Climate change and human impact at Sacrower See (NE Germany) during the past 13,000 years: a geochemical record

Lacustrine sediments in north-eastern Germany have rarely been used as archives to address the effects of climate change and human impact on both lake ecosystem and landscape evolution for this region. Sacrower See, a hardwater lake located in Brandenburg, provides a unique sediment record covering the past 13,000 years which was used to reconstruct climatic and anthropogenic forcing on lacustrine sedimentation. Time control is provided by 12 AMS ¹⁴C dates of terrestrial plant remains, the Laacher See Tephra, and the onset of varve formation in AD 1870 (80 cal. BP). Geochemical (including XRF logging of major elements, CNS analyses as well as δ¹³C_org and δ¹⁵N measurements) and pollen analyses allowed detecting detailed environmental changes in the sediment record. During the Younger Dryas cold phase increased soil erosion and hypolimnetic oxygen depletion enhanced the nutrient supply to the lake water causing eutrophic conditions. The beginning of the Holocene is characterized by large changes in C/N ratios, total sulphur, δ¹³C of bulk organic matter as well as in K, Si, and Ti, reflecting the response of the lake’s catchment to climatic warming. Reforestation reduced the influx of detrital particles and terrestrial organic matter. The first, rather weak evidence of human impact is documented only in the pollen record at 5,500 cal. BP. However, until 3,200 cal. BP sedimentological and geochemical parameters indicate relatively stable environmental conditions. During periods of intense human impact at around 3,200, 2,800, and 900 cal. BP peaks in Ti and K represent phases of increased soil erosion due to forest clearing during the Bronze Age, Iron Age, and Medieval Times, respectively. In general, greater variation is observed in most variables during these perturbations, indicating less stable environmental conditions. The steady rise of biogenic silica accumulation rates during the Holocene reflects an increasing productivity of Sacrower See until diatoms were outcompeted by other algae during the last centuries. The applied multi-proxy approach fosters the interpretation of the sediment record to reveal a consistent picture of environmental change including environmental factors controlling lake ontogeny and the effects of human impact.     

GEOMORPHOLOGY OF THE LAKE SHEWA LANDSLIDE DAM,BADAKHSHAN, AFGHANISTAN,USING REMOTE SENSING DATA

Lake Shewa in northeastern Badakhshan, Afghanistan, was dammed sometime in antiquity when a large rock avalanche (sturzstrom) from the fault‐shattered and strongly weathered Archean gneisses of the Zirnokh peaks to the north moved into the Arakht River valley. This rock avalanche dammed up the river and its tributaries to a dam thickness of c. 400 m, producing a 12‐km‐long lake that is as much as 270 m deep, leaving c. 80 m of freeboard to the top of the dam. At least four separate instances of slope failure have been mapped at the site of the landslide dam, as well as a rock glacier, using remotely sensed data, historical maps, and Google Earth?. Spring seepage through the dam face has caused several recent subsidiary debris slides, which if continued at a large enough scale for long enough, or with additional seismicity from the active strike‐slip faults that cross beneath the landslide dam, could threaten its integrity. Otherwise the clean water that emerges from the dam face could be the source of an unvarying mini‐hydroelectric power source, in addition to the agricultural irrigation that it provides at the present time.     

The pelagic distribution of marine birds in a heterogeneous environment

In this paper I review recent, small-scale, process-oriented studies of the pelagic distribution of marine birds. I examine the roles played by a variety of hydrographic features, including steep flow gradients (fronts) and water column stratification, in determining the abundance or availability of avian prey. The ice edge/marginal ice zone is a frontal area of particular interest in polar regions. In most oceanic systems we have examples of avian use of a feature, hut only poor information on the importance of the feature for supporting the population as a whole. I review recent studies of the spatial and numerical concordance of marine birds and their prey, and find that these studies have yielded mixed results, with correlations stronger for piscivorous birds, particularly murres foraging on capelin, than for planktivores. Review of investigations of multispecies interactions during foraging shows that flock foraging has both beneficial and negative aspects. Interspecific facilitation of foraging occurs in numerous interactions involving both other species of birds and marine mammals. However, co-occurrence of predators may occur because both seek the same prey, and caution must be used in assessing mutualistic interactions between predatory species.     

An imaging,tunable magneto-optical filter

The Imaging, Tunable Magneto-Optical Filter (ITMOF) is a one- or two-cell magnetic birefringence filter designed to measure the Doppler shift of the solar potassium line (770 nm) with respect to a laboratory standard. Two gas vapor cells contain isotopically refined potassium and operate at temperature near 393 K. Hot cell windows are employed in a carefully controlled thermal environment to limit spurious birefringence in the pyrex cell and prevent condensation in the light path. Electromagnets provide a variable strength and direction longitudinal magnetic field of up to 5000 G on each cell. There is no rotating quarter-wave plate or other moving parts. The final image is detected with a CCD camera system.     

Aeolian to marine transition in Cambro—Ordovician cratonic sheet sandstones of the northern Mississippi valley, U.S.A.

Cratonic quartz sandstones have presented several intractable problems. Besides their extreme textural and compositional maturity and paucity of shale, their sheet-like geometry is particularly notable. If the sandstones were entirely marine, as long supposed, such geometry is difficult to explain in terms of modern shelf sediments, which are generally held to be either relict or only slightly reworked by the Holocene transgression (palimpsest). Re-study of two quartz sandstones in the northern Mississippi Valley region reveals evidence for significant non-marine deposition followed by varying degrees of marine reworking during transgressions. Facies patterns are similar in the Cambrian Wonewoc and Ordovician St Peter sandstones, both of which overlie unconformities. In both, a large-scale cross-stratified facies believed to represent aeolian ergs passes laterally into a planar-and-channelled facies inferred to represent sand plains composed of braided fluvial and aeolian sand sheet deposits. Criteria of aeolian deposition in both facies include adhesion structures, large ripple index, fine climbing translatent lamination, grainfall and grainflow stratification. Criteria of braided fluvial deposition include shallow channels containing sequences of thinning-upward sets of trough cross-stratification, reactivation surfaces, low-index ripples, and polygonal cracks. Probable aeolian sand sheets contain flat bedding punctuated by small channels, adhesion structures, and coarse-sand ripples with large index. There is a conspicuous absence of trace and body fossils from these inferred non-marine deposits. In contrast is a burrowed and trough cross-stratified facies characterized by medium-scale cross-bedding alternating with bioturbated intervals and rare brachiopod or trilobite-mould coquinas, which is interpreted as shallow marine. In both formations, this last facies replaces laterally and overlaps the other two, reflecting transgression and variable reworking. The main areas of non-marine deposits in both formations are capped by a thin, burrowed subfacies that represents the culmination of each transgression; that is, a stillstand during which sediment influx ceased and both physical winnowing and bioturbation were intense. It is suggested that the sheet-like geometry of many cratonic quartz sandstones is due primarily to initial sand dispersal by aeolian and fluvial processes. That such processes must have been orders-of-magnitude more important on pre-Devonian, vegetation-free landscapes than they have been since, not only helps to explain the sheet-like character but also the exceptional maturity of the older cratonic sandstones.     

Submerged forest off Nyuzen, Kurobegawa alluvial fan, Toyama Bay, Central Japan

Remnants of a submerged ancient forest have been found on the continental shelf of NW Japan off the Kurobe alluvial fan in Toyama Bay. The remains, standing tree stumps and roots, are located at depths between 20 and 40 m and ages of 8,000 years B.P. to 10,000 years B.P. have been determined by the ¹⁴C method. Alnus and Salix are the most commonly preserved genera and the trees grew on the now sub-merged seaward margin of the alluvial fan. Pollen analysis permits an estimate of palaeo-temperatures 2°C to 4°C lower than at present. Diatoms give some indication of salinity variations at the time of forest development and suggest brackish water, possible lagoonal conditions. The distribution of the stumps and roots suggests that there were probably two separate forests which were overwhelmed by rising sea-level and flash flood deposits. The present day submarine exposures may be due to recent submarine erosion related to the seaward movement of flood waters which passed from the fan into the upper reaches of the Toyama submarine canyon system.     

Metal ion remediation by polyamidoamine dendrimers: a comparison of metal ion,oxidation state,and titania immobilization

The exceptional ability of dendrimers to coordinate metal ions yields the potential for many applications including wastewater remediation, which is the focus of this study. Here, the comparison of metal ion removal rate from simulated wastewater by generation 4 dendrimers with external hydroxyl functional groups (G4-OH) is evaluated for Ni²⁺, Fe²⁺, and Fe³⁺ ions. Ni²⁺ to amine complexation occurred more rapidly than Fe³⁺, which was more rapid than Fe²⁺ complexation. These results indicate that both charge density and d-electron configuration are important toward the chelation rate. The impact of both factors is discussed in light of existing models in which precursor aquation rates have been proposed as a key intermediate step. Additionally, the application of the dendrimers as chelation agents is further advanced by immobilizing the dendrimer to titania and re-evaluating its chelation ability for Ni²⁺ removal. The dendrimer immobilization decreased the pseudo-first-order rate coefficient for Ni²⁺—amine complexation at a pH of 7 by a factor of 7.5. This result is significant as it suggests that mass transfer becomes important following immobilization of the dendrimer to titania.