneity for basement rocks at the IBDP–ICCS site,as also shown by the drill cores.The occurrence of Grenville-age gabbro is related to a prominent bowl-like structure observed on local two-dimensional seismic reflection profiles and the three-dimensional volume that is interpreted as a deep-seated mafic sill complex.Furthermore,heterogeneities such as the brecciated EGRP rhyolite and later gabbro intrusion observed in the basement lithology at the IBDP–ICCS may reflect previously unknown distal elements of the 1.1 Ga Midcontinent Rift in the EGRP and more likely Grenville-age extension.     

Formation of subantarctic mode water in the southeastern Indian Ocean

Subantarctic Mode Water (SAMW) is the name given to the relatively deep surface mixed layers found directly north of the Subantarctic Front in the Southern Ocean, and their extension into the thermocline as weakly stratified or low potential vorticity water masses. The objective of this study is to begin an investigation into the mechanisms controlling SAMW formation, through a heat budget calculation. ARGO profiling floats provide estimates of temperature and salinity typically in the upper 2,000 m and the horizontal velocity at various parking depths. These data are used to estimate terms in the mode water heat budget; in addition, mode water circulation is determined with ARGO data and earlier ALACE float data, and climatological hydrography. We find a rapid transition to thicker layers in the central South Indian Ocean, at about 70°S, associated with a reversal of the horizontal eddy heat diffusion in the surface layer and the meridional expansion of the ACC as it rounds the Kerguelen Plateau. These effects are ultimately related to the bathymetry of the region, leading to the seat of formation in the region southwest of Australia. Upstream of this region, the dominant terms in the heat budget are the air–sea flux, eddy diffusion, and Ekman heat transport, all having approximately equal importance. Within the formation area, the Ekman contribution dominates and leads to a downstream evolution of mode water properties.     

Bias in GRACE estimates of ice mass change due to accompanying sea-level change

Observations of spatio-temporal variations in the geopotential using the GRACE satellites have been used to estimate recent mass fluxes from polar ice sheets and glaciers. However, these estimates have not considered the potential bias associated with the migration of water that accompanies the ice melt. This migration is driven by the diminished gravitational attraction of the melting ice reservoir, and this migration, as well as the crustal loading it induces, will contribute to the observed geopotential anomaly. The extent to which this contribution contaminates the ice mass flux estimates depends on how far the smoothing filters applied to the GRACE data extend beyond the ice margins into the ocean. Using the Antarctic Peninsula as a case study, we estimate the magnitude of this bias for a range of melt areas and Gaussian smoothing filter radii. We conclude that GRACE estimates of ice mass loss over the Antarctic Peninsula are systematically overestimating the loss by up to 10  $\%$ for filter radii of less than 500 km.     

Regional climate changes drive increased scaled-chrysophyte abundance in lakes downwind of Athabasca Oil Sands nitrogen emissions

Several limnological and paleolimnological investigations have linked enhanced atmospheric nitrogen (N) deposition to nutrient enrichment and increased primary production. The Athabasca Oil Sands Region (AOSR) in northeast Alberta, Canada is a significant source of N emissions, particularly since development intensified during the 1990s, and recent paleolimnological investigations provide evidence of increased lake production in adjacent areas subject to enhanced N deposition. The AOSR, however, has also experienced atmospheric warming since ca. AD 1900, and therefore the relative effects of nutrient deposition and climate changes on lake production remain unclear. We undertook a factorial-design paleolimnological assessment of 16 lakes in northwest Saskatchewan to quantify changes in abundance and species composition of scaled chrysophytes over the past 100 years. Study sites included both N-limited and P-limited lakes within control regions, as well as lakes that receive enhanced N deposition from the AOSR. We hypothesized that a change in algal communities within N-limited AOSR-impacted lakes, without concurrent changes in the other lake groups, would suggest AOSR-derived N as a driver of enhanced primary production. Instead, marked increases in concentrations of scaled chrysophytes, mainly Mallomonas crassisquama, occurred in the recent sediments in cores from all four lake groups (N-limited vs. P-limited, impacted vs. control), suggesting that regional climate change rather than N deposition was the paramount process enhancing chrysophyte production. Because chrysophyte abundances tended to be higher in deep, lower-pH lakes, and chrysophyte time series were fit best by lake-specific generalized additive models, we infer that climate effects may have been mediated by additional catchment and/or lake-specific processes.     

The eccentric frame decomposition of central force fields

The rosette-shaped motion of a particle in a central force field is known to be classically solvable by quadratures. We present a new approach of describing and characterizing such motion based on the eccentricity vector of the two body problem. In general, this vector is not an integral of motion. However, the orbital motion, when viewed from the nonuniformly rotating frame defined by the orientation of the eccentricity vector, can be solved analytically and will either be a closed periodic circulation or libration. The motion with respect to inertial space is then given by integrating the argument of periapsis with respect to time. Finally we will apply the decomposition to a modern central potential, the spherical Hernquist–Newton potential, which models dark matter halos of galaxies with central black holes.     

The Peerless structure,Daniels County,northeastern Montana: A probable late Ordovician impact structure

Abstract— The Peerless structure is an ?6 km‐diameter sub‐surface anomaly located in Daniels County, northeastern Montana. The disruption of sedimentary rock in the structure lies between 2624 to 2818 m below the topographic surface. Seismic mapping shows a typical complex crater composed of a central uplift ?2 km across, which shows structural uplift of up to 90 m, an annular ring ?4 km across, and an outer rim ?6 km in diameter. The youngest disrupted rock unit is the upper Ordovician Red River formation, which indicates that the structure was formed about 430–450 Ma ago.