Removal of lead (II) from synthetic and batteries wastewater using agricultural residues in batch/column mode

The present article explores the ability of five different combinations of two adsorbents (Arachis hypogea shell powder and Eucalyptus cameldulensis saw dust) to remove Pb(II) from synthetic and lead acid batteries wastewater through batch and column mode. The effects of solution pH, adsorbent dose, initial Pb(II) concentration and contact time were investigated with synthetic solutions in batch mode. The Fourier transform infrared spectroscopy study revealed that carboxyl and hydroxyl functional groups were mostly responsible for the removal of Pb(II) ions from test solutions. The kinetic data were found to follow pseudo-second-order model with correlation coefficient of 0.99. Among Freundlich and Langmuir adsorption models, the Langmuir model provided the best fit to the equilibrium data with maximum adsorption capacity of 270.2 mg g^?1. Column studies were carried out using lead battery wastewater at different flow rates and bed depths. Two kinetic models, viz. Thomas and Bed depth service time model, were applied to predict the breakthrough curves and breakthrough service time. The Pb(II) uptake capacity (q _e = 540.41 mg g^?1) was obtained using bed depth of 35 cm and a flow rate of 1.0 mL min^?1 at 6.0 pH. The results from this study showed that adsorption capacity of agricultural residues in different combinations is much better than reported by other authors, authenticating that the prepared biosorbents have potential in remediation of Pb-contaminated waters.     

Deformation behavior of migmatites: insights from microstructural analysis of a garnet–sillimanite–mullite–quartz–feldspar-bearing anatectic migmatite at Rampura–Agucha,Aravalli–Delhi Fold Belt,NW India

International Journal of Earth Sciences - In the present study we investigate the microstructural development in mullite, quartz and garnet in an anatectic migmatite hosted within a Grenvillian-age...     

Some vibrational bands of theC-X system of V0 molecules in the umbral spectrum of the Sun

Vibrational transition probabilities namely Franck-Condon factors and r-centroids have been evaluated using an approximate analytical method for theC-X system of V0. Morse potential energy curves forX _{4 –} andC _{4 –} states of V0 have been constructed using the latest spectroscopic data. The value of r-centroids for the band have been found to increase linearly with the corresponding wavelength. We show results for new transition and ten new bands in the umbral spectrum of the Sun.     

Morphotectonic Appraisal of Yamuna River Basin in Headwater Region: A Relative Active Tectonics Purview

In the present paper integrated appraisals of landform evolution and their geomorphic features, drainage networks across the upper part of Yamuna river basin have been attempted by using various geomorphic indices such as watershed, drainage density (D), drainage texture, stream-gradient index (SL), hypsometric integral (HI), drainage basin asymmetry (AF), mountain front sinuosity (Smf), sinuosity index (SI), valley floor height and width ratio (Vf) and data of historical earthquakes in characterizing the basin in view of relative index of active tectonics (RIAT) on DEM in geographic information systems (GIS) environment to assess the influence of recent tectonics on geomorphologic growth of the basin.The substantiated RIAT classes through some field observations and corroborated by recent seismicity reveal the recent activation of Yamuna tear faults in the basin with delineation of four RIAT classes such as class-1 (inactive 9.8% of the area), class-2 (low active; 16.40% of the area), class-3 (moderately active; 42.38% of the area) and class-4 (very active; 31.62%). The results suggest that the Himalayan frontal thrust (HFT) and Yamuna tear (YT) located in the basin is morphogenic in nature and got activated several times as evidenced by number of seismic activities in the basin and adjoining regions. The incision, and sharp turning of rivers, crenulations and warping of cross beddings/laminations and silt/clay beds and lenses, megascopic and mesoscopic faulting in sediment sequences suggest a very active nature of the HFT and YT till date in association with three prolific microseismogenic weak zones These active discontinuities appear to support the formation and development of different deformational features in sediment sequences which may be indirectly related to subduction and underthrusting of Indian plate under Eurasian plate below the Himalayan mountain chain.     

Tectonometamorphic Evolution of Jutulsessen,Gjelsvikfjella, cDML,East Antarctica

The Jutulsessen area, can provide a vital clue to the supercontinent assembly of Gondwana Land as it is situated within the Circum East Antarctic Mobile Belt just east of the Penksockett rift marking the divide between the central Dronning Maud Land from the Western Dronning Maud Land. This landmass is dominated by migmatitic quartzo-feldspathic rocks intruded by syn to post-tectonic granites. The work highlights the data from western part cDML area with a view to arrive at a more comprehensive model for the cDML and subsequently to the super continent assembly. Granitic and migmatitic gneisses comprising of amphibolitic and biotite rich enclaves. The gneisses show variations from quartzo-felspathic gneiss to amphibolitic gneiss. The area has witnessed complex geological history involving at different deformational episodes with concomitant metamorphism. The pervasive dominant foliation trends NW-SE with shallow to medium dips towards SW. In the Stabben area, a nonfoliated intrusive syenite-gabbro pluton limits the gneissic exposures. Compositionally, the orthogneisses plot in the monzogranitegranodiorite field where as the mafic dykes/enclaves plot in the basalt-andesite-rhyodacite field. The bulk geochemical characteristics suggest significant crustal contamination. Garnet-biotite Fe-Mg exchange thermometry gives peak metamorphic temperature of 483° C for the gneisses and 628° C for the dioritic enclave within gneisses. A peak metamorphic grade of upper amphibolite to granulite facies is deduced from the mineral assemblages. Widespread anatexis has led to extensive occurrence of migmatites in the area. Recent geochronological studies assign an age of 1170 Ma to 970 Ma for the migmatites/gneisses and an emplacement age of 501 Ma for the Stabben gabbro and syenite. The discriminant plots of the Jutulsessen rocks indicate diverse origin ranging from pre-plate collision to post-collision orogenic tectonic setting. The mafic enclaves/dykes show ocean island arc to MORB affinities. Voluminous addition of juvenile crust during the Pan-African orogeny strongly overprints earlier structures.     

Ocean model derived global surface circulation and Vertical velocity

In this article, the authors examine Sea surface temperature (SST), Sea surface circulation (SSC) and Vertical velocity (VV) fields from simulation of 25 layers coarse resolution Modular ocean model (MOM version 3.0) with prescribed wind forcing for the region 74.25°S to 65°N, 180°W-180°E. It is found that distribution of SST simulated by the model shows its consistency with the observed climatology. However, simulated SST in the areas of Arabian Sea, Bay of Bengal, Indonesian Throughflow (ITF) region and east of North America near equator exhibit slight warming with respect to observation, which may be due to model deficiency and forcing problems. Circulation features suggest that one of the strongest current viz. Antarctic circumpolar current (ACC) along with other major current systems viz. Gulf stream current, North and South Pacific current, Agulhas current, Labrador current, Canary current, etc are captured well by the model. In the Indian Ocean and other ocean basins, current patterns are well captured by the model simulation. Intense upwelling as well as downwelling areas is marked in the horizontal distribution of VV, which is as expected. VV show quasi-stagnant and convergent regions suggesting that floating materials may be accumulated during January/July in the real ocean and wind driven circulation may act as an important contribution for such transport of floating materials in these regions. An attempt has also been made to understand the fluctuations of the SST in NINO 3.4 region during the period of model simulation using SST anomalies.     

Assessment of Kalpana-1 Rainfall Product over Indian Meteorological Sub-Divisions During the Summer Monsoon Season

In this paper, Kalpana-1 derived INSAT Multispectral Rainfall Algorithm (IMSRA) rainfall estimates are compared with two multisatellite rainfall products namely, TRMM Multisatellite Precipitation Analysis (TMPA)-3B42 and Global Satellite Mapping of Precipitation (GSMaP), and India Meteorological Department (IMD) surface rain gauge (SRG)-based rainfall at meteorological sub-divisional scale over India. The performance of the summer monsoon rainfall of 2013 over Indian meteorological sub-divisions is assessed at different temporal scales. Comparison of daily accumulated rainfall over India from IMSRA shows a linear correlation of 0.72 with TMPA-3B42 and 0.70 with GSMaP estimates. IMSRA is capable to pick up daily rainfall variability over the monsoon trough region as compared to TMPA-3B42 and GSMaP products, but underestimates moderate to heavy rainfall events. Satellite-derived rainfall maps at meteorological sub-divisional scales are in reasonably good agreement with IMD-SRG based rainfall maps with some exceptions. However, IMSRA performs better than GSMaP product at meteorological sub-divisional scale and comparable with TMPA data. All the satellite-derived rainfall products underestimate orographic rainfall along the west coast, the Himalayan foothills and over the northeast India and overestimate rainfall over the southeast peninsular India. Overall results suggest that IMSRA estimates have potential for monsoon rainfall monitoring over the Indian meteorological sub-divisions and can be used for various hydro-meteorological applications.     

Variability of surface roughness and turbulence intensities at a coastal site in India

Surface-layer features with different prevailing wind directions for two distinct seasons (Southwest Monsoon and Northeast Monsoon) on the west coast of India are studied using data obtained from tower-based sensors at a site located about 500 m from the coast. Only daytime runs have been used for the present analysis. The surface boundary-layer fluxes have been estimated using the eddy correlation method. The surface roughnessz ₀ obtained using the stability-corrected wind profiles (Paulson, 1970) has been found to be low for the Southwest monsson season. For the other season,z ₀ is relatively high. The drag coefficientC _D varies with height in the NE monsoon season but not in the season with lowz ₀. This aspect is reflected in the wind profiles for the two seasons and is discussed in detail. The scaling behaviour of friction velocityu _* and the turbulence intensity of longitudinal, lateral and vertical winds _u, _v and _w, respectively) are further examined to study their dependence on fetch. Our study shows that for the non-dimensional case, _u/u_* and _v/u_* do not show any surface roughness dependence in either season. On the other hand, for _w/u_* for the season with lowz ₀, the values are seen to agree well with that of Panofskyet al. (1977) for homogeneous terrain whereas for the other season with highz ₀, the results seem to conform more to the values observed by Smedman and Högström (1983) for coastal terrain. The results are discussed in the light of observations by other investigators.     

The ice sheet dynamics around Dakshin Gangotri glacier,Schirmacher Oasis,East Antarctica vis-à-vis topography and meteorological parameters

Recession of the snout of Dakshin Gangotri glacier in the western part of Schirmacher Oasis, East Antarctica has been recorded over two decades. However, the rate of retreat is not uniform and varies at different locations. The ice wall forming the western flank of the glacier has shown an average retreat of 17.07 m between 2001 and 2009 while the snout had gone back by 6.94 m (average) during the same period. Before 2001, the snout had shown a complete recession of 3.13 m (average). The snout occupies valley area receiving less amount of solar radiation as compared to the western wall, which is a vertical cliff receiving maximum amount of solar radiation. The notable difference in the rate of recession in different parts of the Dakshin Gangotri glacier overriding Schirmacher Oasis can be attributed to combined effect of natural factors, including meteorological parameters, ice sheet dynamics and geomorphology of that area.     

Hydrogeochemistry of coal mine water of North Karanpura coalfields,India: implication for solute acquisition processes,dissolved fluxes and water quality assessment

Mine water samples collected from different mines of the North Karanpura coalfields were analysed for pH, electrical conductivity, total dissolved solids (TDS), total hardness (TH), major anions, cations and trace metals to evaluate mine water geochemistry and assess solute acquisition processes, dissolved fluxes and its suitability for domestic, industrial and irrigation uses. Mine water samples are mildly acidic to alkaline in nature. The TDS ranged from 185 to 1343 mg L^?1 with an average of 601 mg L^?1. Ca²⁺ and Mg²⁺ are the dominant cations, while SO₄ ^2? and HCO₃ ^? are the dominant anions. A high concentration of SO₄ ^2? and a low HCO₃ ^?/(HCO₃ ^? + SO₄ ^2?) ratio (<0.50) in the majority of the water samples suggest that either sulphide oxidation or reactions involving both carbonic acid weathering and sulphide oxidation control solute acquisition processes. The mine water is undersaturated with respect to gypsum, halite, anhydrite, fluorite, aluminium hydroxide, alunite, amorphous silica and oversaturated with respect to goethite, ferrihydrite, quartz. About 40% of the mine water samples are oversaturated with respect to calcite, dolomite and jarosite. The water quality assessment shows that the coal mine water is not suitable for direct use for drinking and domestic purposes and needs treatment before such utilization. TDS, TH, F^?, SO₄ ^2?, Fe, Mn, Ni and Al are identified as the major objectionable parameters in these waters for drinking. The coal mine water is of good to suitable category for irrigation use. The mines of North Karanpura coalfield annually discharge 22.35 × 10⁶ m³ of water and 18.50 × 10³ tonnes of solute loads into nearby waterways.