Anatomy of the middle ordovician sevier shale basin,eastern Tennessee

The Sevier Shale basin in eastern Tennessee comprises one of the thickest clastic sequences (nearly 2500 m) of Middle Ordovician age in North America. The lower one-half of the sequence is composed of Lenoir, Whitesburg, Blockhouse and Sevier Formations, in ascending order. The sequence ranges in age from Whiterockian to lower Wilderness in North American stages.The Middle Ordovician sequence exhibits tidal flat (Mosheim Member of Lenoir Fm.), subtidal (main body of Lenoir Fm.), slope (Whitesburg Fm.), anoxic basin (Blockhouse Fm), turbidite and contourite (Sevier Fm.) facies. The Sevier basin evolved in five stages: First, a widespread marine transgression initiated carbonate-shelf deposition in the study area. Second, a major tectonic downwarping event caused the stable shelf to break and subside rapidly at a rate of 60–65 cm 1000 yrs^?1, and areas of shelf facies became areas of slope and basin facies. Third, global transgressions maintained the deep anoxic conditions for nearly 10 Ma. Fourth, turbidites began to fill the basin from a westward-prograding submarine fan system. Fifth, contour currents reworked the turbidites and progressively ventilated the Sevier basin. The basin-filling process terminated with shallow-water/subaerial clastics at the end of Middle Ordovician.     

Lateral variations in the taupo ignimbrite

The young non-welded Taupo ignimbrite shows remarkable lateral variations which are documented by granulometric and component analyses, and studies of maximum clast size and density. The grain size spans practically the entire known ignimbrite field, the coarser proximal ignimbrite having a median diameter 100 times greater than the finest distal ignimbrite. The content and maximum size of lithic fragments decrease also by a factor of 100 between proximal and distal parts. The content of free crystals first rises to reach a peak, but thereafter decreases to attain a very low value in far-distal exposures. The pumice maximum size decreases by a factor of about 10, and the most conspicuously coarse pumice rocks occur in a girdle nearly halfway out from vent to distal limit. The pumice in each grain size class decreases in density to half of its near-source value in distal ignimbrite. The overall outward trend is towards an ignimbrite which consists wholly of fine vitric ash; some distal exposures closely approach this condition.These variations are accounted for by a combination of processes operating in the moving ash flow. One is a continuous fragmentation of pumice leading to a rounding of the clasts, a progressive decrease in maximum size, the generation of much vitric dust, and the liberation of crystals. Another is a continuous sedimentation of heavy constituents (lithics and crystals), and an antipathetic rise of lighter coarse pumice towards the top of the flow. These processes operated in a moving flow whose upper layers travelled progressively farther from source; it is the topmost layers, strongly depleted in heavy constituents and enriched in light pumice, which have travelled the farthest and constitute the far-distal parts of the ignimbrite.A number of ignimbrite facies are characterized: the ignimbrite proper, with its proximal, distal, and pumice concentration zone facies; the deposits which form in the head and are then over-ridden by the body of the flow, including the fines-depleted ignimbrite variant and the heavies-enriched ground layer; and the ignimbrite veneer deposits which are left behind by the flow, which differ little from the ignimbrite except in their landscape-mantling form and the occurrence in them of lee-side coarse pumice lenses.     

Application of the Mussel Watch concept in studies of the distribution of hydrocarbons in the coastal zone of the Ebro Delta

The Mussel Watch concept was applied in a study of man-induced chemical changes in the Ebro Delta on the Catalonian coast to obtain a preliminary assessment of the distribution of synthetic organic compounds, petroleum and biogenic hydrocarbons in the local coastal zone. Mussels, oysters and clams were selected as the indicator organisms. Levels of petroleum accumulated by mussels were generally high, in the order of 100–800 μg^?1 dry weight, equivalent to those in mussels in the most polluted harbours and bays of California. The relative distributions of the steranes and pentacyclic triterpanes in the mussels were significantly different from those found in petroleum from a local field, indicating that local petroleum was not contributing to the present contamination. The composition of biogenic compounds was variable, probably reflecting differences in the composition of local plankton communities, PCB levels were high in relation to current levels in mussels from US sites, reflecting continuing PCB use in Spain. The Delta appears to be a point source of a number of organochlorine compounds, including HCB, the DDT compounds, endrin and γ-chlordane. Levels of the DDT compound o,p′-DDD, a pharmacologically active substance, were unexpectedly high; identification was confirmed by GS/MS. Many unidentified peaks were present on EC chromatograms, indicating a more complex pattern of contamination than might be suggested by printed summaries of data.     

Distribution of hydrocarbons in the oyster,Pinctada margaratifera,along the coast of Kuwait

Concentrations of total hydrocarbons within the boiling point range of the alkanes n-C₁₄ and n-C₃₂ were determined in oysters, Pinctada margaratifera, from coastal waters of Kuwait. Levels of petroleum-derived hydrocarbons were highest in an area adjacent to the major oil loading facilities. Whether the use of dispersants to treat minor spills increases levels of incorporation of petroleum compounds into the food webs could not be concluded from the data of this study. Levels of total petroleum-type hydrocarbons in the oysters at this site were equivalent to those in mussels, Mytilus sp., from harbours, bays and urban coastal areas of California. The Kuwaiti oysters lacked a C₂₈ pentacyclic triterpane that was present in extracts of mussels from southern California that had been recently exposed to a minor spill or to a natural seepage. Levels of DDE and PCB were comparable to those in relatively unpolluted areas of North America.     

Sisterhood and Seine‐Nets: Engendering Development and Conservation in Ghana's Marine Fishery

As processors and marketers of fish, women fishtraders in the Fanti town of Cape Coast, Ghana have become powerful financers and owners of canoes, nets, and other fishing equipment. Since the 1960s, when motors were first introduced to Ghana's artisanal canoe fleet, two interrelated processes have occurred in Cape Coast. First, Ghana's fisheries have become increasingly exploited and—in the case of some species—overfished. Second, the social relations of production in the artisanal sector have shifted from being socially embedded to being more market‐based and impersonal. I argue that two recent Women in Development (WID) projects in particular have contributed to the breakdown of fishtraders’ traditional economic networks and livelihood strategies: (a) loan schemes that target women's associations, and (b) the 1985 Intestate Succession Law, which reconfigured inheritance rights. These WID projects, based on western notions of gender and the household, have created disharmony and mistrust among Cape Coast's fishtraders rather than promoting their “development.” The breakdown of fishtraders’ labor and marketing organizations has resulted in increasingly desperate strategies to get fish, increased degradation of Ghana's marine environment, and uncertainty for the future of the coastal economy.     

Isotopic responses to basaltic injections into silicic magma chambers: a whole-rock and microsampling study of macrorhythmic units in the Pleasant Bay layered gabbro-diorite complex, Maine, USA

The Pleasant Bay layered gabbro-diorite complex (420 Ma) formed via repeated injections of mafic magma into a felsic magma chamber. It is dominated by repeating sequences (macrorhythmic units) with chilled gabbroic bases which may grade upward into medium-grained gabbro, diorite and granite. Each unit represents an injection of mafic magma into the chamber followed by differentiation. Increases in Sr_i and decreases in )_Ndi with stratigraphic height indicate open-system isotopic behaviour and exchange between the mafic and felsic magmas. Isotopic variations of whole-rock samples in individual macrorhythmic units do not conform to bulk mixing or AFC models between potential parental magmas. Sr isotopic studies of single feldspar crystals from one macrorhythmic unit indicate that exchange of crystals between the resident felsic magma and mafic influxes was important, that some of the rocks contain feldspar xenocrysts, and that the rocks are isotopically heterogeneous on an intercrystal scale. Xenocryst abundance increases with stratigraphic height, suggesting that crystal exchange occurred in situ. The lack of disequilibrium textures in the xenocrystic feldspar indicates the evolved macrorhythmic magma and resident silicic magma were of a similar composition and likely in thermal equilibrium at the time of crystal transfer. Mafic chilled margins are enriched in alkalis and isotopically evolved compared with mafic dikes (representing the parental melts) and suggest rapid in-situ diffusional exchange following emplacement of individual mafic replenishments.     

Thermobarometry of mafic igneous rocks based on clinopyroxene-liquid equilibria, 0–30 kbar

 Models for estimating the pressure and temperature of igneous rocks from co-existing clino-pyroxene and liquid compositions are calibrated from existing data and from new data obtained from experiments performed on several mafic bulk compositions (from 8–30 kbar and 1100–1475° C). The resulting geothermobarometers involve thermodynamic expressions that relate temperature and pressure to equilibrium constants. Specifically, the jadeite (Jd; NaAlSi₂O₆)–diopside/hedenbergite (DiHd; Ca(Mg, Fe) Si₂O₆) exchange equilibrium between clinopyroxene and liquid is temperature sensitive. When compositional corrections are made to the calibrated equilibrium constant the resulting geothermometer is (i) 10⁴ T=6.73−0.26^* ln [Jd^px*Ca^liq*Fm^liqDiHd^px*Na^liq*Al^liq] −0.86^* ln [Mg^liqMg^liq+Fe^liq]+0.52^*ln [Ca^liq] an expression which estimates temperature to ±27 K. Compared to (i), the equilibrium constant for jadeite formation is more sensitive to pressure resulting in a thermobarometer (ii) P=−54.3+299^* T10⁴+36.4^* T10⁴ ln [Jd^px[Si^liq]^2*Na^liq*Al^liq] +367^*[Na^liq*Al^liq] which estimates pressure to ± 1.4 kbar. Pressure is in kbar, T is in Kelvin. Quantities such as Na^liq represent the cation fraction of the given oxide (NaO_0.5) in the liquid and Fm=MgO+FeO. The mole fractions of Jd and diopside+hedenbergite (DiHd) components are calculated from a normative scheme which assigns the lesser of Na or octahedral Al to form Jd; any excess Al^VI forms Calcium Tschermak’s component (CaTs; CaAlAlSiO₆); Ca remaining after forming CaTs and CaTiAl₂O₆ is taken as DiHd. Experimental data not included in the regressions were used to test models (i) and (ii). Error on predictions of T using model (i) is ±40 K. A pressure-dependent form of (i) reduces this error to ±30 K. Using model (ii) to predict pressures, the error on mean values of 10 isobaric data sets (0–25 kbar, 118 data) is ±0.3 kbar. Calculating thermodynamic properties from regression coefficients in (ii) gives V^Jd _f of 23.4 ±1.3 cm³/mol, close to the value anticipated from bar molar volume data (23.5 cm³/mol). Applied to clinopyroxene phenocrysts from Mauna Kea, Hawaii lavas, the expressions estimate equilibration depths as great as 40 km. This result indicates that transport was sufficiently rapid that at least some phenocrysts had insufficient time to re-equilibrate at lower pressures. Received: 16 May 1994/Accepted: 15 June 1995     

Tidal marsh stratigraphy, sea-level change and large earthquakes, i: a 5000 year record in washington, U.S.A.

Many of the estuaries of the Pacific Northwest of the U.S.A. and Canada contain stratigraphic sequences typified by alternating peat-mud couplets. Recent studies in this region interpret such couplets as the product of repeated large (magnitude S or 9) earthquakes on the Cascadia subduction zone. The resultant pattern of land-level movements is described by a model, the ‘earthquake deformation cycle’, of coseismic land subsidence followed by land uplift during interseismic strain accumulation. However, peat-mud couplets similar to those recorded in the Pacific Northwest are found on other less tectonically active temperate-latitude coasts, such as northwest Europe and the Atlantic coast of the U.S.A., where they have been interpreted as the product of non-seismic coastal processes. In this paper we apply the methods and scientific framework common to sea-level investigations in northwest Europe to a sequence of peat-mud couplets recorded in the lower Johns River, an estuary in southern Washington, to provide a test of the ‘earthquake deformation cycle’.Stratigraphic investigations of the intertidal sediments along the lower Johns River, using lithological, pollen, diatom and foraminiferal data, show evidence for eight coastal submergence events during the last 5000 years. To evaluate the ‘earthquake deformation cycle’ we assess the lateral extent of peat-mud couplets, the synchroneity of submergence, the presence of tsunami deposits accompanying submergence, and the suddenness and amount of submergence. Each submergence is shown to be accompanied by changes in coastal sedimentation broadly commensurate with those predicted by the ‘earthquake deformation cycle’, demonstrating the continued intermittent seismic activity of the Cascadia subduction zone throughout the mid and late-Holocene.Quantitative analyses of contemporary and fossil biostratigraphic data, using TWINSPAN and Detrended Correspondence Analysis, enable us to estimate the magnitude of submergence accompanying each peat-mud couplet. One event was accompanied by submergence of about 1.5 m or more, four events by intermediate submergence of about 1±0.5 m, and a further three events by submergence of <0.5 m. There is evidence for non-seismic relative sea-level rise prior to two of the eight submergence events, but for at least the last 3500 years the magnitude of relative sea-level rise has been less than the combined influence of sediment accretion following submergence and interseismic land uplift.     

A blast of gas in the latest Paleocene: simulating first-order effects of massive dissociation of oceanic methane hydrate

Carbonate and organic matter deposited during the latest Paleocene thermal maximum is characterized by a remarkable -2.5% excursion in delta 13C that occurred over approximately 10(4) yr and returned to near initial values in an exponential pattern over approximately 2 x 10(5) yr. It has been hypothesized that this excursion signifies transfer of 1.4 to 2.8 x 10(18) g of CH4 from oceanic hydrates to the combined ocean-atmosphere inorganic carbon reservoir. A scenario with 1.12 x 10(18) g of CH4 is numerically simulated here within the framework of the present-day global carbon cycle to test the plausibility of the hypothesis. We find that (1) the delta 13C of the deep ocean, shallow ocean, and atmosphere decreases by -2.3% over 10(4) yr and returns to initial values in an exponential pattern over approximately 2 x 10(5) yr; (2) the depth of the lysocline shoals by up to 400 m over 10(4) yr, and this rise is most pronounced in one ocean region; and (3) global surface temperature increases by approximately 2 degrees C over 10(4) yr and returns to initial values over approximately 2 x 10(6) yr. The first effect is quantitatively consistent with the geologic record; the latter two effects are qualitatively consistent with observations. Thus, significant CH4 release from oceanic hydrates is a plausible explanation for observed carbon cycle perturbations during the thermal maximum. This conclusion is of broad interest because the flux of CH4 invoked during the maximum is of similar magnitude to that released to the atmosphere from present-day anthropogenic CH4 sources.