Amplifiers, filters and geomorphic responses to climate change in Kentucky rivers

Efforts to predict responses to climate change and to interpret modern or paleoclimate indicators are influenced by several levels of potential amplifiers, which increase or exaggerate climate impacts, and/or filters, which reduce or mute impacts. With respect to geomorphic responses and indicators, climate forcings are partly mediated by ecological, hydrological, and other processes which may amplify or filter impacts on surface processes and landforms. Then, geomorphic responses themselves may be threshold-dominated or dynamically unstable, producing disproportionately large and long-lived responses to climate changes or disturbances. Or, responses may be dynamically stable, whereby resistance or resilience of geomorphic systems minimizes the effects of changes. Thus a given geomorphic response to climate could represent (at least) two levels of amplification and/or filtering. An example is given for three fluvial systems in Kentucky, U.S.A, the Kentucky, Green, and Big South Fork Rivers. Climate impacts in the early Quaternary were amplified by glacially-driven reorganization of the ancestral Ohio River system to the North, and by dynamical instability in the down-cutting response of rivers incising plateau surfaces. Effects of more recent climate changes, however, have been filtered to varying extents. Using alluvial terraces as an example, the study rivers show distinctly different responses to climate forcings. The lower Green River has extensive, well-developed terraces recording several episodes of aggradation and downcutting, while the Big South Fork River has no alluvial terraces. The Kentucky River is intermediate, with limited preservation of relatively recent terraces. The differences can be explained in terms of differences among the rivers in (1) filtering effects of constraints on fluvial responses imposed by strongly incised, steep-walled bedrock controlled valleys; and (2) amplifier effects of periodic damming of lower river reaches by glaciofluvial outwash.     

A new 40Ar/39Ar eruption age for the Mount Widderin volcano,Newer Volcanic Province,Australia, with implications for eruption frequency in the region

The Mount Widderin shield volcano is located near Skipton, western Victoria, in the Western Plains subprovince of the monogenetic Pliocene–Holocene Newer Volcanic Province (NVP). Radiometric ages for lavas in the Hamilton–Skipton–Derrinallum area are few, owing to limited suitable outcrop for K–Ar or ⁴⁰Ar/³⁹Ar geochronology studies. Existing age constraints for flows in this area have been inferred from Regolith Landform Units (RLUs), complemented by a small number of K–Ar studies on ≥1 Ma flows. Although the RLU approach provides a valuable overview of relative eruption ages across the NVP, it is of limited use in eruption frequency studies. Additional radio-isotopic ages are required to refine age ranges for individual RLUs, and to validate previous assignment of individual flows to specific RLUs. We report a new, high-precision ⁴⁰Ar/³⁹Ar age of 389 ± 8 ka (2σ) for a Mount Widderin basalt sample. Based on this age and geomorphic observations, we propose that both the Widderin and Elephant lava flows be reassigned from the Eccles RLU to the Rouse RLU. We use the 389 ± 8 ka (2σ) age for Widderin, along with published K–Ar ages, to anchor a stratigraphic sequence of 15 individual flows in the Hamilton–Skipton–Derrinallum area, demonstrating that intermittent volcanism has occurred in this area from ≥3 Ma to ≤0.389 Ma. Within the limits of available data for the NVP, this time span of volcanic activity is second only to that of the Melbourne area. We consider the significance of the Widderin eruption age, in conjunction with published age constraints for maars and scoria cones of the Western Plains subprovince, building on previous studies that have focused solely on lava flow ages. The inclusion of the additional data weakens the argument for a decrease in volcanic activity after ca 0.9 Ma as implied by published ages for lava flows only. Additional detailed combined geochronology–geomorphology studies of lavas, scoria cones and maars in strategically selected small areas are advocated to better understand eruption frequency across the NVP.     

Activation volumes for oxygen exchange between the GaO4Al12(OH)24(H2O)127+(aq) (GaAl12) polyoxocation and aqueous solution from variable pressure O NMR spectroscopy

Activation volumes for exchange of oxygen between bulk aqueous solution and sites in the GaO₄Al₁₂(OH)₂₄(H₂O)₁₂⁷⁺(aq) (GaAl₁₂) complex were measured by variable-pressure ¹⁷O NMR techniques. Near 322 K, rates of exchange for the less labile set of bridging hydroxyls in the GaAl₁₂ decrease by a factor of about two with increasing pressure from 0.1 to 350 MPa. These data indicate a substantially positive activation volume of ΔV^‡ = +7 ± 1 cm³/mol, which is the first activation volume measured for a bridging hydroxyl in a polynuclear complex. This result suggests significant bond-lengthening in the activation step. Electrostriction effects should be small because exchange occurs via a pH-independent path under the experimental conditions. The second, more labile set of bridging hydroxyls exchange too rapidly for the variable-pressure techniques employed here. The exchange of bound-water molecules on the GaAl₁₂ was observed at P = 350 MPa using the ¹⁷O-NMR line-broadening technique. Comparison with previous measurements at 0.1 MPa indicates decreasing line width from 0.1 to 350 MPa for temperatures at which exchange dominates, yielding an activation volume of ΔV^‡ = +3(± 1) cm³/mol. This activation volume is smaller than the value for the Al(H₂O)₆³⁺ complex, suggesting that water exchange on the larger GaAl₁₂ complex has less dissociative character although the average charge density is lower.     

Development of a subglacial drainage system and its effect on glacitectonism within the polydeformed Middle Pleistocene (Anglian) glacigenic sequence of north Norfolk,Eastern England

The efficiency of subglacial drainage is known to have a profound influence on subglacial deformation and glacier dynamics with, in particular, high meltwater contents and/or pressures aiding glacier motion. The complex sequence of Middle Pleistocene tills and glacial outwash sediments exposed along the north Norfolk coast (Eastern England) were deposited in the ice-marginal zone of the British Ice Sheet and contain widespread evidence for subglacial deformation during repeated phases of ice advance and retreat. During a phase of easterly directed ice advance, the glacial and pre-glacial sequences were pervasively deformed leading to the development of a thick unit of glacitectonic mélange. Although the role of pressurised meltwater has been recognised in facilitating deformation and mélange formation, this paper provides evidence for the subsequent development of a channelised subglacial drainage system beneath this part of the British Ice Sheet filled by a complex assemblage of sands, gravels and mass flow deposits. The channels are relatively undeformed when compared to the host mélange, forming elongate, lenticular to U-shaped, flat-topped bodies (up to 20–30 m thick) located within the upper part of this highly deformed unit. This relatively stable channelised system led to an increase in the efficiency of subglacial drainage from beneath the British Ice Sheet and the collapse of the subglacial shear zone, potentially slowing or even arresting the easterly directed advance of the ice sheet.     

Post‐tectonic clastic dykes in the Dalradian of Scotland and Ireland: implications for delayed lithification and deformation of sediments

Structures associated with soft‐sediment deformation are preserved in the Neoproterozoic Dalradian Supergroup of SW Scotland and NW Ireland. Clastic dykes display a range of age relationships to regional Caledonian D₁ folds and fabrics from pre‐tectonic to hitherto unrecognized post‐tectonic. Evidence for the post‐D₁ timing of some dykes includes the emplacement of centimetre‐scale injections along regional S₁ cleavage, the disorientation and transport of cleaved wall‐rock clasts within larger dykes, and clastic dykes which markedly cross‐cut and transect F₁ fold hinges and axial planes. Collectively, these observations are compatible with the earliest regional (D₁) structures deforming a sequence which contained locally overpressured and unlithified pockets of sediment. These critical relationships indicate that overpressured pockets of unlithified sediment were possibly retained within the Dalradian for significant periods of time spanning at least 120 Ma given existing isotopic constraints. Copyright © 2000 John Wiley & Sons, Ltd.