Quantitative Simulation of the Hydrothermal Systems of Crystallizing Magmas on the Basis of Transport Theory and Oxygen Isotope Data: An analysis of the Skaergaard Intrusion

Application of the principles of transport theory to studiesof magma-hydrothermal systems permits quantitative predictionsto be made of the consequences of magma intruding into permeablerocks. Transport processes which redistribute energy, mass,and momentum in these environments can be represented by a setof partial differential equations involving the rate of changeof extensive properties in the system. Numerical approximationand computer evaluation of the transport equations effectivelysimulates the crystallization of magma, cooling of the igneousrocks, advection of chemical components, and chemical and isotopicmass transfer between minerals and aqueous solution. Numerical modeling of the deep portions of the Skaergaard magma-hydrothermalsystem has produced detailed maps of the temperature, pressure,fluid velocity, integrated fluid flux, ¹⁸O-values in rock andfluid, and extent of nonequilibrium exchange reactions betweenfluid and rock as a function of time for a two-dimensional cross-sectionthrough the pluton. An excellent match was made between calculated¹⁸O-values and the measured ¹⁸O-values in the three principalrock units, basalt, gabbro, and gneiss, as well as in xenolithsof roof rocks that are now embedded in Layered Series; the latterwere evidently depleted in ¹⁸O early in the system's coolinghistory, prior to falling to the bottom of the magma chamber.The best match was realized for a system in which the bulk rockpermeabilities were 10^–13 cm² for the intrusion, 10^–11cm² for basalt, and 10^–16 cm² for gneiss; reaction domainsizes were 0.2 cm in the intrusion and gneiss and 0.01 cm inthe basalts, and activation energy for the isotope exchangereaction between fluid and plagioclase was 30 kcal/mole. The calculated thermal history of the Skaergaard system wascharacterized by extensive fluid circulation that was largelyrestricted to the permeable basalts and to regions of the plutonstratigraphically above the basalt-gneiss unconformity. Althoughfluids circulated all around the crystallizing magma, fluidflow paths were deflected around the magma sheet during theinitial 130,000 years. At that time, crystallization of thefinal sheet of magma and fracture of the rock shifted the circulationsystem toward the center of the intrusion, thereby minimizingthe extent of isotope exchange between rocks near the marginof the intrusion at this level. For comparison, similar calculationswere also made for pure conductive cooling; it was found thatthe rate of crystallization of the magma body was not changed.The solidified pluton cooled by a factor of about 2 faster inthe presence of a hydrothermal system. Transport rates of thermal energy out of the intrusion and oflow-¹⁸O fluids into the intrusion controlled the overall isotopeexchange process. During the initial 150,000 years, temperatureswere high and reaction rates were fast; thus, fluids flowinginto the intrusion quickly equilibrated with plagioclase. However,the temperature decreased between 120,000 and 175,000 yearsand caused a decrease in reaction rates and an increase in theequilibrium fractionation factor between plagioclase and fluid.Consequently, during this time period fluids in the intrusiontended to be out of equilibrium with plagioclase. After 175,000years temperatures had decreased sufficiently that reactionrates became insignificant, but convection rates were largeenough to redistribute fluid and enlarge the regions where fluidand plagioclase were out of equilibrium. By 400,000 years, thepluton had cooled to approximately ambient temperatures, andthe final ¹⁸O values were ‘frozen in’. Reactionsbetween hydrothermal fluid and the intrusion occurred over abroad range in temperature, 1000-200 °C, but 75 per centof the fluid circulated through the intrusion while its averagetemperature was >480 °C. This relatively high temperatureis consistent with the observation that only minor amounts ofhydrothermal alteration products were formed in the naturalsystem, even where several per mil shifts in ¹⁸O were detected. The relative quantities of fluid to rock integrated over theentire cooling history were 0.52 for the upper part of intrusion,0.88 for the basalt, 0.003 for the gneiss, and 0.41 for theentire domain. Almost all of the fluid flowed into the intrusionfrom the basalt host rocks that occur adjacent to the side contactsof the intrusion. Convection transferred about 20 per cent ofthe total heat contained in the gabbro upward into the overlyingbasalts; the remaining 80 per cent of the heat was transferredby conduction.     

Abnormal features of Macoma balthica (Bivalvia) in the Baltic Sea: alerting symptoms of environmental adversity?

Recent studies of the Baltic clam Macoma balthica (L.) from the southern Baltic (the Gulf of Gdansk) have revealed striking morphological, histological and cytogenetic features. Strong deformation of the shell, including elongation of the posterior end and the appearance of an easily visible flexure in this part, has been recorded. The population contribution of the deformed blunt shelled ("irregular") clams ranged from 0% to 65% and tended to increase with depth. The morphologically "irregular" clams had higher accumulated tissue concentrations of trace metals (As, Ag, Cd, Pb, Cu and Zn), indicating a different metal handling ability. Adverse conditions in deeper water regions of the Gulf (e.g. hypoxia, hydrogen sulphide, elevated bioavailability of contaminants) have been suggested as inducers of the phenotypical changes (morphological deformation) in part of the population and, in parallel, of the specific physiological adaptations that result in higher metal accumulation in the "irregular" clams. Cytogenetic and histological analyses showed the presence of tumours in gill cells and digestive system of the affected clams, the prevalence of disseminated neoplasia ranging from 0% to 94% depending on the site. The disease was manifested by a modified karyotype (i.e. an abnormal number and morphology of chromosomes), a higher activity of nucleolar organizer regions (AgNORs), and tissue lesions (enlarged cells, actively proliferative with pleomorphic nuclei). Bottom sediments showed acute toxicity and have been proposed as a source of an initialising carcinogenic factor. However, none of the ecotoxicological studies provided was successful in the clear demonstration of a single (or multifactorial) agent that can account for the disseminated neoplasia.     

UHP metamorphism recorded by kyanite-bearing eclogite in the Seve Nappe Complex of northern Jämtland,Swedish Caledonides

The first evidence for ultrahigh-pressure (UHP) metamorphism in the Seve Nappe Complex of the Scandinavian Caledonides is recorded by kyanite-bearing eclogite, found in a basic dyke within a garnet peridotite body exposed close to the lake Friningen in northern Jämtland (central Sweden). UHP metamorphic conditions of ~ 3 GPa and 800 °C, within the stability field of coesite, are constrained from geothermobarometry and calculated phase equilibria for the peak-pressure assemblage garnet + omphacite + kyanite + phengite. A prograde metamorphic evolution from a lower P–T (1.5–1.7 GPa and 700–750 °C) stage during subduction is inferred from inclusions of pargasitic amphibole, zoisite and kyanite in garnet cores. The post-UHP evolution is constrained from breakdown textures, such as exsolutions of kyanite and silica from the Ca-Eskola clinopyroxene. Near isothermal decompression of eclogite to lower crustal levels (~ 0.8–1.0 GPa ) led to formation of sapphirine, spinel, orthopyroxene and diopside at granulite facies conditions. Published age data suggest a Late Ordovician (460–445 Ma) age of the UHP metamorphism, interpreted to be related to subduction of Baltoscandian continental margin underneath an outboard terrane, possibly outermost Laurentia, during the final stages of closure of the Iapetus Ocean. The UHP rocks were emplaced from the hinterland collision zone during Scandian thrusting of the nappes onto the Baltoscandian foreland basin and platform. The record of P–T conditions and geochonological data from UHP rocks occurring within the allochthonous units of the Scandinavian Caledonides indicate that Ordovician UHP events may have affected much wider parts of the orogen than previously thought, involving deep subduction of the continental crust prior to final Scandian collision between Baltica and Laurentia.     

Multi-stakeholder collaboration yields valuable data for cetacean conservation in Gamba,Gabon

Private industry, the Government of Gabon and two international NGOs collaborated to conduct marine surveys off the coast of Gabon, Central Africa. Surveys addressed multiple objectives of surveillance and monitoring, the documentation of the distribution of and threats to the marine megafauna, and capacity-building among government agents and local early-career scientists. During 22 days of survey effort over a two-year period, observers documented humpback whales Megaptera novaeangliae, bottlenose dolphins Tursiops truncatus, Atlantic humpback dolphins Sousa teuszii and common dolphins Delphinus delphis. Humpback whale presence was limited to the months of July to November. Bottlenose dolphins were present year-round and photo-identification of individuals indicated a closed, resident population, with an abundance estimate of 118 (CV = 21.6%, 95% CI 78–180). Small open-decked fishing vessels with gillnets were observed concentrated around river mouths within 2 km of shore, while commercial trawlers were at least 10 km offshore; all were confirmed to be registered and legal. Observations of marine turtles, flocks of marine birds, and floating logs and other debris were sparse. This multi-stakeholder collaboration to conduct a marine survey can serve as an effective model by which funding and logistic support from private industry paired with technical expertise from NGOs and academic institutions can benefit marine and coastal conservation.     

Modeling bio-geomorphological influences for offshore sandwaves

The coastal environment shows a wide range of bed patterns, for which sandwaves and sandbanks are among the most common. Less known in this context is the high benthic diversity in the coastal environment, which gives rise to the question to what extend the benthos interacts with the shape of the seabed. This paper reviews field and flume experiments on bio-geomorphological influences between benthos and sediment and tests the hypothesis that both the occurrence and the dimensions of sandwaves are dependent on the benthic diversity in the North Sea. Mathematical inclusions to account for biological activity in idealized models reveal that biota is able to influence the wavelength of sandwaves significantly, compared to the default case. More importantly, the models indicate that biota is able to induce bed patterns under conditions when the physical parameters suggest a stable flat bed and vice versa. Present model explorations indicate that future research should focus on the parameterization of subtidal biological activity on sediment dynamics and thereby on seabed patterns. Such knowledge will enable process-based modeling of the spatial and temporal variation in biological activity on seabed morphodynamics and validate the proposed modeling approach with field measurements.     

Aluminum-26 in meteorites—VII. Ureilites,their unique radiation history

Cosmogenic ²⁶A1 activities have been measured by γ-γ coincidence counting in the three ureilites which had not previously been studied. The values in dpm/kg are: Dingo Pup Donga, 38.4 ± 2.4; North Haig, 39.3 ± 4.8; Dyalpur, 55.8 ± 4.8. Five of the six known ureilites thus have lower ²⁶A1 contents, 63 per cent to 77 per cent, than the calculated saturation values, in marked contrast to most other stony meteorites. This cannot be attributed to short cosmic ray exposure ages. Nor do size and depth effects account for the narrow range of ²⁶A1 activities, because a nuclear particle track study indicates that preatmospheric radii were highly variable, from ≥ 40 cm for Goalpara to only a few cm for Dingo Pup Donga. By default, the most likely explanation is that the ureilites had much smaller or much larger orbits than all other stony meteorites.