Dissolution rates of metals in Fe oxides: implications for sampling ferruginous materials with significant relict Fe oxides

A study of the pattern of dissolution of synthetic and natural Fe oxides in 6 M HCl indicates that the rate of element release from synthetic Fe oxides is strongly influenced by mineralogy and the level of element incorporation. Synthetic maghemite (γ-Fe₂O₃) samples are subject to much more rapid dissolution than goethite (FeOOH) and hematite (α-Fe₂O₃). In samples dominated by hematite and maghemite, Cu, Zn and particularly Pb, in comparison to Fe, are preferentially released during the early stages of dissolution. Similar patterns are apparent from the dissolution of hematite- and maghemite-dominated samples derived from natural gossan. Comparison of XRD scans with data from the dissolution of natural gossan samples transformed by incremental heating to hematite- and maghemite-dominated assemblages suggests that the degree of crystallinity may also be a significant factor in the release of elements incorporated in the Fe oxides. Ferruginous materials made up of varying proportions of goethite, hematite, maghemite, kaolinite and quartz are important sampling materials in a range of regolith environments. These are products of complex chemical and mechanical mobilization over long periods of geological time. If the patterns of Fe oxide dissolution in 6 M HCl and the release of incorporated metals reflect stability in such weathering regimes, knowledge of the retention characteristics of incorporated metals in different Fe oxide phases, as indicated by this study, will be useful in the planning and interpretation of geochemical surveys in such regions.     

Hydrocarbons of the hypersaline basins of Shark Bay,Western Australia

Shark Bay is an 8000 sq. km shallow marine embayment on the western coast of Western Australia. The waters exhibit a well established salinity gradient from oceanic to hypersaline. The chemical assemblage of sediment hydrocarbons along the salinity gradient may be classified into two distinct chemogeographic types. Firstly, oceanic sediments contain n-alkanes and a suite of highly branched and branched/cyclic C₂₅ alkenes. Hypersaline sediments are characterised by a high relative abundance of a C₂₅H₅₀ alkene together with an analogous C₂₀H₄₀ alkene and its parent C₂₀H₄₂ alkene (2,6,10-trimethyl-7-(3-methylbutyl)-dodecane). A pair of alkanes C₂₁H₄₂ and C₂₂H₄₄ increase in concentration and relative abundance with depth. The hydrocarbons of the hypersaline basins are found in only trace amounts in oceanic sediments. These chemical signals are overlain by further input indicative of the immediate biotic community.     

Drainage sampling for uranium in the Torrington district, New South Wales, Australia

A brief orientation study has been conducted to evaluate the use of drainage geochemical sampling for U in the granitic and forested terrain of the Torrington district of northeastern New South Wales. Anomalous U levels are present in both stream sediments and waters draining a known W prospect containing accessory U. The U dispersion is affected by interrelated environmental factors such as catchment physiography and the organic content of the stream sediments. The influence of organic content on U level in stream sediments is most significant. Variation in sediment organic content is related to accumulation of vegetal organic debris and charcoal in stream channels by sheetwashing of sparsely covered forest floors particularly in catchments of high topographic relief. The U is apparently absorbed onto the organic material from ephemerally flowing stream waters. Temporal variations in U content of stream sediment are indicated which necessitate careful consideration in planning and interpreting the results of a survey in this environment.     

Dynamics and local boundary properties of the dawn-side magnetopause under conditions observed by Equator-S

Magnetic field measurements, taken by the magnetometer experiment (MAM) on board the German Equator-S spacecraft, have been used to identify and categorise 131 crossings of the dawn-side magnetopause at low latitude, providing unusual, long duration coverage of the adjacent magnetospheric regions and near magnetosheath. The crossings occurred on 31 orbits, providing unbiased coverage over the full range of local magnetic shear from 06:00 to 10:40 LT. Apogee extent places the spacecraft in conditions associated with intermediate, rather than low, solar wind dynamic pressure, as it processes into the flank region. The apogee of the spacecraft remains close to the magnetopause for mean solar wind pressure. The occurrence of the magnetopause encounters are summarised and are found to compare well with predicted boundary location, where solar wind conditions are known. Most scale with solar wind pressure. Magnetopause shape is also documented and we find that the magnetopause orientation is consistently sunward of a model boundary and is not accounted for by IMF or local magnetic shear conditions. A number of well-established crossings, particularly those at high magnetic shear, or exhibiting unusually high-pressure states, were observed and have been analysed for their boundary characteristics and some details of their boundary and near magnetosheath properties are discussed. Of particular note are the occurrence of mirror-like signatures in the adjacent magnetosheath during a significant fraction of the encounters and a high number of multiple crossings over a long time period. The latter is facilitated by the spacecraft orbit which is designed to remain in the near magnetosheath for average solar wind pressure. For most encounters, a well-ordered, tangential (draped) magnetosheath field is observed and there is little evidence of large deviations in local boundary orientations. Two passes corresponding to close conjunctions of the Geotail spacecraft are analysed to confirm boundary orientation and motion. These further show evidence of an anti-sunward moving depression on the magnetopause (which is much smaller at Equator-S). The Tsyganenko model field is used routinely to assist in categorising the crossings and some comparison of models is carried out. We note that typically the T87 model fits the data better than the T89 model during conditions of low to intermediate K_p index near the magnetopause and also near the dawn-side tail current sheet in the dawnside region.     

Starburst galaxies and structure in the submillimetre background towards the Hubble Deep Field

We use an 850-μm SCUBA map of the Hubble Deep Field (HDF) to study the dust properties of optically-selected starburst galaxies at high redshift. The optical/infrared (IR) data in the HDF allow a photometric redshift to be estimated for each galaxy, together with an estimate of the visible star-formation rate. The 850-μm flux density of each source provides the complementary information: the amount of hidden, dust-enshrouded star formation activity. Although the 850-μm map does not allow detection of the majority of individual sources, we show that the galaxies with the highest UV star-formation rates are detected statistically, with a flux density of about S ₈₅₀=0.2 mJy for an apparent UV star-formation rate of 1  h ⁻² M_⊙ yr⁻¹. This level of submillimetre output indicates that the total star-forming activity is on average a factor of approximately 6 times larger than the rate inferred from the UV output of these galaxies. The general population of optical starbursts is then predicted to contribute at least 25 per cent of the 850-μm background. We carry out a power-spectrum analysis of the map, which yields some evidence for angular clustering of the background source population, but at a level lower than that seen in Lyman-break galaxies. Together with other lines of argument, particularly from the NICMOS HDF data, this suggests that the 850-μm background originates over an extremely wide range of redshifts – perhaps 1≲ z ≲6.