A Lagrangian Model to Predict the Modification of Near-Surface Scalar Mixing Ratios and Air–Water Exchange Fluxes in Offshore Flow

A model was developed to predict the modification with fetch in offshore flow of mixing ratio, air–water exchange flux, and near-surface vertical gradients in mixing ratio of a scalar due to air–water exchange. The model was developed for planning and interpretation of air–water exchange flux measurements in the coastal zone. The Lagrangian model applies a mass balance over the internal boundary layer (IBL) using the integral depth scale approach, previously applied to development of the nocturnal boundary layer overland. Surface fluxes and vertical profiles in the surface layer were calculated using the NOAA COARE bulk algorithm and gas transfer model (e.g., Blomquist et al. 2006, Geophys Res Lett 33:1–4). IBL height was assumed proportional to the square root of fetch, and estimates of the IBL growth rate coefficient, α, were obtained by three methods: (1) calibration of the model to a large dataset of air temperature and humidity modification over Lake Ontario in 1973, (2) atmospheric soundings from the 2004 New England Air Quality Study and (3) solution of a simplified diffusion equation and an estimate of eddy diffusivity from Monin–Obukhov similarity theory (MOST). Reasonable agreement was obtained between the calibrated and MOST values of α for stable, neutral, and unstable conditions, and estimates of α agreed with previously published parametrizations that were valid for the stable IBL only. The parametrization of α provides estimates of IBL height, and the model estimates modification of scalar mixing ratio, fluxes, and near-surface gradients, under conditions of coastal offshore flow (0–50 km) over a wide range in stability.     

A photometric study of the nova‐like variable TT Arietis with the MOST satellite

Variability on all time scales between seconds and decades is typical for cataclysmic variables (CVs). One of the brightest and best studied CVs is TT Ari, a nova‐like variable which belongs to the VY Scl subclass, characterized by occasional low states in their light curves. It is also known as a permanent superhumper at high state, revealing “positive” (P_S > P₀) as well as “negative” (P_S < P₀) superhumps, where PS is the period of the superhump and P₀ the orbital period. TT Ari was observed by the Canadian space telescope MOST for about 230 hours nearly continuously in 2007, with a time resolution of 48 seconds. Here we analyze these data, obtaining a dominant “negative” superhump signal with a period P_S = 0.1331 days and a mean amplitude of 0.09 mag. Strong flickering with amplitudes up to 0.2 mag and peak‐to‐peak time scales of 15–20 minutes is superimposed on the periodic variations. We found no indications for significant quasi‐periodic oscillations with periods around 15 minutes, reported by other authors. We discuss the known superhump behaviour of TTAri during the last five decades and conclude that our period value is at the upper limit of all hitherto determined “negative” superhump periods of TTAri, before and after the MOST run. (© 2013 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

A geochemical approach to distinguishing competing tectono-magmatic processes preserved in small eruptive centres

Small eruptive centres (SECs) representing short-lived, isolated eruptions are effective samples of mantle heterogeneity over a given area, as they are generally of basaltic composition and show evidence of little magmatic processing. This is particularly powerful in volcanic arcs where the original melting process generating stratovolcanoes is often obscured by additions from the down-going slab (fluids and sediments) and the overlying crust. The Pucón area of southern Chile contains active and dormant stratovolcanoes, Holocene, basaltic SECs and an arc-scale strike-slip fault (the Liquiñe Ofqui Fault System: LOFS). The SECs show unexpected compositional heterogeneity considering their spatial proximity. We present a detailed study of these SECs combining whole rock major and trace element concentrations, U-Th isotopes and olivine-hosted melt inclusion major element and volatile contents to highlight the complex inter-relations in this small but active area. We show that heterogeneity preserved at individual SECs relates to different processes: some start in the melting region with the input of slab-derived fluids, whilst others occur later in a centre’s magmatic history with the influence of crustal contamination prior to olivine crystallisation. These signals are deduced through the combination of the different geochemical tools used in this study. We show that there is no correlation between composition and distance from the arc front, whilst the local tectonic regime has an effect on melt composition: SECs aligned along the LOFS have either equilibrium U-Th ratios or small Th-excesses instead of the large—fluid influenced—U-excesses displayed by SECs situated away from this feature. One of the SECs is modelled as being generated from fluid-enriched depleted mantle, a source which it may share with the stratovolcano Villarrica, whilst another SEC with abundant evidence of crustal contamination may share its plumbing system with its neighbouring stratovolcano Quetrupillán, showing that polygenetic–monogenetic connections are unpredictable. Such marked preservation of individual magmatic histories highlights the isolation of individual melting events even in complex and highly volcanically active areas.     

Magnesium ion chemistry in the stratosphere

Laboratory measurements of reaction rate constants of magnesium ions and magnesium containing ions with O₃, NO, HNO₃, and H₂O₂ have been carried out in a flowing afterglow experiment. Mg⁺ ions react with O₃ to produce MgO⁺ ions, which in turn react with O₃ to produce Mg⁺ ions. Mg⁺ ions react with HNO₃ and H₂O₂ to produce MgOH⁺ ions. MgOH⁺ ions react rapidly with HNO₃ to produce NO⁺₂ ions and Mg(HO)₂. One can therefore conclude that Mg⁺, MgO⁺, or MgOH⁺ ions could not have significant concentrations in the stratosphere if gas phase magnesium compounds were present. The failure to observe these ions therefore cannot be used as evidence that the stratospheric magnesium, resulting from meteor ablation at higher altitudes, is in condensed phases. This is in contrast to the case for sodium where the ion chemistry is such that the failure to observe hydrated Na⁺ ions proves that gas phase sodium compounds are not present in the stratosphere.     

The elastic response of multiple underream anchors

A technique is developed for the analysis of multiple underream anchor systems resting in an elastic soil. This technique may be used to consider anchor systems involving arbitrary anchor inclination and depth beneath the soil surface, as well as arbitrary number, shape, size and spacing of underreams. The approach is largely analytical in nature and involves only a fraction of the computation required for a finite element analysis. Consideration is given to the effects of anchor depth and inclination to the soil surface, and the spacing and number of underreams upon the elastic response of anchor systems. On the basis of the result from this study, a simple, approximate method for estimating the response of multiple underream anchors is proposed. This approach involves the use of several interaction charts, which are presented in the paper, and can be used as a hand method for estimating the load–displacement behaviour of quite general anchor systems to sufficient accuracy for most practical purposes. The use of the approximate approach is illustrated by an example.     

Thermomagnetic analysis of meteorites, 3. C3 and C4 chondrites

Thermomagnetic analysis was made on samples of all known C3 and C4 chondrites in a controlled oxygen atmosphere. Considerable variation was noted in the occurrence of magnetic minerals, comparable to the variation observed earlier in the C2 chondrites. Magnetite was found as the only major magnetic phase in samples of only three C3 chondrites (2–4 wt.%) and the Karoonda C4 chondrite (7.7 wt.%). The magnetite content of these three C3 chondrites is only about one-third that observed in the C1 and C2 chondrites which were found to contain magnetite as the only magnetic phase. Five C3 chondrites were observed to undergo chemical change during heating, producing magnetite: this behavior is characteristic of troilite oxidation. Upper limits on initial magnetite content of about 1–9% were established for these meteorites. Samples of the remaining five C3 chondrites and the Coolidge C4 chondrite were found to contain both magnetite and metallic iron. In two samples, iron containing ≤2% Ni was observed, while in the other four, the iron contained 6–8 wt.% Ni. In addition to containing both magnetite and iron metal, three of these samples reacted during heating to form additional magnetite. Variations in the magnetic mineralogy and, hence by inference bulk mineralogy, of C3 and C4 chondrites indicate a more complex genesis than is evident from whole-rock elemental abundance patterns.     

Thermomagnetic analysis of meteorites, 2. C2 chondrites

Samples of all eighteen of the known C2 chondrites have been analyzed thermomagnetically. For eleven of these, initial Fe₃O₄ content is low (generally <1%) and theJ_s-T curves are irreversible. The heating curves show variable greater (up to 10 times) than it is initially. This behavior is attributed to the production of magnetite from a thermally unstable phase — apparently FeS. Four of the remaining seven C2 chondrites contain Fe₃O₄ as the only significant magnetic phase: initial magnetite contents range from 4 to 13%. The remaining three C2 chondrites contain iron or nickel-iron in addition to Fe₃O₄. These seven C2 chondrites show little evidence of the breakdown of a thermally unstable phase.