Magma ascent rate and initial water concentration inferred from diffusive water loss from olivine-hosted melt inclusions

As the water concentration in magma decreases during magma ascent, olivine-hosted melt inclusions will reequilibrate with the host magma through hydrogen diffusion in olivine. Previous models showed that for a single spherical melt inclusion in the center of a spherical olivine, the rate of diffusive reequilibration depends on the partition coefficient and diffusivity of hydrogen in olivine, the radius of the melt inclusion, and the radius of the olivine. This process occurs within a few hours and must be considered when interpreting water concentration in olivine-hosted melt inclusions. A correlation is expected between water concentration and melt inclusion radius, because small melt inclusions are more rapidly reequilibrated than large ones when the other conditions are the same. This study investigates the effect of diffusive water loss in natural samples by exploring such a correlation between water concentration and melt inclusion radius, and shows that the correlation can be used to infer the initial water concentration and magma ascent rate. Raman and Fourier transform infrared spectroscopy measurements show that 31 melt inclusions (3.6–63.9 μm in radius) in six olivines from la Sommata, Vulcano Island, Aeolian Islands, have 0.93–5.28 wt% water, and the host glass has 0.17 wt% water. The water concentration in the melt inclusions shows larger variation than the data in previous studies (1.8–4.52 wt%). It correlates positively with the melt inclusion radius, but does not correlate with the major element concentrations in the melt inclusions, which is consistent with the hypothesis that the water concentration has been affected by diffusive water loss. In a simplified hypothetical scenario of magma ascent, the initial water concentration and magma ascent rate are inferred by numerical modeling of the diffusive water loss process. The melt inclusions in each olivine are assumed to have the same initial water concentration and magma ascent rate. The melt inclusions are assumed to be quenched after eruption (i.e., the diffusive water loss after eruption is not considered). The model results show that the melt inclusions initially had 3.9–5.9 wt% water and ascended at 0.002–0.021 MPa/s before eruption. The overall range of ascent rate is close to the lower limit of previous estimates on the ascent rate of basalts.     

对就地养老的反思——“人”与“地方”关系视角①

在有关养老的老年学和地理学研究中,“就地养老”是一个广泛使用的概念,并一直被认为是解决老龄人口养老需求的有效政策手段。迄今为止,关于就地养老的研究主要关注了很多能够让老年人健康就地(或在家)养老的物质方面的因素,比如住房条件或家庭照护。有些老年学研究者们认识到,就地养老受到居住环境中实体环境和社会、情感因素的共同影响。但我们认为,在养老体验研究中,要更加深入地审视“人”和“地方”之间的复杂关系。特别是,我们主张就地养老成功的因素是地方具有维持良好关系的潜力。提到“地方(place)”一词的时候,人们过分局限于关注老年人身体上接近的地理空间,或是具有实体边界的地方,例如房子或社区。而我们通过回顾现有文献发现,对许多选择就地养老的人来说,更具有意义的是随着时间的推移,他们在不同空间尺度上所建立起来的多元的、网络化的社会和非社会关系。基于这个新的视角,可以更好地理解老年人与地方的多层次的联系,以及从不同尺度和不同类型的人与地方的关系来考察就地养老的意义。     

First View of the Solar Core from Golf Acoustic Modes

After 8 months of nearly continuous measurements the GOLF instrument, aboard SOHO, has detected acoustic mode frequencies of more than 100 modes, extending from 1.4 mHz to 4.9 mHz. In this paper, we compare these results with the best available predictions coming from solar models. To verify the quality of the data, we examine the asymptotic seismic parameters; this confirms the improvements achieved in solar models during the last decade. Using the GOLF set of frequencies for l=0, 1, 2, 3 combined with the LOWL second year data set for l > 3 we then carry out inversions to infer properties of the solar core. This largely confirms the previous results down to around 0.1 R⊙, while there remain differences, even closer to the centre, where the present study shows an extreme sensitivity of the inversion results to the values of the frequencies. We finally consider physical processes which may influence directly or indirectly the solar core structure.     

Wind-driven ocean circulation transition to barotropic instability

This article deals with the ocean circulation driven by steady zonal winds, and damped by bottom and biharmonic friction, when represented by the simple barotropic vorticity equation. A double gyre antisymmetrical wind stress pattern in a square basin is considered. Wind forcing and dissipation parameters are chosen within the ranges of what has been used in previous studies. The flow characteristics for both steady and unsteady situations are tentatively described as functions of model external parameters through the analysis of a large set of numerical experiments. Functional relations are derived for the mid-latitude jet parameters (length, width and transport) on the basis of scaling arguments. With the diagrams established for these quantities in forcing and dissipation parameter relations allow quantitative predictions of model response to a wide range of parameter choices to be made. The transition to barotropic instability is interpreted by analysing and comparing the spin-up phase of different numerical experiments leading either to stable or unstable solutions. Two major types of destabilization are identified, namely through meandering of the mid-latitude eastward jet and Rossby wave radiation from the westward return flow. The characteristics of the flows are shown to be highly sensitive to the external parameter changes. Competition between eddy kinetic energy level and eastward jet extension appears to consttitute the key point of this class of solutions, controlling in particular the intensity of transport in the inner gyres, driven by the eddy field on the two sides of the mid-basin jet, in a very similar manner to that of the more complex multilayered EGCMs.     

Pedogenetic and diagenetic fabrics in the Upper Proterozoic Sarnyëré formation (Gourma, Mali)

Several diagenetic fabrics are described in the uppermost member of the Sarnyéré formation, an Upper Proterozoic dolomite (700-600 Ma). Micronodular micrite, microsparite showing nodulisation processes, orbicular crusts and oncoids are thought to be due to the pedogenetic alteration of an algal (Porostromata) boundstone. Further evolution in a vadose zone creates a network of cavities which are later filled by “cave stromatolites”, micropopcorn micrite and multilayered cements. A rhythmical repetition of facies evidences a polyphased pedogenetic history, leading to a 30 m thick highly complex section. Such numerous and diversified structures are rarely preserved, especially in Proterozoic rocks, but each of them have equivalents in recent examples of caliche soil profiles.     

Intercalibration of Mg Isotope Delta Scales and Realisation of SI Traceability for Mg Isotope Amount Ratios and Isotope Delta Values

The continuous improvement of analytical procedures using multi‐collector technologies in ICP‐mass spectrometry has led to an increased demand for isotope standards with improved homogeneity and reduced measurement uncertainty. For magnesium, this has led to a variety of available standards with different quality levels ranging from artefact standards to isotope reference materials certified for absolute isotope ratios. This required an intercalibration of all standards and reference materials, which we present in this interlaboratory comparison study. The materials Cambridge1, DSM3, ERM‐AE143, ERM‐AE144, ERM‐AE145, IRMM‐009 and NIST SRM 980 were cross‐calibrated with expanded measurement uncertainties (95% confidence level) of less than 0.030‰ for the δ^25/24Mg values and less than 0.037‰ for the δ^26/24Mg values. Thus, comparability of all magnesium isotope delta (δ) measurements based on these standards and reference materials is established. Further, ERM‐AE143 anchors all magnesium δ‐scales to absolute isotope ratios and therefore establishes SI traceability, here traceability to the SI base unit mole. This applies especially to the DSM3 scale, which is proposed to be maintained. With ERM‐AE144 and ERM‐AE145, which are product and educt of a sublimation–condensation process, for the first time a set of isotope reference materials is available with a published value for the apparent triple isotope fractionation exponent θ_app, the fractionation relationship ln α(^25/24Mg)/ln α(^26/24Mg).     

The effect of willow control using a glyphosate formulation on aquatic invertebrates within a New Zealand wetland

Exotic trees, such as willow (Salix spp.), have become invasive around New Zealand waterways. Lowland wetlands in particular are vulnerable, with invasions changing hydrology and causing biodiversity loss. Applying herbicide to the willow canopy is a cost-effective control method, however uncertainty remains around effects on wetland aquatic invertebrates. Within a North Island, New Zealand, wetland, we conducted a paired before-after, control-impact study to determine if aerially applied glyphosate (with adjuvants) affected invertebrate assemblages. No effect on communities was detected during the first year after glyphosate treatment, however significant differences between control and spray-exposed communities were found during the second year, coinciding with a significant drought event in March 2013. By the third year, no statistically significant differences were found between communities from control and spray-exposed sites. This study suggests that glyphosate use, in comparable environments, is unlikely to affect aquatic invertebrates. Furthermore, the study illustrates invertebrate communities’ resilience to drought events.     

Radionuclides as tracers of water fronts in the South Indian Ocean—ANTARES IV Results

Anthropogenic ⁹⁰Sr, ^239,240Pu and ²⁴¹Am were used as tracers of water mass circulation in the Crozet Basin of the South Indian Ocean, represented by three main water fronts—Agulhas (AF), Subtropical (STF) and Subantarctic (SAF). Higher ⁹⁰Sr concentrations observed north of 43°S were due to the influence of AF and STF, which are associated with the south branch of the Subtropical gyre, which acts as a reservoir of radionuclides transported from the North to the South Indian Ocean. On the other hand, the region south of 43°S has been influenced by SAF, bringing to the Crozet Basin Antarctic waters with lower radionuclide concentrations. The ²³⁸Pu/^239,240Pu activity ratios observed in water and zooplankton samples indicated that, even 35 years after the injection of ²³⁸Pu to the Indian Ocean from the burn-up of the SNAP-9A satellite, the increased levels of ²³⁸Pu in surface water and zooplankton are still well visible. The radionuclide concentrations in seawater and their availability to zooplankton are responsible for the observed ²¹⁰Po, ^239,240Pu and ²⁴¹Am levels in zooplankton.