Dated wood from Alaska and the Yukon: Implications for forest refugia in Beringia

Postulations on the existence of forest refugia in parts of Beringia during the last glacial have been, in large part, based on ambiguous evidence. Existing data on radiocarbon-dated and identified fossil wood and macrofossils from Alaska and northwest Canada are synthesized here and are augmented by results of palynological studies in an effort to show the persistence of some, and total extinction of other, tree and large shrub species. Possible dispersal routes taken by species that reinvaded Beringia in postglacial times are also reconstructed from the fossil record. Macrofossil and pollen evidence, when combined with climatic factors, makes cottonwood a good candidate for survival during the last glacial. Larch and aspen are also candidates, though the evidence for them is less positive. Pollen and macrofossils of alder are very scarce in deposits of the last glacial age, and if it survived at all, it was probably in very isolated vegetatively reproducing clones. Shrub birch may have been present in Beringia, but tree birch probably was reintroduced during the Holocene. Spruce also appears to have been absent in Alaska from about 30,000 to 11,500 yr ago and probably reinvaded Beringia from a refugium south of the Laurentide ice sheet.     

Effects of pollution on the benthos of the Firth of Forth

A long-term benthic study has been undertaken in the Firth of Forth to assess the environmental impact of a new sewage treatment scheme for the city of Edinburgh. The Sewage Scheme reduces the suspended solids content of the liquid effluent by approximately 60% and achieves a lowering of the concentration of materials in solution through more efficient dilution and dispersion. Marked changes in the intertidal benthic flora and fauna have been recorded along the Edinburgh coastal zone. These changes have been apparent as the decline and disappearance of populations of certain pollution indicator species and the appearance and establishment of several species previously unrecorded along the more polluted parts of the Edinburgh shoreline. Study of the sublittoral benthos has shown no deleterious effect arising from the new effluent outfall, although there does appear to be some enhancement of the fauna in the area.     

Water quality in the firth of forth

A long-term programme of water quality monitoring has been undertaken in the Firth of Forth to assess the environmental impact of a new sewage treatment scheme for the City of Edinburgh. The sewage scheme reduces the suspended solids content of the liquid effluent by approximately 60% and achieves a lowering of the concentration of materials in solution through more efficient dilution and dispersion. The application of a sea water quality index to water quality data has demonstrated a significant improvement along the Edinburgh coastal zone, resulting mainly from a reduction in suspended solids, biochemical oxygen demand, primary nutrients and faecal contamination. There has been no apparent change in the levels of trace metals.     

40Ar/39Ar and K–Ar geochronology of magmatic and hydrothermal events in a classic low-suphidation epithermal bonanza deposit: El Peñon, northern Chile

The epithermal El Peñon gold–silver deposit consists of quartz–adularia veins emplaced within a late Upper Paleocene rhyolitic dome complex, located in the Paleocene–Lower Eocene Au–Ag belt of northern Chile. Detailed K–Ar and ⁴⁰Ar/³⁹Ar geochronology on volcano–plutonic rocks and hydrothermal minerals were carried out to constrain magmatic and hydrothermal events. The Paleocene to Lower Eocene magmatism in the El Peñon area is confined to a rhomb-shaped basin, which was controlled by N–S trending normal faults and both NE- and NW-trending transtensional fault systems. The earliest products of the basin-filling sequences comprise of Middle to Upper Paleocene (～59–55 Ma) welded rhyolitic ignimbrites and andesitic to dacitic lavas, with occasional dacitic dome complexes. Later, rhyolitic and dacitic dome complexes (～55–52 Ma) represent the waning stages of volcanism during the latest Upper Paleocene and the earliest Eocene. Lower Eocene porphyry intrusives (～48–43 Ma) mark the end of the magmatism in the basin and a change to a compressive tectonomagmatic regime. ⁴⁰Ar/³⁹Ar geochronology of hydrothermal adularia from the El Peñon deposit yields ages between 51.0±0.6 and 53.1±0.5 Ma. These results suggest that mineralization occurred slightly after the emplacement of the El Peñon rhyolitic dome at 54.5±0.6 Ma (⁴⁰Ar/³⁹Ar age) and was closely tied to later dacitic–rhyodacitic bodies of 52 to 53 Ma (K–Ar ages), probably as short-lived pulses related to single volcanic events.     

O-Sr isotopic variations in Miocene granitoids from the Aegean: evidence for an origin by combined assimilation and fractional crystallization

Sr, O, and D/H isotopic compositions have been analyzed in Miocene metaluminous to slightly peraluminous (I-type) granitoids of the central Aegean. Individual plutonic complexes display significant variations in their ¹⁸O and initial⁸⁷Sr/⁸⁶Sr compositions.D and ¹⁸O compositions of minerals and whole-rocks are mostly in the magmatic range. Some samples from Naxos and Mykonos/Delos show low D and ¹⁸O values characteristic of meteoric-water-hydrothermal interaction, but as a whole the changes in ¹⁸O and Sr isotopic compositions as a result of hydrothermal alteration were slight, even in instances where marked alteration is petrographically observable. Consequently, the bulk-rock variations of ¹⁸O from 8.1 to 12.0 and of⁸⁷Sr/⁸⁶Sr from 0.70438 to 0.71450 may be regarded as primary and indicative of the conditions of their evolution. Heterogeneous isotopic compositions observed in the individual plutons of Serifos, Ikaria, Samos and Kos may be caused by the multiple intrusion of chemically and isotopically distinct magma pulses, with high viscosities and relatively rapid consolidation in most cases preventing complete homogenization. The granitoids of Serifos, Ikaria and Kos display weak correlations between the initial⁸⁷Sr/⁸⁶Sr and ¹⁸O and 1/Sr. The granitoid province shows a positive correlation between⁸⁷Sr/⁸⁶Sr and ¹⁸O and a non-linear relationship between⁸⁷Sr/⁸⁶Sr and 1/Sr, whereby 1/Sr increases more rapidly than the isotopic ratio as the degree of fractionation of the rocks increases. It is argued that assimilation of older continental material by mantle-derived arc magmas with combined fractionation (AFC) is the most plausible model to explain the chemical and isotopic characteristics of the granitoids and the geological situation in which rock-types trend from granodiorites in the (south)west, near the inferred Oligocene-Miocene suture, to granites in the center and monzonites in the (north)east of the province.     

Precursory seismic quiescence: A preliminary assessment of the hypothesis

Numerous cases of precursory seismic quiescence have been reported in recent years. Some investigators have interpreted these observations as evidence that seismic quiescence is a somewhat reliable precursor to moderate or large earthquakes. However, because failures of the pattern to predict earthquakes may not, in general, be reported, and because numerous earthquakes are not preceded by quiescence, the validity and reliability of the quiescence precursor have not been established.We have analyzed the seismicity rate prior to, and in the source region of, 37 shallow earthquakes (M 5.3–7.0) in central California and Japan for patterns of rate fluctuation, especially precursory quiescence. Nonuniformity in rate for these pre-mainshock sequences is relatively high, and numerous intervals with significant (p<0.10) extrema in rate are observed in some of the sequences. In other sequences, however, the rate remains within normal limits up to the time of the mainshock. Overall, in terms of an observational basis for intermediate-term earthquake prediction, no evidence is found in the cases studied for a systematic, widespread or reliable pattern of quiescence prior to the mainshocks.In earthquake sequences comprising full seismic cycles for 5 sets of (M 3.7–5.1) repeat earthquakes on the San Andreas fault near Bear Valley, California, the seismicity rates are found to be uniform. A composite of the estimated rate fluctuations for the sequences, normalized to the length of the seismic cycle, reveals a weak pattern of a low rate in the first third of the cycle, and a high rate in the last few months. While these observations are qualitative, they may represent weak expressions of physical processes occurring in the source region over the seismic cycle.Re-examination of seismicity rate fluctuations in volumes along the creeping section of the San Andreas fault specified by Wyss and Burford (1985) qualitatively confirms the existence of low-rate intervals in volumes 361, 386, 382, 372 and 401. However, only the quiescence in volume 386 is found by the present study to be statistically significant.     

Human-induced changes in winter surface Albedo

Meteorology and Atmospheric Physics - The surface albedo of snow-covered deforested portions of the United States is approximately twice as high as when naturally vegetated. Moderate increases of...     

Kinetics and mechanisms of the reaction of zoisite to anorthite under hydrothermal conditions: reaction phenomenology away from the equilibrium region

The kinetics and mechanisms of the dehydration reactions of zoisite have been studied at 635°–792° C, 1–2 kbar. The equilibrium reaction does not occur and is replaced by metastable reactions involving the formation of gehlenite and a calcium tri-octahedral mica, instead of corundum: zoisite anorthite+grossular+gehlenite +calcium 3T mica+H₂O.The experimental data can be interpreted by zero-order equations dX _An/dt=k (X _An=fractional extent of reaction, t=time, k=zero-order rate constant). These relations hold for variations in P, T, A _initial(the initial surface area of zoisite) and also in the presence of seed crystals, which enhance the reaction rate. No induction period is evident and only at advanced stages of reaction are sharp decreases observed in the rate, which are attributed to physical affects (shrinking particles, armouring). SEM studies show that dissolution of zoisite is anisotropic, occurring preferentially parallel to the crystallographic b-axis, with the result that a characteristic sawtooth etch structure develops. Garnet grows as euhedral crystals located in cavities or on teeth of dissolving zoisite, whereas anorthite forms as clusters of coalescing grains which spread over and enclose the zoisite. In seeded runs, garnet growth initiates on both seeds and on zoisite surfaces whereas anorthite growth is more closely tied to the seeds, resulting in the development of clusters of smaller grains.The experimental evidence favours dissolution and nucleation-controlled growth as rate-determining processes. The preservation of zero-order kinetics in the face of shrinking particles is attributed to the anisotropic dissolution mechanism, which effectively preserves a constant reaction interface. The rate effects of nucleation appear to accord with the classic model in which growth of crystal layers is initiated by the formation of coherent nuclei.The temperature dependence of rate constants reflects both thermally activated Arrhenius-type behaviour and the rate-depressing influences of approach to equilibrium. Similarly pressure affects on reaction rate can be interpreted in terms of competition between rate enhancement due to pressure increase and rate-depression accompanying the approach to equilibrium. Although the equilibrium-approach effects accord with current treatments of reaction kinetics, a problem exists in deriving an exact relation coupling dissolution and nucleation rate control. Consequently an overall-reaction rate equation, such as that of Fisher and Lasaga (1981), is only partially successful in interpreting the temperature dependence of rates. The data suggest that the surface reaction equation of Wood and Walther (1983) only applies when nuclei are present.     

Aircraft measurements of oxides of nitrogen along the eastern rim of the Asian continent: Winter observations

Aircraft observations of oxides of nitrogen (NO _y ), measured with a ferrous sulfate converter, over the sea surrounding the Japanese islands (30–43° N, 131–141° E) were carried out in the winter of 1983 and 1984 at altitudes mostly between 3 and 8 km. NO _y defined here is the sum of NO, NO₂, and other unstable oxides of nitrogen that are converted to NO by ferrous sulfate. The main observations were:

1. Over the Pacific Ocean between the latitudes of 30–35° N, the observed NO _y mixing ratio between 3 and 8 km was a fairly constant 200 pptv. The NO mixing ratio increased with altitude from 15 pptv at 3 km to 35 pptv at 7 km.
2. Over the Sea of Japan, tropospheric NO _y mesured between 1 and 6 km started increasing with latitude North of 35° N and reached about 1000 pptv at 40° N.
3. NO _y was measured in an air mass transported from the stratosphere near a tropopause fold region. When the ozone mixing ratio was between 80 and 140 ppbv, the NO _y mixing ratio was about 200 pptv.

     

Volatile transport during the crystallization of anatectic melts: oxygen, boron and hydrogen stable isotope study on the metamorphic complex of Naxos, Greece

Crystallization of anatectic melts in high-temperature metamorphic terrains releases volatile-rich magmas that can be transported into adjacent lithologies. This study addresses the variations in the oxygen, boron and hydrogen isotopic composition of aplite-pegmatite dikes that formed during the crystallization of anatectic melts in regional high-temperature metamorphism on the island of Naxos, Greece, and propagated upward into the overlying sequences of metamorphic schist. The transport distance of these dikes was increased through a significant horizontal component of travel that was imposed by contemporaneous low-angle extensional shearing. Laser fluorination oxygen isotope analyses of quartz, tourmaline, garnet, and biotite mineral separates from the aplite-pegmatite dikes show a progressive rise in δ¹⁸O values with increasing distance from the core. Oxygen isotope fractionations among quartz, tourmaline, and garnet show temperature variations from > 700°C down to ∼400°C. This range is considered to reflect isotopic fractionation beginning with crystallization at high temperatures in water-undersaturated conditions and then evolving through lower temperature crystallization and retrograde sub-solidus exchange. Two processes are examined for the cause of the progressive increase in δ¹⁸O values: (1) heterogeneous δ¹⁸O sources and (2) fluid-rock exchange between the aplite/pegmatite magmas and their host rock. Although the former process cannot be ruled out, there is as yet no evidence in the exposed sequences on Naxos for the presence of a suitable high δ¹⁸O magma source. In contrast, a tendency for the δ¹⁸O of quartz in the aplite/pegmatite dikes to approach that of the quartz in the metamorphic rock suggests that fluid-rock exchange with the host rock may potentially be an important process. Advection of fluid into the magma is examined based on Darcian fluid flow into an initially water-undersaturated buoyantly propagating aplitic dike magma. It is shown that such advective flow could only account for part of the ¹⁸O-enrichment, unless it were amplified by repeated injection of magma pulses, fluid recycling, and deformation-assisted post-crystallization exchange. The mechanism is, however, adequate to account for hydrogen isotope equilibration between dike and host rock. In contrast, variations in the δ¹¹B values of tourmalines suggest that ¹¹B/¹⁰B fractionation during crystallization and/or magma degassing was the major control of boron geochemistry rather than fluid-rock interaction and that the boron isotopic system was decoupled from that of oxygen.